DoD STTR 21.C

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Dual-use energetic formulations that can serve as both secondary high explosives and rocket propellants to enable dual-purpose rounds capable of trading range and penetration for detonation. DESCRIPTION: To date no formulation has been able perform as a propellant while offering PBXN-9 detonation velocity for terminal effects. Dual-use energetics offer the promise of an increased target set and extended range within the same round. This topic directly addresses the performance objectives of two Army Cross Functional Teams (CFTs). To this end, the topic requests novel materials for use as both a rocket propellant and a high explosive. The materials should enable development of a dual-use munition offering both an enhanced detonation mode and an extended-range/penetration mode. Such a munition would offer selectable effects through the use of an ignition element for the extended-range mode and a detonator for the high explosive mode. This development is expected to drive advancements in ignition and munition train technology, necessitating smart sensors to determine when the propellant should be detonated during flight. PHASE I: Offeror should produce samples of at least four different formulations under consideration and perform small-scale testing to indicate the materials are safe to handle in suitable quantities. Thermal characterization must be conducted to determine if the material will have the stability requisite for the intended application. This process will also provide data such as enthalpy of combustion, detonation speed, and decomposition temperature. Thermochemical code calculations should be performed to produce initial estimates of the performance of these materials. Small-scale combustion and detonation tests are to be conducted to assess the relative performance of the developmental materials under consideration. PHASE II: Offeror should produce two or three formulations (downselected based on input from Armaments Center) to perform larger scale testing. This process should incorporate tests such as cylinder expansion, detonation velocity and pressure, characterization of mechanical properties, critical diameter, gap sensitivity, strand burner tests (at various pressures), 2x4 inch thrust tests, and aging studies. This data should be evaluated to identify the best candidates for the intended application. PHASE III DUAL USE APPLICATIONS: Phase III will focus on a live-fire demonstration of the developmental formulation in a complete munition. This process will showcase a munition that demonstrates efficient use of the energetic payload in both modes. Other relevant testing such as IM testing, arena testing, set back testing, penetration depth, etc. will also be conducted as necessary depending on the needs of the item manager. REFERENCES: 1. The chemistry of explosives, Jacqueline Akhavan; 2. Introduction to the technology of explosives, Paul Cooper; 3. Explosive Effects and Applications, Jonas Zukas, William Walters KEYWORDS: Explosive, rocket, propellant, munition, secondary, lethality, range, dual use

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Investigate and develop innovative designs and technologies to incorporate RF transparent windows, conformal antenna technology, and supporting apertures on gun-launched smart projectiles with hypersonic capability. DESCRIPTION: Advancements in the development of electromagnetic railguns and extended-range cannon artillery are paving the road for cost-effective engagement of land, sea, and air targets at extreme ranges. To unlock this capability, projectiles must incorporate advanced RF components such as multifunctional conformal antennas. Given the extreme aerothermal environment (>1000°C) and the system-level integration of hypersonic projectiles, these components must reside underneath an RF transparent window to survive and operate for the duration of flight. All components, manufacturing techniques, and integration concepts must also endure gun launch acceleration as high as 30,000 g. PHASE I: Phase I will be a proof of concept study to determine the feasibility of RF transparent window and aperture assembly designs. Investigations should include analysis of potential aperture mounting configurations, ability of the antenna to transmit in S-Ku (2-18 GHz) band (gain, polarization, bandwidth, pattern coverage) through high-temperature compatible materials, survivability of window materials, and window application methods. RF performance shall be verified through simulation and breadboard antenna measurements. A final proposed concept design featuring a detailed description and analysis of both expected thermal and mechanical loads, shall be delivered at the conclusion of the phase I effort. PHASE II: The proposer shall deliver two prototype radome/antenna assemblies integrated with the prototype antenna apertures in an existing large caliber projectile form factor with the proposed integrated RF transparent window or thermal protection system (TPS) solution. The design should ensure survivability of high shock and thermal loads without additional thermal protective systems or layers. The materials shall be designed for minimal impact to wave front distortion and boresight error. The design should also minimize weight, volume, and specialized handling and processes. The design will feature high-performance TPS composites for hypersonic window and radome applications with wide pass bands in the L through Ku band range (1-18 GHz) for various functions, including GPS navigation and guidance and terminal homing. Also of interest is operation up to W-band (94 GHz). The proposer must demonstrate launch survivability of window materials. The proposer must also conduct multi-minute extreme thermal testing of window/aperture assemblies to include electromagnetic measurements during testing to ensure the apertures can avoid failure or degradation underneath a high-temperature window. Integration with system-level thermal protection systems should also be explored. PHASE III DUAL USE APPLICATIONS: The proposer must coordinate with prime contractors and all service components to fully develop, integrate, and test the performance and survivability characteristics of the design for integration into extended-range Army platforms and joint development efforts. This technology with be a strong candidate for product improvements to munitions in service with the service components. REFERENCES: 1. Santamaria, Maj. Paul & Draheim, Capt. Steve. Acquisition, Army ALT Magazine. “PEO Ammunition, ARDEC and the Army Rapid Capabilities Office come together at Picatinny Arsenal” https://asc.army.mil/web/news-alt-jas-18-long-range-short-term/; 2. 256 120mm Smoothbore Gun, www.inetres.com/gp/military/cv/weapon/M256.html KEYWORDS: Hypersonic, projectile, radio frequency, communications, munition, artillery, sensors, high-temperature materials, antenna

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Develop techniques to incorporate energetic solid filler such as HMX, RDX, or Nitroguanidine (NQ) with feedstock for additive manufacturing of gun propellant. DESCRIPTION: This development effort focuses on materials to enable 3D printing of gun propellants. Additive manufacturing presents the opportunity for performance gains through highly engineered complex structures. These structures offer the potential for increased loading densities and higher surface area progressivity. These properties, in turn, translate to extended range for existing weapon platforms. The developmental materials must match the high-strain-rate mechanical properties of JA2 propellant while providing propellant performance characteristics that match or exceed those of M31A2. The threshold energy level is a calculated impetus of 950 J/g with an objective level of 1100 J/g. The materials should also have superior low-temperature properties to avoid brittle fracture (glass transition below -50 Deg F, Tg) and should retain shape up to 145 deg F. This level of will likely be achieved through the addition of the energetic fillers. Materials can be a mixture of various polymers and additives. The proposed solution must not produce toxic combustion products and those that result in excessive residue and erosion. Oxygen balance and ignition properties must also be considered up front for this solution to be viable for defense applications. PHASE I: Demonstration of achieving greater than or equal to 75% solids loading by mass of filler with 1.7 - 1.9 g/cc density and nominal particle size of 10 micrometers. Second and equally weighted deliverable is demonstration of utilizing a commercial off the shelf or custom 3D printer that uses vat photopolymerization methods to obtain samples for testing. Third is characterization of preliminary mechanical properties including uniaxial compression results at high strain rates (1/100 seconds) and associated material characterization (density, microscopy, physical, chemical, etc.). If the capability to demonstrate at 1/100 seconds is unavailable in the private sector, lower strain rates with accompanying analysis may be used to extrapolate results. Alternatively, proposer may submit the material for evaluation at US government facilities at no charge. Additionally, cure/penetration depth of development materials must demonstrated and provided. PHASE II: Required Phase II deliverables would be scale-up of feedstock and delivery of said feedstock in a quantity greater than 500 ml. to a government and/or contractor facility for further performance evaluation. Subscale evaluation of said materials in both mechanical and combustion testing would be required to corroborate the results of phase I. The contractor stablished resolution limits, delivering sample calibration prints of said materials (and associated analysis) with proposed printing methods utilizing vat photopolymerization (selected during phase I). PHASE III DUAL USE APPLICATIONS: The end state of this research would be a material feedstock that balances high-performance combustion characteristics and superior mechanical properties in the extreme gun environment during the interior ballistic event. The target US Army application would be the 155mm Artillery platform due to the need for extended range. This technology will be transitioned to GOCO ammunition plants such as Radford Army Ammunition Plant, and will benefit from early engagement with the prime contractors operating these facilities. Commercial applications of this material include dental use (highly dense and highly filled materials), high performance composites, clean burning pyrotechnics (fireworks), and any application where a consumable 3d Printed object is needed. REFERENCES: 1. Photopolymerization processes of thick films and in shadow areas: a review for the access to composites; Patxi Garra, Céline Dietlin, Fabrice Morlet-Savary, Frédéric Dumur, Didier Gigmes, Jean-Pierre Fouassier and Jacques Lalevée; Polymer Chemistry - Royal Society of Chemistry 2017; Polym. Chem., 2017, 8, 7088; 2. Office of Naval Research ONR Scientific Officer: Steven G. Fishman; 01 January 1993- December 31, 1994; Final Technical Report August 25, 1997; 3. Preparation and Properties of Dental Composite Resin Cured under Near Infrared Irradiation; Motohiro Uo, Eiki Kudo, Aya Okada, Kohei Soga and Yasuo KOGO; Department of Biomedical Materials & Engineering, Hokkaido University, Sapporo 060-8586, Japan, Department of Material Science and Technology, Tokyo University of Science, Chiba 278-8510, Japan; mail@m-uo.com; 4. CHARACTERIZATION OF CURING KINETICS AND POLYMERIZATION SHRINKAGE IN CERAMIC-LOADED PHOTOCURABLE RESINS FOR LARGE AREA MASKLESS PHOTOPOLYMERIZATION (LAMP) A Thesis Presented to The Academic Faculty by Kiran Kambly In Partial Fulfillment Of the Requirements for the Degree Master of Science in Mechanical Engineering Georgia Institute of Technology Dec, 2009 KEYWORDS: 3D printing, additive manufacture, gun propellant, gun propulsion, combustion, highly filled material, highly filled composite, high performance photopolymer, photopolymer, toughness

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Develop and demonstrate energetic ingredients for polymer resin systems (monomers, plasticizer(s), related additives) for use in explosive and propellant formulations with additive manufacturing capabilities. DESCRIPTION: The US Army has a need to develop energetic formulations suitable for additive manufacturing (AM) based on printing technologies such as direct-write extrusion and vat polymerization. To enhance the energetic performance and printability of these formulations, new energetic ingredients for AM resin systems are desired. Specifically, these include energetic monomers, crosslinkers, and plasticizers. Although additive manufacturing techniques are largely recent developments, energetic polymers and plasticizers have a relatively long history. Their purpose has generally been as components in chemically cured energetic formulations such as explosive “cast-cure” or polymer-bonded explosives (PBX), where energetic monomers and plasticizers are blended with high-solids loadings of explosive materials (e.g. RDX) and chemically cured into a desired shape/configuration. Existing energetic polymer examples include glycidyl azide polymer (GAP) and poly(3-nitratomethyl-3-methyloxetane) (polyNIMMO). Plasticizer examples include nitroisobutanetriol (NIBTN), bis(2,2-dinitroproplyl) acetal/formal (BDNPA/F), and triethylene glycol dinitrate (TEGDN). In general, these materials often suffer from drawbacks such as poor mechanical properties, stability or sensitivity issues, lower achievable solids-loading, production difficulties, and/or low energetic performance. They were also not developed with next-generation additive manufacturing technologies in mind. Printing techniques such as direct-write extrusion and vat polymerization typically require curable resin systems with appropriate rheological properties, controllable curing and good interlayer adhesion. To both provide higher energetic performance and better align with these AM technologies, new high energy-density, curable polymeric resin materials are required to push the envelope of energetic performance while enhancing stability and improving producibility.   PHASE I: With the goal of working towards one or more complete, curable, high-performance energetic resin system(s), design and determine the technical feasibility for producing novel, AM-applicable energetic resin ingredients to include one or more of the following: energetic monomer(s), energetic polymer(s), energetic plasticizer(s), and/or related additives including photoinitiators and other curatives. Perform theoretical energetic calculations to establish predicted performance and aid in the selection of materials. Develop synthetic approaches to the materials and produce small lab-scale quantities of materials for characterization and safety screening. In addition to strong energetic performance and safe handling, selected materials should be chemically compatible with traditional military explosive ingredients (e.g. nitramines) and munition housing materials (e.g. stainless steel). PHASE II: Required Phase II deliverables will include the formulation of the identified Phase I energetic polymeric materials into complete chemically-curable energetic resin systems suitable for AM processing. Develop and demonstrate scale-up of down-selected ingredients to the pilot production scale. Evaluate printing of specific parts to demonstrate printability of the resin system. The small business will ship 100 gram samples of the resin system(s) to DEVCOM Armaments Center for verification of product quality and suitability for AM processing. PHASE III DUAL USE APPLICATIONS: The pilot processes developed in Phase II will be scaled up to the production level. Military applications will focus on explosive and propellant charges. Commercialization areas potentially include the construction, mining, and space industries. REFERENCES: 1. Provatas, A., Energetic Polymers and Plasticisers for Explosive Formulations—A Review of Recent Advances, Technical Report DSTO-TR-0966, Defence Science and Technology Organisation (DSTO), Aeronautical and Maritime Research Laboratory, Melbourne, Victoria, Australia, April 2000, https://apps.dtic.mil/dtic/tr/fulltext/u2/a377866.pdf; 2. Ligon, S. C.; Liska, R.; Stampfl, J.; Gurr, M.; Mulhaupt, R., Polymers for 3D Printing and Customized Additive Manufacturing. Chem. Rev., 2017, 117 (15), 10212-10290; 3. Desai, H. J.; Cunliffe, A. V.; Hamid, J.; Honey, P. J.; Stewart, M. J.; Amass, A. J., Synthesis and characterization of α,ω-hydroxy and nitrato telechelic oligomers of 3-(nitratomethyl)-3-methyloxetane (NIMMO) and glycidyl nitrate (GLYN). Polymer, 1996, 37 (15), 3461-3469; 4. Straathof, M. H.; van Driel, C. A.; van Lingen, J. N. J.; Ingenhut, B. L. J.; ten Cate, A. T.; Maalderink, H. H., Development of Propellant Compositions for Vat Photopolymerization Additive Manufacturing. Propellants, Explos., Pyrotech., 2020, 45 (1), 36-52. KEYWORDS: Additive manufacturing, explosive formulation, propellant formulation, energetic plasticizer, energetic polymer

OBJECTIVE: Develop a coating for engine fuel systems that will form a protective tribofilm that enables higher-pressure fuel systems to accommodate the variations possible in F-24 fuels. DESCRIPTION: The increasing use of unmanned ground and aerial vehicles has exposed the need for higher performance engines for these systems. Increasing the performance of these engines requires operation at higher fuel pressures, which creates a challenge related to fuel lubricity. Sufficient fuel lubricity in the engine fuel systems is a necessity for effective operation. At higher pressures that need is more acute, as insufficient lubricity could lead to catastrophic failure due to wear or damage. Most of these vehicles use F-24 jet fuel. There are many different blends of F-24 due to variations in the base fluid and contaminants present. This makes it very difficult to employ in higher-pressure common rail engines, as they may not have sufficient lubricity under all the potential F-24 formulations available. It may not be possible to obtain the ideal formulation of F-24 in the field, and the use of an unsuitable formulation may impair or damage the engine. For higher-pressure fuel systems to be practical in a logistical sense, a solution that enables consistent lubricity for these engines under a variety of conditions and formulations is required. The most practical solution would be a coating that provided protection and sufficient lubricity to the engine parts during operation by formation of renewable protective coatings. A recently proposed solution is the use of coatings that form self-lubricating carbon-based diamond like coatings due to catalytic breakdown of hydrocarbons and contaminants in the fuel [1,2]. This previously was very difficult as these catalysis reactions are facilitated by the use of precious metals such as platinum and gold [3]. In addition, the coating also had to be nanostructured to obtain the desired level of interaction with the organic compounds in the fuel. Recent publications, however, have established it is possible to create nanocrystalline coatings using physical vapor deposition and sputtering techniques [4]. In addition, advances in the field of nanocrystalline alloy design have led to the discovery of a number of potential nanocrystalline alloy compositions that are suitable to fabrication via sputtering or other surface coating techniques [5]. This opens up the possibility of creating a stable nanocrystalline coating using more cost effective alloying elements. In fact, there have been recent publications demonstrating protective tribofilm formation using coatings containing Co, Mo, Cr, Al, and other alloying elements [1, 6]. This makes it plausible that a practical nanocrystalline alloy that forms protective tribofilms during engine operation could be developed for wide scale employment in the field. While some coatings have been demonstrated in the laboratory, there is still a great deal of development required before they can be utilized in an engine fuel system. Any coating used for this application must be stable under a variety of conditions and robust under mechanical stresses. The tribofilm formed must be protective, otherwise the coating would prematurely wear and cause the engine to fail. In addition, the processing challenges related to industrial scale application of the coating and consistent application to complex geometries have to be addressed. PHASE I: The offeror(s) shall develop a coating for AISI 52100 steel that will form protective tribofilms in alkane based fuels. A composition shall be selected that will form a stable nanocrystalline structure, not utilize precious metals such as platinum, palladium, and gold, and be mechanically stabile under load. The mechanism used to create the tribofilm can be based on any type of or combination of mechanisms (e.g. compositional, morphological, mechanical, etc.). However, the tribofilm created should provide protection for the coating and the steel and renew through continuing interactions with the fuel. The coating itself should not require reapplication for long-term function. The final deliverable shall be at least one candidate coating composition, lubricity testing results, and evidence of tribofilm formation. The coating shall be applied to a ball of AISI 52100, and tested for lubricity under following conditions: 1) in comparison to the standard hardened AISI 52100 ball, 2) with at least two fuels selected from diesel, Jet-A, and F-24, 3) using fuel lubricity standard ASTM D6079 (High-Frequency Reciprocating Rig), and 4) using fuel lubricity standard ASTM D5001 (Ball-On-Cylinder Lubricity Evaluator). F-24 can be obtained from the Army sponsor. PHASE II: The offeror(s) shall continue to refine the coating composition, and begin to develop the processing approach for uniform application of the coatings to conformal and complex parts. The compositions identified in Phase I should be adjusted to be suitable for wide scale industrial fabrication. The offeror(s) should select a processing approach, and develop methodologies for uniform application of the coating on conformal AISI 52100 steel parts relevant to high-pressure fuel pumps. The final deliverables shall be four components (pumping piston, piston bore, small crowned cylinder, large cylinder) of a pump rated to reach 1500 bar or greater, with the coating uniformly applied to all contacting surfaces and tested for lubricity in two mechanical interfaces. Interface 1: One piston/bore conformal interface shall be tested with coating on the external surface of a piston and internal surface of a bore (both 5 to 8 mm diameter with clearance of less than 2 micrometer between piston/bore), reciprocating between 1-cm and 2-cm axial interface length, at a reciprocating frequency of at least 30 Hz. Interface 2: One cam-like interface shall be tested between a coated crowned cylinder of 5 to 8 mm sliding on a larger coated cylinder at 4 m/s. Lubricity testing in these two interfaces shall be conducted: 1) in comparison to hardened AISI 52100 steel in the same geometries and conditions, and 2) with three fuels (diesel, Jet-A, and F-24). Alternatively, the coating may be applied to components of a commercial high-pressure fuel pump with an oblong, rotary cam system capable of reaching 1500 bar fuel pressure, to include the pumping piston/cylinder and sliding interfaces of the cam system, and demonstrated with respect to an unmodified pump under conditions similar to those for the two interfaces. PHASE III DUAL USE APPLICATIONS: The technology will support reliable engine operation of internal combustion reciprocating engines for Class II and III Unmanned Aerial Systems, for medium-sized ground vehicles, and for generators. The offeror(s) will adapt the processing technology to apply it to existing engine fuel systems. Coatings for other metallic alloys or composite materials will be developed. The process will be adapted so that engine components with the protective component are commercially available to researchers working on high-pressure fuel systems designs. The coatings could either be used to modify commercially available high-pressure fuel system components in an aftermarket process, or the coating could be integrated into new fuel system designs. REFERENCES: 1. Erdemir, A; Ramirez, G.; Eryilmaz, O; Narayanan, B; Liao, Y.; Kamath, G; and Sankaranarayanan, S; Carbon-based tribofilms from lubricating oils, Nature, Vol 536, Aug 4 2016; 2. Ali, M.; Xianjun, H.; Abdelkareem, M; Gulzar, M; and Elsheikh, A.H., Novel approach of the graphene nanolubricant for energy saving via antifriction wear in automobile engines, Tribology International, Vol 124, 2018, pp. 209-229; 3. Argribay, N; Babuska, T.F.; Curry, J.F.; Dugger, M.T.; Lu, P.; Adams, D.P.; Nation, B.L.; Doyle, B.L.; Pham, M.; Pimentel, A.; Mowry, C.; Hinkle, A.R.; and Chandross, M., In-situ tribochemical formation of self-lubricating diamond-like carbon films, Carbon, Vol. 138, 2018, pp. 61-68; 4. Zhou, XY.; Kaub, T; Martens, RL; and Thompson, GB., Influence of Fe(Cr) miscibility on thin film grain size and stress, Thin Solid Films, Vol. 612, Aug 1, 2016, pp. 29-35; 5. Gibson, M; Schuh, C, Segregation-induced changes in grain boundary cohesion and embrittlement in binary alloys, Acta Materialia, Vol. 95, 2015, pp. 145-155; 6. Bobzin, K.; Brögelmann, T.; and Kalscheuer, C.; Arc PVD (Cr, Al, Mo)N and (Cr,Al,Cu)N coatings for mobility applications, Surface & Coatings Technology, Vol. 384, 2020, pp. 125046 KEYWORDS: Coatings, fuel lubricity, catalysis, tribology, nanostructured coating, active coating

OBJECTIVE: Develop, optimize, and demonstrate the use of high-throughput, sub-scale ballistic test setup that incorporates automated or autonomous functionality to maximize both data output and fidelity relative to full-scale ballistic testing. DESCRIPTION: Data-driven materials design is a burgeoning field with the potential to rapidly accelerate new materials development, provided that large volumes of data can be efficiently generated and analyzed. The Department of Defense (DoD) is interested in data-driven design of next-generation protection materials. However, ballistic evaluation of protection materials presents a significant bottleneck: due to safety concerns and stringent testing requirements (e.g., the V50 ballistic test for armor as described by DoD MIL-STD-662F), full-scale ballistic tests are expensive and generate data at a very low rate, on the order of 10 samples/day. Sub-scale ballistic testing (e.g., laser-driven micro-projectiles, air gun-driven microbeads, electric-discharge-driven flyer plates) offers a potential route around these limitations, with the ability to use dramatically smaller projectiles and smaller samples to improve safety, expense, and significantly increase throughput. Nonetheless, sub-scale ballistic data collection is still relatively slow—alignment and calibration are exhaustively hands-on processes that could benefit from automation—and analysis is still done manually and post mortem. For example, fragmentation analysis, a valuable proxy for impact performance of brittle protection materials, is still done by manually collecting and analyzing each fragment that results from the subscale ballistic impact. Importantly, the accuracy of sub-scale methods against full-scale ballistic tests must be further evaluated: equivalent testing standards do not yet exist, and sub-scale techniques are only valuable so far as they provide accurate information about the real-world ballistic performance of a protection material. This situation warrants a concerted effort to enable high-throughput sub-scale ballistic testing and carefully evaluate its fidelity. The goal for this effort is to develop a sub-scale ballistic testing platform as a critical tool for data-driven, high-throughput design and characterization of next-generation protection materials. PHASE I: Define and develop an approach for high-throughput sub-scale ballistic testing of macroscale protection materials. The specific sub-scale method is not prescribed, but must be capable of creating ballistic, high loading rate (i.e. between 104 and 107 s-1) mechanical testing conditions that serve as an accurate proxy for a full-scale ballistic test. Specific capabilities that are desired include: in situ quantitative characterization and analysis capabilities that provide as good or better determination of ballistic performance as traditional post mortem manual analysis or conventional failure probability analyses, like V50. The approach should also be capable of automation (e.g., in sample preparation/loading, alignment, data processing, etc.) to maximize testing and data throughput: the concept must demonstrate a 10-fold improvement in the rate of experimentation over manual subscale ballistic testing, and a 100-fold improvement over full scale ballistic testing conventionally used to satisfy V50/MIL-STD-662F. Note that the approach is not intended to replace ballistic testing standards, but rather shall complement existing standards by enabling rapid screening of materials. The method should be tailored for research and development of next-generation hard protection materials based on ceramics, composites, and/or metals (as opposed to soft materials like polymers, or low-dimensional materials like graphene), and must serve as an accurate surrogate for full-scale ballistic testing while simultaneously enabling safe, high-throughput data generation and collection for data-driven design of advanced protection materials. The concept must also outline an approach for qualifying the accuracy of the method with respect to predicting material performance under full scale ballistic testing based on MIL-STD-662F. If awarded the Phase I option, the small business will demonstrate the feasibility of the proposed concept/approach. Develop a Phase II plan. PHASE II: Based on Phase I results, develop, demonstrate, and validate the proposed high-throughput test apparatus for sub-scale ballistic testing. The accuracy of the automated in situ approach will be quantified relative to a manual post mortem approach to data analysis, using the same sub-scale ballistic technique. The test must demonstrate a 10-fold improvement in the rate of experimentation with respect to manual subscale ballistic testing, and a 100-fold improvement over full scale ballistic testing to satisfy V50/MIL-STD-662F. The technique should encompass one or more of the following projectile geometries: highly planar flyer plates, spheres, and/or projectiles with ogived noses. The technique should enable various angles of target obliquity with respect to the vector of projectile velocity. High throughput data generation should be leveraged to facilitate data-driven inferences about the behavior and design of protection materials. The fidelity of the sub-scale technique and these inferences will be evaluated with select full-scale ballistic tests for V50/MIL-STD-662F. It is recommended that the performer work with government laboratories and/or established testing agencies to perform these select ballistic tests. It is also recommended that the performer work with bulk material vendors/Original Equipment Manufacturers (OEMs) and/or ballistic testing agencies to facilitate transition for Phase III. Successful completion of Phase II shall include a demonstration to DEVCOM Army Research Laboratory scientists and engineers engaged in ballistic testing of protection materials. PHASE III DUAL USE APPLICATIONS: The completion of this effort would provide an automated tool that receives, prepares, assesses, and analyzes the ballistic performance of subscale samples in a way that accurately reflects the global behavior of the bulk material. Phase III will transition high throughput sub-scale ballistic testing techniques to commercial suppliers through bulk material vendors, OEMs, or other partnering agreement(s). Commercialization of this technology may be through the development of kits or modules for retrofitting existing subscale ballistic testing apparatus, or through the development of full turn-key systems. If successful, this technology would provide DoD engineers with a platform for rapidly assessing the ballistic performance of next generation armor materials. REFERENCES: 1. MIL-STD-662F, Department of Defense Test Method Standard: V50 Ballistic Test for Armor (18 December 1997), http://everyspec.com/MIL-STD/MIL-STD-0500-0699/MIL-STD-662F_6718/; 2. NIJ Standard-0101.06, Ballistic Resistance of Body Armor (July 2008), https://www.ncjrs.gov/pdffiles1/nij/223054.pdf; 3. ASTM E3110 / E3110M – 19, Standard Test Method for Collection of Ballistic Limit Data for Ballistic-resistant Torso Body Armor and Shoot Packs; 4. Mallick, Debjoy D., and Ramesh, K.T. “Dynamic Fragmentation of Boron Carbide Using Laser-Driven Flyers.” International Journal of Impact Engineering, Vol. 136 (2020), 103416, https://www.sciencedirect.com/science/article/pii/S0734743X19307304; 5. Hassani, Mostafa, Veysset, David, Nelson, Keith A., and Schuh, Christopher A. “Material Hardness at Strain Rates Beyond 106 s-1 via High Velocity Microparticle Impact Indentation.” Scripta Materialia, Vol. 177 (2020), 198-202. https://www.sciencedirect.com/science/article/pii/S1359646219306256; 6. Lee, Jae-Hwang, Loya, Phillip E., Lou, Jun, and Thomas, Edwin L. “Dynamic Mechanical Behavior of Multilayer Graphene via Supersonic Projectile Penetration.” Science, Vol. 346 (2014), 1092-1096. https://science.sciencemag.org/content/346/6213/1092 KEYWORDS: Ballistic test, armor design, subscale testing, data-driven design, protection material, automation, machine learning, autonomous experimentation, high-throughput experimentation

OBJECTIVE: Develop, optimize, and demonstrate fast, frequency-agile, stimuli-responsive, and tunable optical filters that autonomously protect sensors from damaging optical beams, while allowing unobstructed transmission of non-damaging wavelengths and intensities. DESCRIPTION: The Department of Defense (DoD) increasingly relies on advanced imaging technologies to perform critical functions like intelligence, surveillance, and reconnaissance (ISR) and positioning, navigation, and timing (PNT). Advanced imaging sensors—like electro-optical/infrared (EO/IR) cameras and micro-bolometers—will dramatically proliferate as DoD continues to modernize with autonomous platforms such as the Army’s Next Generation Combat Vehicle. However, these sensors are vulnerable to inadvertent and adversarial electromagnetic (EM) attack: future operating environments will be replete with a wide range of EM waves of varied frequency and intensity, many of which could temporarily or permanently blind or damage imaging systems. The ability to control strong light-matter interaction in liquid crystals[1], metamaterials [2-5], epsilon-near-zero (ENZ) materials [6,7], phase change materials (PCMs) [8,9], micro-electromechanical systems (MEMS) [10],and soft materials [11-14] suggest that these state-of-the-art materials systems can be leveraged to create tunable filters that autonomously respond to EM attack. For example, spatial light modulation (SLM) by metamaterials, holography, and liquid crystals enables selective-area light attenuation [1,2]. Digital metamaterials offer lenses and phase modulators capable of light redirection and beam steering [3,4]. Non-linear optical responses in Bragg reflector stacks and ENZ materials provide another potential route to autonomous light attenuation [5-7]. Integrating these concepts with PCMs, MEMS, and micro-mirrors may reveal new opportunities and platforms for programmable SLM and beam steering [8-10]. Finally, soft materials like liquid crystal elastomers and photo-responsive hydrogels have recently emerged as new platforms for autonomous manipulation of light [11-14], offering new abilities to create nano/microstructures that move in response to light and platforms for trapping and guiding laser beams. New capabilities in nano-/microfabrication may enable new, hierarchical approaches that combine multiple stimuli-responsive materials and architectures to further enhance adaptability. If under EM attack, an imaging system must incorporate a filter that rapidly senses an EM wave, determines its wavelength, and autonomously responds to attenuate or re-direct the wave if necessary. This capability is necessary over broad spectral ranges, including ultraviolet, visible, short-wave infrared (SWIR), and long-wave infrared (LWIR). An ideal intelligent filter mechanism would be (1) Operable in typical battlefield conditions; (2) Compatible with dynamically reconfigurable and/or multi-spectral imaging systems; (3) Low-cost, to enable wide adaptation across the DoD; (4) Adaptable to different imaging architectures; and (5) Non-disruptive to imaging performance (e.g., range, resolution, frame-rate, etc.). This topic seeks innovative materials approaches to creating such filters, based on passive material-based intrinsic responses and/or active feedback circuits incorporating tunable materials. Adaptive filters should autonomously detect changes in operating conditions and/or EM-based insults (e.g., a change in lighting conditions vs. incident laser beams) and respond appropriately by physically dimming, shuttering, switching, filtering, blocking, and/or rejecting the dynamic light conditions. The response should further be localized to the incident beam or spot where appropriate, to maintain an unobstructed field-of-view for the rest of the imaging system. Finally, there is also a significant need for scaled-up manufacturing capacity and yield—the desired adaptive filters should be amenable to integration with imaging sensors with minimum added size, weight, power, and cost (SWaP-C). PHASE I: Design a concept for candidate FAST filters and describe the proposed materials systems, architectures, and control schemes that will be employed. Perform ab initio atomistic modeling, full wave EM simulations, quasi-static simulations, finite element analysis, and/or technology computer-aided design (TCAD) as needed to demonstrate the feasibility of the proposed approach. Outline the techniques and procedures that will be used to fabricate the proposed design and characterize its dynamic filtering performance. Develop an approach to integrate the proposed FAST filter with a desired sensor technology, imaging platform, or form factor, selected from the following: focal-plane array (flat or curved), optical windows and lenses, glasses, contact lenses, goggles, or visors. As appropriate, create a partial prototype that demonstrates the functionality of one or more of the proposed design elements: the dynamic materials system, the filter architecture, the control scheme (if applicable), and/or the integration scheme. FAST filter designs should inherently address or be easily adaptable to operate in the visible (380 – 780 nm) and the short-wave infrared (SWIR, 780 – 3000 nm) portions of the EM spectrum. Ultraviolet (UV, 100 – 380 nm) and mid-/long-wave infrared (MWIR/LWIR, 3000 – 14000 nm) light are also of (secondary) interest. The filtering mechanism should be dormant under normal imaging conditions, with optical transmission of 70 – 80% or greater at the nominal imaging wavelengths. The filter should autonomously respond to respond to high-fluence light (e.g., a high-power laser with a fluence on the order of 1 J/cm2) above the damage threshold of the imaging system should be interdicted by the filter changing its optical density (OD) by 3 or more (i.e., less than 0.1% of the incident laser energy should reach the sensor). The filter responses should be as localized to the incident spot size, in order to allow uninterrupted imaging while obscuring the sensing element(s) beneath the incident spot. These filter responses should be fully reversible, and the response time, including recovery to normal imaging conditions, should be no longer than 50 milliseconds. Articulate feasible pathways to response times of 1 nanosecond or less. Secondary considerations for FAST filter design include: 1) Low fluence light (e.g., changes in lighting conditions caused by shadows or moving between indoors and outdoors) should cause the filter to remain passive so that the imaging system can automatically adjust to lighting conditions; 2) Medium fluence light (e.g., an adversarial laser-based sensor or probe) should be fully absorbed, redirected, or otherwise mitigated to cloak the imaging system. PHASE II: Based on Phase I modeling and proofs of concept, fabricate, test, and demonstrate at least one operational FAST filter prototype. The prototype should be capable of autonomous optical responses with sub-ns response times. The FAST filters should reversibly cycle over 105 times without suffering more than 2% degradation in response time, OD change, reflection, transmission, dormant state/position, etc. Using a detailed analysis of system trades and input from appropriate stakeholders, propose a pathway to refine and integrate the FAST filter prototype with a candidate imaging system of interest to or used by the Army. Depending on the target imaging system, the FAST filters should increase the total SWaP-C burden by 0.1% or less, should not adversely impact imaging performance, and should allow normal imaging modality over typical ranges of brightness/lighting conditions; more specifically, FAST filters under normal imaging conditions should not change the system’s modulation transfer function by more than 10%, and should not change transmission of imaging wavelengths by more than 20%. PHASE III DUAL USE APPLICATIONS: Phase II should demonstrate a FAST filter that is appropriate for implementation with existing and/or future Army imaging systems. Phase III will transition the newly developed FAST filter technology to commercial availability through the prime contractors that build these imaging systems, the original equipment manufacturers that manufacture sensing components, other relevant suppliers, and/or other partnering agreement(s), as appropriate. Commercialization of this technology may occur via the incorporation of one or more FAST filters anywhere in an imaging system (e.g., windows, lenses, shutters, FPA pixels, etc.). Ideally, a successful effort will deliver a capability upgrade for a relevant Army Program of Record at the end of Phase III, in the form of an imaging system that autonomously responds to EM attack with no added cognitive burden to the user, and a minimum added SWaP-C burden. Expected dual-use applications include autonomous vehicles, LiDAR, border security, and protecting civilian optical imaging systems (e.g., thermal imaging of the sun). REFERENCES: 1. Forbes, A., Dudley, A., & McLaren, M. (2016). Creation and detection of optical modes with spatial light modulators. Advances in Optics and Photonics, 8(2), 200-227; 2. Fan, K., Suen, J. Y., & Padilla, W. J. (2017). Graphene metamaterial spatial light modulator for infrared single pixel imaging. Optics Express, 25(21), 25318-25325; 3. Della Giovampaola, C., Engheta, N. Digital metamaterials. Nature Mater 13, 1115–1121 (2014); 4. Cui, T. J., Qi, M. Q., Wan, X., Zhao, J., & Cheng, Q. (2014). Coding metamaterials, digital metamaterials and programmable metamaterials. Light: Science & Applications, 3(10), e218-e218; 5. Vella, J. H., Goldsmith, J. H., Browning, A. T., Limberopoulos, N. I., Vitebskiy, I., Makri, E., & Kottos, T. (2016). Experimental realization of a reflective optical limiter. Physical Review Applied, 5(6), 064010; 6. Nahvi, E., Liberal, I., & Engheta, N. (2020). Nonlinear metamaterial absorbers enabled by photonic doping of epsilon-near-zero metastructures. Physical Review B, 102(3), 035404; 7. Alam, M. Z., Schulz, S. A., Upham, J., De Leon, I., & Boyd, R. W. (2018). Large optical nonlinearity of nanoantennas coupled to an epsilon-near-zero material. Nature Photonics, 12(2), 79-83; 8. Bhupathi, S., Wang, S., Abutoama, M., Balin, I., Wang, L., Kazansky, P. G., Long, Y., & Abdulhalim, I. (2020). Femtosecond Laser-Induced Vanadium Oxide Metamaterial Nanostructures and the Study of Optical Response by Experiments and Numerical Simulations. ACS Applied Materials & Interfaces; 9. Jafari, M., Guo, L. J., & Rais‐Zadeh, M. (2019). A reconfigurable color reflector by selective phase change of GeTe in a multilayer structure. Advanced Optical Materials, 7(5), 1801214; 10. Hong, J., Chan, E., Chang, T., Fung, T. C., Hong, B., Kim, C., Ma, J., Pan, Y., Van Lier, R., Wang, S.G., & Wen, B. (2015). Continuous color reflective displays using interferometric absorption. Optica, 2(7), 589-597; 11. Yao, Y., Waters, J. T., Shneidman, A. V., Cui, J., Wang, X., Mandsberg, N. K., Li, S., Balazs, A. C., & Aizenberg, J. (2018). Multiresponsive polymeric microstructures with encoded predetermined and self-regulated deformability. Proceedings of the National Academy of Sciences, 115(51), 12950-12955; 12. Davidson, E. C., Kotikian, A., Li, S., Aizenberg, J., & Lewis, J. A. (2020). 3D Printable and Reconfigurable Liquid Crystal Elastomers with Light‐Induced Shape Memory via Dynamic Bond Exchange. Advanced Materials, 32(1), 1905682; 13. Morim, D. R., Meeks, A., Shastri, A., Tran, A., Shneidman, A. V., Yashin, V. V., Mahmood, F., Balazs, A. C., Aizenberg, J., & Saravanamuttu, K. (2020). Opto-chemo-mechanical transduction in photoresponsive gels elicits switchable self-trapped beams with remote interactions. Proceedings of the National Academy of Sciences, 117(8), 3953-3959; 14. Waters, J. T., Li, S., Yao, Y., Lerch, M. M., Aizenberg, M., Aizenberg, J., & Balazs, A. C. (2020). Twist again: Dynamically and reversibly controllable chirality in liquid crystalline elastomer microposts. Science Advances, 6(13), eaay5349. KEYWORDS: Metamaterials, phase-change materials, epsilon-near-zero materials, dynamic filters, optics, spatial light modulation, focal plane array, sensors

OBJECTIVE: To develop semiconductor optical amplifiers (SOA), with performances that match or exceed those of Erbium-doped fiber amplifiers, for potential applications in photonic integrated circuits and photonic systems. DESCRIPTION: The Erbium-doped fiber amplifier (EDFA) [1] has been the workhorse in commercial (e.g., long-haul fiber-optic communication systems) and defense (e.g., high power lasers) applications for more than three decades. The reasons for the success of EDFAs are low noise figure, large gain bandwidth, high saturation power, and low polarization dependence. The EDFA is typically pumped by either a 980 nm or a 1480 nm semiconductor laser diode, which already contains an optical amplifier, namely, the semiconductor optical amplifier (SOA). For the last two decades, the photonics industry has tried, in vain, to displace EDFAs by SOAs to reduce the cost as well as SWaP (size, weight and power). One of the main drawbacks of the SOA, in comparison with the EDFA, is its noise figure. Commercial SOA initially had noise figures above 6 dB due to coupling losses from the SOA waveguide to the optical fibers [2]. Recent efforts in reducing the coupling loss has results in SOA noise figures approaching 5 dB [3]. However, EDFAs can routinely maintain noise figures around 4 dB. The disadvantage in noise figure for SOAs is due to the fundamental noise processes of the semiconductor gain medium, and therefore, requires novel solutions to overcome. Another issue with SOAs is the low saturation power. Compared to the EDFA, the active region of the SOA has a cross-sectional area on the order of micron squared whereas the active region of the EDFA has a cross-sectional area on the order of 100 micron squared. To date, commercial SOAs can offer saturation power around 15 dBm, much lower than EDFAs [4]. The third disadvantage of the SOA is its polarization-dependent gain since, naturally, the quantum-well active region favors the transverse-electric mode in the amplification processes [5]. These three disadvantages, however, have not stopped the photonic industry’s pursuits of eventually replacing EDFAs by SOAs. One such recent example is the use of broadband SOAs for digital coherent optical communication, in which one broadband SOA can replace three EDFAs in the S, C, and L band, respectively [6]. Nevertheless, the fundamental disadvantages of the SOA clearly hindered such efforts. For example, the polarization-dependent gain was reduced by using the complicated polarization-diversity configuration, which significantly increase the complexity of the device [6]. The relatively high noise figure also prevented the SOAs from being used for long-haul transmission. If the drawbacks in noise figure, saturation power and polarization sensitivity can be overcome, SOAs can have a tremendous impact on defense and commercial applications. Low-noise, high-power SOAs are extremely desirable in photonic integrated circuits such as RF photonic phased arrays for radars, microwave photonic filters and processors for electronic warfare, as well as high-power direct laser diodes. The purpose of the STTR program is to support the development of novel SOAs that can replace EDFAs at least in certain applications scenarios. PHASE I: To design, fabricate and characterize an SOA with optical gain of up to 20 dB or more with noise figure below 5 dB, saturation power above 20 dBm in the C band. In addition, provide a design that will further reduce the noise figure to below 4.5 dB and polarization-dependent gain to below 2 dB, and increase saturation power to above 27 dBm in the C+L band. Specifically, to formulate novel SOA device structures to reduce the noise figure and increase the bandwidth and saturation power. PHASE II: To design, fabricate and characterize an SOA with optical gain of up to 20 dB or more with noise figure below 4.5 dB, polarization dependence below 2 dB, saturation power above 27 dBm in the C+L band. Demonstrate the application of SOA for analog/digital photonic links and photonic signal processors. In addition, provide a design that will further reduce the noise figure to below 4.0 dB, and increase saturation power to above 30 dBm in the S+C+L band, with low polarization-dependent gain. Production-scale costs of the SOA should be studied to show viability for reasonable cost reduction at manufacturing volumes. Motivation for phase III follow-on investment should be made evident. PHASE III DUAL USE APPLICATIONS: Pursuit system-level defense and commercial applications based upon the SOAs developed in phase II. Clearly identify the advantages of the novel SOAs over EDFAs and other existing SOA structures. The photonic system employing multiple SOAs developed in this program should be integrated at a military installation or on a military platform in potential applications scenarios including but not limited to communications, electronic warfare, sensing and directed energy. Dual-use applications of the SOA in digital coherent fiber-optic communication systems and high-power laser systems are encouraged. REFERENCES: 1. Emmanuel Desurvire, Erbium-Doped Fiber Amplifiers: Principles and Applications, Wiley, New York 1994; 2. Niloy K Dutta and Qiang Wang, Semiconductor Optical Amplifiers (Second Edition), World Scientific, 2013; 3. J. R. Kim et al., "Spot-size converter integrated polarization insensitive semiconductor optical amplifiers," in IEEE Photonics Technology Letters, vol. 11, no. 8, pp. 967-969, Aug. 1999, doi: 10.1109/68.775315; 4. G.P. Agrawal, Fiber-optic Communications Systems, (Wiley, 2010); 5. M. A. Newkirk et al., "1.5 um multiquantum-well semiconductor optical amplifier with tensile and compressively strained wells for polarization-independent gain," in IEEE Photonics Technology Letters, vol. 5, no. 4, pp. 406-408, April 1993, doi: 10.1109/68.212680; 6. Jeremie Renaudier, Amirhossein Ghazisaeidi, "Scaling Capacity Growth of Fiber-Optic Transmission Systems Using 100+nm Ultra-Wideband Semiconductor Optical Amplifiers", Lightwave Technology Journal of, vol. 37, no. 8, pp. 1831-1838, 2019 KEYWORDS: Optical communications, high power laser, Semiconductor Optical Amplifier (SOA), erbium doped fiber amplifier (EDFA), laser diodes

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Develop low-cost, small-size multiple-input multiple-output (MIMO) radar at millimeter-wave frequencies capable of analyzing target micro-Doppler signatures for detection, classification and tracking of unmanned aerial systems (UASs) in highly cluttered environments. DESCRIPTION: Proliferation of UASs, more commonly referred to as drones, is emerging as one of the largest threats to the US Army’s mission. These systems could provide US adversaries with a low-cost means of conducting intelligence, surveillance, and reconnaissance missions against or even attacking US forces. Many small UASs cannot be detected by traditional air defense systems due to their size, construction material, and flight altitude. Conventional microwave systems for detecting small airborne threats, such as counter rocket and mortar (C-RAM) radars, rely on high target speed to reject clutter but face challenges for low, slow, small UASs. The greater Doppler sensitivity and narrower radar beamwidths can be achieved at millimeter-wave (MMW) (30-300 GHz) frequencies could potentially enable detection and resolution of slower objects in more complex terrain. Larger radar bandwidths allow high range resolution, which can facilitate the classification and tracking of slow moving objects. MMW offers additional advantages over optical and infrared parts of the electromagnetic spectrum. MMW has good penetration characteristics in the presence of fog, smoke or dust. Radars are active sensors that operate independently of external lighting and the time of day, allowing day/night/all-weather operation. On the system side, recent advances in low cost RF-CMOS technology have significantly lowered the cost of MMW systems, and enabled the commercialization of these systems such as automotive radars. Building on low power RF-CMOS technology, low cost single-chip collision avoidance radars at 77 GHz have become widely available. Besides offering high range resolution, they also include multiple transmitters and receivers in a single-chip form factor that can be electronically configured into coherent beam forming mode for MIMO (multiple-input, multiple-output) radar mode with enhanced angular resolution. MMW radars operating in MIMO mode are particularly attractive for tracking UASs. A reliable UAS radar system must be able to discriminate quadcopters, fixed-wing drones, from birds and slow-moving ground objects. Micro-Doppler is generated due to the organic motion of the various components within a target, such as propeller blade rotation for a drone or wing flapping for a bird. Because these motions result in distinct time-Doppler-frequency patterns, micro-Doppler is more useful than RCS or bulk speed for unique identification of small UAS targets. Higher frequencies at MMW band could be advantageous by providing better Doppler resolution from ground clutter in a shorter time, therefore reducing the minimum detectable target velocity. When combined with artificial neural networks or other machine learning algorithms, these micro-Doppler features can be used to train a radar to detect and classify an UAS. Despite the potential advantages of MMW radar for counter UAS detection, many challenges exist in hardware and software. Hardware at MMW frequencies remains expensive and low efficiency, resulting bulky systems with high power consumption. Fully utilization of micro-Doppler features will require development in low phase-noise sources as well as classification algorithms that can operate with limited training data. The goal of this STTR topic is overcoming these challenges to achieve systems with both high spatial resolution and classification performance using micro-Doppler extracted from MMW MIMO radar returns. PHASE I: Establish a MMW MIMO radar simulation testbed for detection, classification and tracking of small UASs. Determine system architecture and radar system parameters. Determine radar system hardware specifications and perform trade study between system size, architecture, operating frequency, antenna structure, range, power consumption, etc. Perform design of a prototype radar based on optimized parameters selected from the trade study. Initiate development of signal processing algorithms for the prototype radar. Machine learning techniques are encouraged for processing micro-Doppler signatures for identification and classification of UAS targets. The prototype radar design should demonstrate detection ranges up to 500 m, altitudes between from 10 to 200 ft., and radial speeds between 2 – 10 m/s, and demonstrate simulated classification accuracy > 90% for discrimination of small UAS versus birds, pedestrians, and road vehicles. PHASE II: Improve prototype radar design developed in Phase I and build a hardware prototype based on the improved design to realize a low power MMW MIMO radar testbed for detection, classification, and tracking of small UASs in complex terrain. Integrate radar system hardware, signal processing software, and user display to demonstrate small UAS detection at ranges up to 1 km, altitudes between 10 and 400 ft., and radial speeds between 2 – 30 m/s in government-defined complex terrain. Establish training data requirements to achieve classification accuracy > 95% for discrimination of small UAS versus birds, pedestrians, and road vehicles. Identify promising approaches to extend detection ranges up to 3 km in potential Phase III research. PHASE III DUAL USE APPLICATIONS: A low-cost, small-size MMW MIMO radar for detection, classification and tracking of UASs in highly cluttered environments will fill a critical technology gap for the Army. Phase III commercialization of the compact MMW radar developed in this STTR project, if successful, will provide an effective tool for developing strategies for countering potential hostile UAS threats. Phase III efforts will include ruggedizing the radar package and further capability enhancements such as extending detection ranges. Similarly, the MMW radars can be used for detecting and classify intruding UASs for civilian applications. REFERENCES: 1. J. Wang, Y. Liu, and H. Song, “Counter-Unmanned Aircraft System(s) (C-UAS): State of the Art, Challenges and Future Trends,” arXiv, 2020; 2. R.Z. Syeda, et. al., “Design of a mm-wave MIMO radar demonstrator with an array of FMCW radar chips with on-chip antennas,” Proceedings of the 16th European Radar Conference, 2019; 3. D. Tahmoush, “Review of micro-doppler signatures,” IET Radar, Sonar & Navigation, vol. 9, no. 9, pp. 1140–1146, 2015; 4. S. Rahman and D.A. Robertson, “Radar micro-Doppler signatures of drones and birds at K-band and W-band,” Scientific Report, 8, 17396 (2018) KEYWORDS: RADAR, MIMO, micro-Doppler, millimeter-wave, unmanned aerial systems (UASs)

OBJECTIVE: Develop a breakthrough technology for treating bacterial infections, particularly those associated with multidrug resistant (MDR) pathogens. DESCRIPTION: Bacterial infections are particularly significant for military personnel in situations where there may be a long delay between the injury and treatment at a hospital or clinic. The requirement is for a technology that is readily available in far-forward situations and effective against the ESKAPE pathogens (Enterococcus faecium, Staphylococcus aureus, Klebsiella pneumoniae, Acinetobacter baumannii, Pseudomonas aeruginosa, and Enterobacter species). Of these, Acinetobacter baumannii has been reported among veterans and soldiers who served in Iraq and Afghanistan and has been referred to as “Iraqibacter.” [1] These organisms are the leading cause of nosocomial infections throughout the world. The proposed solution should be safe for users and ideally minimize the potential for organisms to develop resistance. This system could be applied as a bandage or a skin/wound surface treatment to minimize the probability of bacterial infections. Beyond the urgent military need, there is a significant public health requirement for improved antimicrobial wound treatments: there are currently 6.5 million people in the U.S. with chronic wounds or wounds that are slow to heal, according to the U.S. National Institutes of Health [2]. A particularly promising route to a novel antibacterial effective against MDR pathogens is antimicrobial photodynamic therapy (aPDT), also referred to as photodynamic inactivation (PDI). In this process a dye is activated by a light source and interacts with oxygen to produce reactive oxygen species (ROS) with an antimicrobial effect [3, 4, 5, 6]. While many antimicrobial technologies have been investigated, the photodynamic approach has the unique advantage of applying a separate energy source to aid the antimicrobial activity. The ROS are effective against a broad spectrum of species, and this mode of action helps to prevent pathogens from developing resistance. The proposer should identify an effective, portable light source and show how it could be used in far-forward situations. The light-activated approach is potentially limited due to the absorption of light by tissue, and the selected wavelength of light can greatly affect depth of penetration; any response should also address the efficacy against deep wounds. PHASE I: In Phase I the contractor should develop the selected photodynamic system and show through in vitro tests that it is effective against MDR pathogens under the expected conditions. Tests should compare its performance to currently used antibacterial agents and demonstrate a significant and potentially clinically valuable improvement in performance. The target system should demonstrate antibacterial performance against one or more of the target organisms that is at least as good as the current alternatives. A desirable feature of a novel antibacterial system is a mode of action that will slow development of resistance in pathogenic organisms. The performer should identify methods to apply this treatment in both military hospitals and far-forward situations, and estimate the size, weight and cost of the new system. *RESEARCH INVOLVING ANIMAL OR HUMAN SUBJECTS: The SBIR/STTR Programs discourage offerors from proposing to conduct Human or Animal Subject Research during Phase 1 due to the significant lead time required to prepare the documentation and obtain approval, which will delay the Phase 1 award. All research involving human subjects (to include use of human biological specimens and human data) and animals, shall comply with the applicable federal and state laws and agency policy/guidelines for human subject and animal protection. Research involving the use of human subjects may not begin until the U.S. Army Medical Research and Materiel Command's Office of Research Protections, Human Research Protections Office (HRPO) approves the protocol. Written approval to begin research or subcontract for the use of human subjects under the applicable protocol proposed for an award will be issued from the U.S. Army Medical Research and Materiel Command, HRPO, under separate letter to the Contractor. Non-compliance with any provision may result in withholding of funds and or the termination of the award. PHASE II: In Phase II the performer will optimize the new photodynamic system. The breakthrough advantage should be clearly identified. For example, is the new system effective against a particular pathogen or category of pathogens? What is the best method of application? What improvement does the new technology provide over existing systems? Does the new technology provide evidence of user safety? In vitro tests will guide development to a photodynamic formulation and bandage pad composition that is effective against multidrug resistant pathogens of concern. During Phase II the performer should define the final product that will be the focus of further testing and FDA clearance, for example by a 510(k) submission demonstrating safety and efficacy. If the performer chooses to test with animal models, all tests must be in compliance with Institutional Animal Care and Use Committee (IACUC) and Animal Care and Use Review Office (ACURO) guidelines. The final product configuration will be thoroughly evaluated, providing data relevant to both efficacy and ease of use in logistically changing environments. At the conclusion of Phase II the performer will have clearly defined a path to FDA clearance. PHASE III DUAL USE APPLICATIONS: Phase III work is typically oriented towards technology transition to Acquisition Programs of Record and/or commercialization of SBIR research or technology. In Phase III, the performer is expected to seek funding from non-SBIR government sources and/or the private sector to develop or transition the prototype into a viable product or service for sale in the military or private sector markets. The Phase III description must include the "vision" or "end-state" of the research. It must describe one or more specific Phase III military applications and/or supported S&T or acquisition program as well as the most likely path for transition of the SBIR from research to operational capability. Additionally, the Phase III section must include (a) one or more potential commercial applications OR (b) one or more commercial technology that could be potentially inserted into defense systems as a result of this particular SBIR project. For this topic, both military and non-military medical markets should be considered. The Military Infectious Diseases Research Program (MIDRP), which protects the U.S. military against naturally occurring infectious diseases, could support additional R&D. This subject is also in the mission space of the Bacterial Diseases branch at Walter Reed Army Institute of Research, which has identified multidrug resistant bacteria as one of the top ten most significant infectious disease threats to U.S. Service Members. In addition to military medical research teams, there are multiple organizations that may be sources of funding for development beyond Phase II, including the Biomedical Advanced Research and Development Authority (BARDA, in HHS) and the Combating Antibiotic-Resistant Bacteria Biopharmaceutical Accelerator (CARB-X; https://carb-x.org/about/overview/), “a global non-profit partnership dedicated to accelerating antibacterial research to tackle the global rising threat of drug-resistant bacteria.” REFERENCES: 1. CDC (2004). Acinetobacter baumannii infections among patients at military medical facilities treating injured U.S. service members, 2002–2004. MMWR Morb. Mortal. Wkly. Rep. 53, 1063–1066; 2. Intermountain Health Care (2017) “Chronic Wounds Affect 6.5 Million in U.S.” https://intermountainhealthcare.org/blogs/topics/live-well/2017/04/chronic-wounds-affect-65-million-in%20us/#:~:text=Known%20as%20the%20silent%20epidemic,U.S.%20National%20Institutes%20of%20Health; 3. Alves et al. (2015). Potential applications of porphyrins in photodynamic inactivation beyond the medical scope. Jn. of Photochemistry and Photobiology C: Photochemistry Reviews 22, 34–57; 4. Gursoy, H., Ozcakir-Tomruk, C., Tanalp, J. et al. (2013) “Photodynamic therapy in dentistry: a literature review” Clin Oral Invest 17, 1113–1125; 5. Mahmoudi et al. (2018). Antimicrobial Photodynamic Therapy: An Effective Alternative Approach to Control Bacterial Infections. J Lasers Med Science (3):154-160; 6. Yin, R., and M. Hamblin. (2015). “Antimicrobial Photosensitizers: Drug Discovery Under the Spotlight.” Current Medicinal Chemistry. March 2015, DOI: 10.2174/0929867322666150319120134 KEYWORDS: Bacterial infection, multidrug resistant, MDR, ESKAPE pathogen, antibacterial, wound healing

OBJECTIVE: Develop a lightweight Solid Oxide Fuel Cell stack with high power density that is also capable of rapid start up times and high cycle life. DESCRIPTION: In austere environments, power and energy are critical to mission success. A Solid Oxide Fuel Cell (SOFC) has the potential to provide this power from a wide variety of fuels including complex hydrocarbons. However, there is an opportunity to significantly reduce the stack power density and drive down system volume. Currently, 1kW and greater solid oxide stacks are large often with power densities less than 500 W per liter. Research to increase power density is needed to address this limitation. A small lightweight 1 to 3kW solid oxide fuel cell system is desired for a multitude of missions ranging from dismounted solider power to silent watch applications. This technology could be used in a variety of roles including: direct power to Army systems or to charge lithium-ion rechargeable batteries which would significantly reduce the logistical burden (weight and volume) for dismounted soldiers by reducing the number of batteries required for extended mission time as well as for a myriad of civilian electronics applications. PHASE I: Design, construct, and evaluate component and subscale demonstrators. These results should support the potential to develop a system capable of less than 40 minute start times, greater than 2000 W per liter power density, and cyclic durability in excess of 100 cycles. Provide a detailed conceptual design of a 1-3 kW power system based upon the results generated in these efforts. PHASE II: In phase II, based on the results from the successful phase I program, design, construct, and evaluate a 1-3kW brass-board Solid Oxide Power System exceeding 3000 W per liter with a start time below 30 minutes. Demonstrate capability to power cycle in excess of 100 times. Deliver brass-board unit to the Army for evaluation. Assess cost and manufacturability of demonstrated technology. PHASE III DUAL USE APPLICATIONS: Robust SOFC power systems with high power densities will significantly impact both military and commercial applications, accelerating product development, particularly for lightweight portable power devices. Because the market and the number of devices in the commercial sector is much larger than the military market, widespread usage of this technology will drive down the cost of devices for the military. Demonstrate Solid Oxide Power System under field conditions in order to assess applicability to various mission profiles. Demonstrate compatibility with JP-8. Likely sources of funding if the phase III program if successful include: C5ISR, PEO Soldier and PEO Combat Support and Combat Service Support Product Manager Mobile Electric Power Systems. REFERENCES: 1. Norbert H. Menzler, Wolfgang Schafbauer, Feng Han, Oliver Büchler, Robert Mücke, Hans Peter Buchkremer, Detlev Stöver, Development of High Power Density Solid Oxide Fuel Cells (SOFCs) for Long-Term Operation, Materials Science Forum, ISSN: 1662-9752, 2010, Vols. 654-656, pp 2875-2878; 2. Thomas L. Cable, Stephen W. Sofie, A symmetrical, planar SOFC design for NASA's high specific power density requirements, Journal of Power Sources, Volume 174, Issue 1, 22 November 2007, Pages 221-227; 3. A. Boudghene Stambouli, E. Traversa, Solid oxide fuel cells (SOFCs): a review of an environmentally clean and efficient source of energy, Renewable and Sustainable Energy Reviews, 6 (2002) 433–455 KEYWORDS: SOFC, Fuel Cell, Power Density

OBJECTIVE: Develop a small, portable, low power field device that can estimate the strength and thickness, to 6 feet, of reinforced concrete structures and identify and locate metal contained therein. DESCRIPTION: Reinforced concrete structures impede the movement of military personnel in a variety of military missions. Non-destructive evaluation (NDE) of the structural characteristics (e.g., material strength, level of reinforcement, thickness) of these structures is important for calculating the amount of charge that must be placed to breach the structure. NDE remains an application requirement in order for missions to remain stealthy. Several techniques have been considered for NDE of reinforced concrete in order to test for defects and deterioration. Techniques such as ultrasound require a transmitter probe that presents short duration high voltage pulses into piezoelectric crystals, and their expansion produces a pressure pulse that administers a broadband field into the concrete. Such systems can be large, require significant power, and are expensive, rendering them impracticable for tactical applications. Conversely, ground penetrating radar is another NDE technique that has also been used extensively to interrogate concrete that may overcome these deficiencies. Currently there are no methods when combined and simple to use to close this need for breaching. While concrete can withstand significant compressive stresses, its tensile strength is approximately an order of magnitude smaller than the compressive strength. Historically, this issue has been addressed by reinforcing concrete with reinforcing bars, rebar, and/or fibers to improve tensile strength. Recent advances in manufacturing high strength concrete mixes, such as those by Lafarge, have rendered current approaches to assessing strength and thickness of concrete (and thus charge size) less accurate. A simple, low power, small and accurate alternative utilizing ground penetrating radar (GPR) technology is sought. GPR has commonly been used for interrogating the ground in a nondestructive fashion in order to assess the presence of objects of interest (landmines, pipes, IEDs) buried below the surface. There are several geophysical companies who utilize GPR for a variety of interrogation applications, including locating rebar in concrete to aid excavation, location of utilities and pipes, forensics and graveyard surveying, etc. The proposed concept for structural assessment of reinforced concrete must operate in a variety of conditions with high accuracy and rapid analysis time. Systems that leverage currently fielded Army systems are preferred, and a detailed proof of concept plan is critical. PHASE I: Develop the hardware and software design that supports the interrogation technology needed to estimate relevant structural parameters such as reinforced concrete thickness—up to six feet, concrete strength over a range of 3,000 to 30,000 psi, density of reinforcement, and presence of fiber reinforcement. In addition, the approach should be able to locate metal substructure. The approach should demonstrate the ability to estimate these parameters in controlled proof-of-concept experiments with an accuracy of one foot in thickness and +/- 3,000 psi in strength over a variety of structures. In addition, the impact of reinforcement additives such as composite or metallic fiber should be assessed and design issues to address any confounding issues should be put forth. Power consumption and estimated system weight must also be addressed and should be within a factor of two of similar Army deployed equipment. The existence of metal objects should be detected and located to =/- one foot on the wall surface and the density of reinforcement and fiber-reinforcement estimated. PHASE II: Develop and field test the proposed system for estimating relevant structural parameters and metal substructure. Optimize the design and algorithms for performance, weight, and power consumption. Develop and engineer hardware and software to meet program goals. Conduct field-testing to validate performance on a variety of representative structures to assess accuracy, time-of-measurement, and identify potential operational limitations of the final hardware. Preference should be given to extending the capability of already deployed Army systems to support multiple functions. PHASE III DUAL USE APPLICATIONS: Describe the "vision" or "end-state" of the research. Include one or more specific Phase III military applications and/or supported S&T or acquisition program as well as the most likely path for transition of the SBIR from research to operational capability. Additionally, the Phase III section must include (a) one or more potential commercial applications OR (b) one or more commercial technology that could be potentially inserted into defense systems as a result of this particular SBIR project. The proposed technology has potential use in numerous applications within the Department of Defense and the commercial sector. The technology could be used for the Department of Homeland Security as well as state and local authorities, and potentially HAZMAT response teams. REFERENCES: 1. ASTM C 1383-04, “Standard Test Method for Measuring the P-Wave Speed and the Thickness of Concrete Plates Using the Impact Echo Method”; 2. Pristov, E., Dalton, W., Piscsalko, G., and Likins, G. “Comparison of Impact-Echo with Broadband Input to Determine Concrete Thickness.” Proc. NDE Conf. on Civil Engin., August, 2006; 3. www.geophysical.com; 4. www.groundradarcarolina.com KEYWORDS: Ground Penetrating Radar, Concrete Characterization, IED Detection, Mine Detection

OBJECTIVE: Develop a novel Frequency Modulated Continuous Wave (FMCW) (RADAR) hand-held device with wire as the wave guide approach detecting, locating, classifying, and predicting electrical cables faults. DESCRIPTION: BACKGROUND: The US Army is currently developing a Frequency Modulated Continuous Wave (FMCW) [RADAR technology] hand-held architecture and tool for detection and localization of simple faults in multi conductor cables. Those simple faults include open and short circuits and deterioration such as corrosion. However, the current FMCW tool is not intended to be capable of predicting future faults. This STTR should 1) complement and capitalize on; and, 2) be distinct from the current FMCW tool. Complementary – this STTR shall complement the current FMCW by employing current FMCW work and architecture, while extending that architecture framework to enable statistical analysis of cables of different types and sizes. Distinct – this STTR shall be distinct from the current FMCW tool by predicting future faults in cables and analyzing complex types of cable degradation to allow for Prognostic and Predictive Maintenance (PPMx) capabilities. PROBLEM: The current standard operating procedures for cable fault detection and diagnosis are unable to detect, locate, and classify intermittent faults and corrosion in electrical wiring and connectors. They require invasive techniques to access, remove and/or disassemble the weapon system under test and analysis, and requires significant power and test equipment for this limited task. Many types of faults are hard to identify and replicate using these procedures and equipment, which leads to frequent “No-Fault-Found” test results in weapons system cable bundles (e.g., radar, intermediate missile, and aircraft). EFFORT: The goal is to capitalize and extend existing efforts and to develop test set consisting of a low power handheld unit suitable for one-person operation, displays measurement results for viewing by its operator, and records and preserves data for transmission and/or download to maintenance facility computers. The unit must be ruggedized for Army fielded operations in its final prototype form. This STTR shall focus on the development of advanced software techniques and data analytics/machine learning (ML) algorithms to predict and recognize wire deterioration, determine what faults may occur, and determine remaining useful life. DELIVERABLES: Written reports, initial and final designs/schematics, prototypes, demonstrations, control software, prediction algorithms, expected system quality parameters (probability of detection [POD], level of confidence), and, transition and commercialization plans.   PHASE I: EXPECTATIONS: (1) Conduct research and develop, (2) report in a white paper, (3) evaluating the use of FMCW signal processing as the primary analysis tool in comparison with alternative radar processes. Identify, craft, and develop initial algorithms, and conduct a simple laboratory demonstration, focused initially on the case of a single wire-pair cable and progressing, as time permits, to more complex wire configurations and cable assemblies. FEASIBILITY: The whitepaper must demonstrate the potential benefits and the shortfalls of research findings, including power, frequency, and signal-to-noise ratios for success, as well as, a novel approach to detection of potential failures, particularly those that could result from kinks, fractures, breaks, and corrosion. Evaluate the potential of analysis based on FMCW radar measurements to predict life expectancy in multi-conductor cables. RESULTS: (1) A white paper capturing all efforts, (2) an initial laboratory design schematics, (3) a demonstration of results; (4) preliminary control software and prediction algorithms; (5) discussion of expected system quality parameters (probability of detection [POD], level of confidence) that will affect the fault detection, characterization and prediction device during Phase II; and, (6) technical and commercial feasibility analysis. FMWC technology is shareable with academics in the STTR effort with appropriate Non-Disclosure Agreements (NDAs), as needed, to protect Intellectual Property. FMCW is a very well known technology for terrestrial imaging, and all aspects of fine tuning the FMCW RADAR for maximum SNR to include "no noise" wave guides. However, FMCW has not been investigated for wire fault detection where the wave guide (the wire) is potentially very noisy. PHASE II: EXPECTATIONS: Specify and develop a hand-held engineering prototype with software algorithms to be evaluated within a controlled environment to detect actual and potential cable failures. Conduct detailed investigations into the capabilities and limitations of the prototype design, to include empirical effects of equipment operating frequency, cable frequency response, wire size, and insulation properties. Perform data analysis on multiple cables of different conductor types and numbers of conductors to determine the variability of measurement results as functions of the cable characteristics. DELIVERABLES: (1) A hand-held prototype demonstrating various fault detection with high POD and high level of confidence (as expected of tactical military equipment), (2) a report documenting all Phase II activities to include but limited to, new research findings, software builds in executable and raw uncompiled form in a common programming language, and preliminary transition and commercialization plans. PHASE III DUAL USE APPLICATIONS: VISION: Work with PEO Aviation Ground Systems and PEO Missiles and Space to identify both peculiar common and specific system requirements for inclusion in a fully engineered ruggedized prototype to address commercial and military safety, health and human factors concerns, as well as perform information assurance (IA) and software qualification testing to be able to operate within the Army digital environment and validate the system functionality for Army rotor craft and/or ground weapon programs of record. The Program Management Offices would be ready to procure limited production units for first article environmental and field operational testing proving its readiness for fielding. Provide training for the user based community to include user manuals and functional guides. Successful technology development and transition would benefit the electrical and communication industry as a whole providing the private sector with a tool to perform expedient fault isolation on multi conductor cables. Other potential applications include other DOD departments with multi-conductor cables, other USG Agencies, commercial industries such as aviation, telecom, automotive, and other automated systems using single or multi-conductor cables. REFERENCES: 1. Sub-cycle detection of incipient cable splice faults to prevent cable damage; Kojovic, L.A.; Williams, C.W., Jr.; Power Engineering Society Summer Meeting, 2000. IEEE Volume 2, 16-20 July 2000; 2. Application of thermoelectric aging models to polymeric insulation in cable geometry; Cooper, E.S.; Dissado, L.A.; Fothergill, J.C.; Dielectrics and Electrical Insulation, IEEE Transactions on [see also Electrical Insulation, IEEE Transactions on] Volume 12, Issue 1, Feb. 2005; 3. Merrill Skolnik, Radar Handbook, 3rd Edition, McGraw Hill, 2008; 4. E. Cabanillas, C. Layer and M. Kafal, "On the phase analysis of multi-carrier signals for high-precision fault detection by reflectometry,"2017 IEEE SENSORS, 2017, pp. 1-3, doi: 10.1109/ICSENS.2017.8234182; 5. C. -K. Lee and Y. -J. Shin, "Detection and Assessment of I&C Cable Faults Using Time–Frequency R-CNN-Based Reflectometry," inIEEE Transactions on Industrial Electronics, vol. 68, no. 2, pp. 1581-1590, Feb. 2021, doi: 10.1109/TIE.2020.2970677; 6. Y. Ohki and N. Hirai, "Detection of abnormality occurring over the whole cable length by frequency domain reflectometry," inIEEE Transactions on Dielectrics and Electrical Insulation, vol. 25, no. 6, pp. 2467-2469, Dec. 2018, doi: 10.1109/TDEI.2018.007344 KEYWORDS: 1) Frequency Modulated Continuous Wave (FMCW) RADAR, 2) Fault Diagnosis, 3) Prognostics, 4) Cable Characteristics, 5) Data Analytics, 6) Machine Learning (ML), 7) Radio Frequency (RF) Transmission Lines, (8) Wave Guide analysis, (9) Artificial Intelligence (AI)

OBJECTIVE: Investigate and develop meta-optic elements that perform mathematical transformations to reduce latency and power requirements using artificial intelligence algorithms for autonomous target recognition. DESCRIPTION: Computer vision-aided Autonomous Target Recognition (ATR) is an important DoD modernization priority that helps extend and enhance human capabilities. Current technologies employ advanced artificial intelligence and machine learning (ML) algorithms for feature generation and object classification. In pursuit of increased accuracy, state-of-the-art models have become increasingly complex, thereby introducing latency into the system. For many applications, some degree of latency is acceptable. However, there is an emerging set of operations where latency reduction is paramount as the decision-making process is currently too slow for autonomous systems to respond appropriately. This is especially true when dealing with complex environments and extremely fast-moving objects such as hypersonic vehicles. One solution for reducing latency is to offload some of the mathematical operations from the processor to the optics. For example, optical analog computation can be used to perform Fourier filtering for image contour detection. This operation produces an image directly on the focal plane that is composed only of contours, effectively performing an image differentiation calculation at the speed of light without any computational expense. In general, optical analog computation performs pre-processing steps that compress the image data and enable ML model solutions with fewer coefficients and lower latency compared with models used on raw data. One drawback of conventional optical analog systems is that they require bulky lenses and large volumes that are not suitable for SWAP-constrained platforms. A promising option to replace conventional optical elements and reduce SWAP is to employ ultra-thin meta-optic devices. Meta-optics, in contrast to bulky refractive optics, produce customized optical functions using subwavelength scatterers that provide abrupt spatially varying phase shifts. By engineering the geometry and arrangement of scatterers, meta-optics can be designed to perform complex mathematical transforms on the incoming light. When applied to ATR algorithms, these meta-optic operators could provide orders of magnitude reduction in latency while maintaining low size, weight, and power requirements for ATR platforms. In this program, the Army seeks to partner with a small business and university participant to investigate and develop meta-optic elements for optical analog computation. These elements will perform the computationally expensive operations of ATR algorithms, leading to significantly reduced latency and power requirements. Results from this effort would support a number of DoD programs and general performance objectives for the optical element include low SWAP, large bandwidth, low f-number, and high efficiency. PHASE I: Design a thin (<1mm) meta-optic device operating in the infrared (MWIR or LWIR) that performs a spatial differentiation operation. Use modeling and analysis to understand the tradeoffs of key meta-optic parameters, which include but may not be limited to bandwidth, field of view, polarization, speed, and efficiency. Fabricate a preliminary meta-optic device and perform imaging experiments to demonstrate feasibility of the design concept, and show a viable path to meeting Army program requirements. PHASE II: Explore more complex meta-optic architectures using innovative design methodologies such as inverse design. Develop a meta-optic device that is paired with a computational algorithm for an advanced prototype demonstration. Demonstrate path to manufacturing meta-optics at production quantities. Deliver advanced prototype to Army customer for further testing and evaluation. PHASE III DUAL USE APPLICATIONS: Design and manufacture meta-optics applicable to specific Army programs. Transition technology to commercial markets where faster artificial intelligence algorithms as well as lower weight and power are important. Some examples include autonomous vehicles, biotechnology, security, and agriculture. REFERENCES: 1. Solli, D., Jalali, B. Analog optical computing. Nature Photonics 9, 704-706 (2015); 2. Zangeneh-Nejad, F., Sounas, D., Alu, A., Fleury, R. Analogue computing with metamaterials. Nature Reviews Materials 6, 207-225 (2021) KEYWORDS: Meta-optics, Optical analog computation, Artificial intelligence, Flat optics

OBJECTIVE: Develop extremely sensitive complementary metal-oxide-semiconductor (CMOS) compatible focal plane array (FPA) technology for imaging in the near-infrared (NIR) band. DESCRIPTION: Current image intensifier (I2) goggle technology for man-portable applications is bulky in size and weight, and does not lend itself to being fused with other solid state sensors, such as shortwave infrared (SWIR), midwave infrared (MWIR) and/or longwave infrared (LWIR). Conventional silicon charge coupled devices (CCDs) and CMOS imagers have not demonstrated passive low light imaging capabilities under heavy overcast starlight levels (approx. 1x10-6 fL). For passive low light level imaging, the signal must be maximized and noise minimized. This topic seeks to develop extremely sensitive CMOS compatible FPAs capable of detecting a signal in the NIR in heavy overcast starlight conditions. To achieve performance comparable to Gen III I2 goggle technology, the solid state technology must be capable of high gain with low excess noise (high signal to noise ratio), high quantum efficiency, and low dark current at ambient temperatures. Solutions should optimize the quantum efficiency (QE) in the NIR from 0.7-1.0µm. NIR imagers that are sensitive beyond 1.0µm (into the SWIR) are encouraged. Size, weight, and power (SWaP) should be taken into account in the final imager solution. Novel device architectures are encouraged; uncooled devices are preferred. PHASE I: Design a sensor optimized to operate in the NIR spectral region, from 0.7-1.0µm, that is capable of detecting a signal in low light conditions, down to approx. 1x10-6 fL. Deliver a preliminary design that demonstrates technical feasibility through design, modeling, and analysis. A kick-off meeting should be held with the Government; monthly progress reports and a final report at the end of Phase I should be submitted. PHASE II: Produce the sensor solution designed in Phase I and integrate it into a prototype imager system, taking into account SWaP. Imagers should be useable in the field (i.e., there should be a means to keep out dust, moisture, etc.), but need not to be ruggedized. Technical reviews should be held with the Government; monthly progress reports and a final report at the end of Phase II should be submitted. Deliver the prototype imager system to the Government, and be available to support at least one field event to observe low light imaging performance. PHASE III DUAL USE APPLICATIONS: Refine imager developed in Phase II into a ruggedized package for military and/or commercial applications. Military applications can include Soldier worn or weapon mounted systems, as well as small autonomous platforms, such as unmanned ground or air vehicles. Nonmilitary commercialization opportunities would include security and surveillance applications. REFERENCES: 1. Bruschini, Claudio & Burri, Samuel & Lindner, Scott & Ulku, Arin & Zhang, Chao & Antolovic, Ivan Michel & Wolf, Melany & Charbon, Edoardo. (2018). Monolithic SPAD Arrays for High-Performance, Time-Resolved Single-Photon Imaging. 1-5. 10.1109/OMN.2018.8454654; 2. Hynecek, Jaroslav. (2001). Impactron - A new solid state image intensifier. Electron Devices, IEEE Transactions on. 48. 2238 - 2241. 10.1109/16.954460; 3. Liu, Yu-Hsin & Yan, Lujiang & Zhang, Alex & Hall, David & Niaz, Iftikhar Ahmad & Zhou, Yuchun & Sham, L. & Lo, Yu-Hwa. (2015). Cycling Excitation Process: An Ultra Efficient and Quiet Signal Amplification Mechanism in Semiconductor. Applied Physics Letters. 107. 053505. 10.1063/1.4928389; 4. Ma, Jiaju & Masoodian, Saleh & Starkey, Dakota & Fossum, Eric. (2017). Photon-Number-Resolving Megapixel Image Sensor at Room Temperature Without Avalanche Gain. Optica. 4. 1474. 10.1364/OPTICA.4.001474; 5. Yan, Lujiang & Yu, Yugang & Zhang, Alex & Hall, David & Niaz, Iftikhar Ahmad & Raihan Miah, Mohammad Abu & Liu, Yu-Hsin & Lo, Yu-Hwa. (2017). An Amorphous Silicon Photodiode with 2 THz Gain‐Bandwidth Product Based on Cycling Excitation Process. Applied Physics Letters. 111. 101104. 10.1063/1.5001170 KEYWORDS: NIR, infrared, imaging, camera, low light, photon counting

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Develop solid state and/or ionic liquid electrolytes that promote safe operation at high voltage and enable superior gravimetric energy density (Wh/kg) when incorporated into high voltage lithium-ion batteries. DESCRIPTION: Solid-state (SSE) and ionic liquid (IL) electrolytes are promising technologies for incorporation into future generations of LIBs. These forthcoming electrolytes can accommodate greater electrochemical stability with increasing voltage, empowering safe engagement of high voltage materials. Development of battery cells with high operating voltage will augment energy and power densities of future lithium-ion batteries, as expressed by Ohm’s law. Increased energy densities will prolongate battery run times or permit smaller batteries capable of comparable mission profiles, minimizing battery weight. Emphasis on these research areas is being proposed now due to the development, which we now know can achieve 5V cell voltages, leading to an opportunity to further enhance the military battery portfolio. Cells of higher operating voltages will also allow simultaneous utilization of electronics, benefitting large platform integration. Successful improvement of SSE and IL at high voltages would assist U.S. Army modernization priorities of Soldier Lethality, Future Vertical Lift, Next Generation Combat Vehicle, and Long Range Precision Fires. Incumbent LIBs fail to assuage the safety requirements for future soldier and vehicle platforms. Solid-state (inorganic solids, composites, polymers, etc.) and ionic liquid electrolytes exhibit improved safety compared to standard carbonate electrolytes due to amelioration of flammability and electrochemical stability issues when paired with lithium-metal anodes. Solid-state electrolytes, have potential to suppress detrimental lithium dendrite formation and provide desired mechanical and thermal stability. Safe electrolytes that enable safe operation with lithium metal anodes at high voltages will forge energy density improvements of 200-250%. Challenges to implementation include charge transfer impedance at the electrode-electrolyte interface that must be mitigated to promote rapid and reversible charge transfer. A feasible solution is the development of an artificial SEI layer to promote accelerated ion diffusion. Polymer electrolytes may exhibit poor adhesion to the solid electrode causing reduced electrolytic penetration into the electrodes, which proliferates resistance. Adding liquid electrolytes to counteract this process is effective but eliminates the safety advantages of the solid electrolytes and is not considered as a solution for this proposal. Additional hindrances for successful utilization of these electrolytes are ionic conductivities of electrolytes at room temperature and below. Electrolyte ionic conductivity is affected by temperature dependence of the viscosity of ionic liquids. The Army requires dependable operation of energy storage devices between -30°C and +55°C. Therefore, enhancing the ionic conductivity of these electrolytes for low temperature operation through use of additives or improved overall design is an additional research objective. Design goals for the resultant cells are listed below. Carbonate electrolytes will not be considered. Proposed improvements to high internal resistances and poor ionic conductivity, and strategy for enabling high voltage operation must be expressed in full detail. Cells must: • Contain lithium-metal anode • Contain solid-state (inorganic solids, composites, polymers, etc.), ionic liquid electrolytes, or safe electrolytes • Operate at high voltage with complete discharge redox behavior occurring above 4.6V • >100 cycles with >80% capacity retention • Cell energy densities > 350 Wh/kg at room temperature • >75% capacity retention at 0 °C with respect to room temperature capacity PHASE I: Design a concept cell for solid state or ionic liquid electrolyte that optimizes gravimetric energy density (>350 Wh/kg) at elevated discharge voltages (with complete discharge redox behavior occurring above 4.6V) and prolonged cycle life above 80% capacity retention. Carbonate electrolytes will not be considered. Phase I deliverables include monthly progress reports describing all technical challenges, technical risk, and progress against the schedule, a final technical report, and 10 laboratory cells (coin or pouch cells) to the U.S. Army for testing. PHASE II: Refine and optimize cell level materials selected in phase I and develop and deliver coin or pouch cells to meet target performance requirements of high voltage operation with complete discharge redox behavior occurring above 4.6V, >350 Wh/kg (cell), 100 cycles > 80% capacity retention at room temperature, and 75% capacity retention at 0 °C with respect to room temperature capacity. Additional optimization with the target of expanding the rate capability of these cells will also be included in phase II. Required phase II deliverables will include 20 cells (coin or pouch), as well as monthly progress reports and a final report. PHASE III DUAL USE APPLICATIONS: Transition this technology to prototype cells of suitable size for packaging and assembly into batteries for soldier carried applications and, upon further testing, inclusion in future Army vehicles such as Future Vertical Lift and Next Generation Combat Vehicle. The product for phase III is multilayered pouch cells with capacities > 2 Ah to be included in future batteries. REFERENCES: 1. Dong, T., Zhang, J., Xu, G., Chai, J., Du, H., Wang, L., ... & Cui, G. (2018). A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery. Energy & Environmental Science, 11(5), 1197-1203; 2. Cho, J. H., Park, J. H., Lee, M. H., Song, H. K., & Lee, S. Y. (2012). A polymer electrolyte-skinned active material strategy toward high-voltage lithium ion batteries: a polyimide-coated LiNi 0.5 Mn 1.5 O 4 spinel cathode material case. Energy & Environmental Science, 5(5), 7124-7131; 3. Zhu, Y. S., Wang, X. J., Hou, Y. Y., Gao, X. W., Liu, L. L., Wu, Y. P., & Shimizu, M. (2013). A new single-ion polymer electrolyte based on polyvinyl alcohol for lithium ion batteries. Electrochimica Acta, 87, 113-118; 4. Xiang, J., Wu, F., Chen, R., Li, L., & Yu, H. (2013). High voltage and safe electrolytes based on ionic liquid and sulfone for lithium-ion batteries. Journal of power sources, 233, 115-120; 5. Seki, S., Kobayashi, Y., Miyashiro, H., Ohno, Y., Usami, A., Mita, Y., ... & Terada, N. (2006). Highly reversible lithium metal secondary battery using a room temperature ionic liquid/lithium salt mixture and a surface-coated cathode active material. Chemical Communications, (5), 544-545; 6. Wu, F., Zhu, Q., Chen, R., Chen, N., Chen, Y., & Li, L. (2015). Ionic liquid electrolytes with protective lithium difluoro (oxalate) borate for high voltage lithium-ion batteries. Nano Energy, 13, 546-553 KEYWORDS: Energy Storage, Polymer Electrolytes, Ionic Liquid electrolytes, High Energy Density, Improved Safety, Soldier Lethality, Future Vertical Lift

OBJECTIVE: Develop and demonstrate a hardware/software approach for Positioning, Navigation and Timing (PNT) using Low Earth Orbiting (LEO) satellites as a component in the context of the PNT Operating System (pntOS). DESCRIPTION: The near term expansion of internet service to include commercial broadband low earth orbiting (LEO) satellites provides a potential for robust PNT, using their waveforms as Signals of Opportunity (SOOP). Unlike Global Navigation Satellite Systems (GNSS), such as GPS, which has an infrastructure to maintain very precise time throughout the constellation, and satellites with specially designed transmitters, clocks, and a waveform dedicated to the PNT function, SOOPs by their nature are in space for another purpose and not optimized for PNT. Therefore, the challenge for this topic is to exploit features of the SOOP waveforms designing innovative techniques in order to establish range to satellites and henceforth provide the user with the dismount/platform’s position and current time (desired). The technology developed under this topic will result in an approach for LEO-PNT that is intended for dismounted Soldiers and Mounted vehicular applications, but may have further applications to aerial, munition and missile applications. The design will use a software defined receiver approach and be capable of incorporation as a component in the context of the Army’s pntOS program enabling maximum application. This technology although designed to work standalone can be used to complement existing navigation sensors that are typically used in navigation systems, including GPS. Expansion to the usage of multiple constellations will serve to optimize performance and resiliency in an RF challenged environment. LEO satellites closer proximity to Earth and signal structures can allow for higher signal powers to reach the end user. Investigations conducted under this topic will include technical design approaches that will improve PNT performance (position and timing (desired) accuracy) and also the ability to operate in RF challenged environments such as dense urban, mountainous, forested and jungle environments. It’s recognized that many implementations of SOOPs use reference stations in surveyed/fixed based locations. For most Army applications reference stations are undesirable due to the logistics burdening associated with manning the station, redeploying it as the unit maneuvers from location to location, emplacement/survey of the station to support operations and the required command and control for the system. A goal of this program is to develop a LEO PNT SOOP technical approach that will not require a reference station. However, cooperative PNT methods that share information using networks sharing information between unit platforms/members is encouraged. However, caution is required not to over burden the network. Metrics that will be assessed include position and time (desired) accuracy, availability of service (analyzed across the earth), bandwidth usage of a network, Size, Weight and Power (SWAP), complexity associated with system initialization and overall set up time. PHASE I: Develop a design for the LEO-PNT system architecture. Determine requirements and conduct a hardware and software functional allocation for the system. The intended system at a minimum will be relevant to operations for dismounted Soldiers and Mounted. Develop system error budgets supporting the performance metrics, providing allocations to the various elements of the system design, transmission medium, local environment, and selected SOOPs, for supporting operations for the intended applications. Conduct necessary trade studies and modeling and simulation that will contribute to the architecture definition, determine feasibility and reduce risk in Phase II. The primary product of Phase I will be a system specification for LEO PNT and how it can be integrated with existing navigation systems. PHASE II: Design and build a system prototype that is capable of supporting demonstrations by dismounted Soldiers and in Mounted as a “plug n play” capability for incorporation within the Army pntOS. The initial prototype may be scaled in terms of capacity (numbers of compatible LEO SOOP constellations, minimum for Phase II will be 2), but it should be proven that full scale operation is feasible with the resulting design. Use cases to be demonstrated are dismounted Soldier and Mounted, proving sufficient PNT capability in open range, forested/jungle, and urban. Metrics mention in the Description will be evaluated. PHASE III DUAL USE APPLICATIONS: This topic has the potential to scale and continue to grow and support the entire Army (perhaps DOD) PNT ecosystem. Continued development and refinement of the system will be further expanded in terms of compatibility with additional SOOP constellations, and improvements made through cooperative sharing of information. This capability could easily be accommodated to a commercial capability supporting non-military functions, for virtually an unlimited number of applications. REFERENCES: 1. Fused Low-Earth-Orbit GNSS, Peter A. Iannucci and Todd E. Humphreys, Radionavigation Laboratory The University of Texas at Austin; 2. Performance Evaluation of Navigation Using LEO Satellite Signals with Periodically Transmitted Satellite Positions; Christian T. Ardito, Joshua J. Morales, Joe J. Khalife, Ali A. Abdallah, and Zaher M. Kassas, University of California, Irvine; 3. Navigation using Carrier Doppler Shift from a LEO Constellation: TRANSIT on Steroids; Mark L. Psiaki, Virginia Polytechnic Institute and State University; 4. Leveraging Commercial Broadband LEO Constellations for Navigation: Tyler G. R. Reid, Andrew M. Neish, Todd F Walter, & Per K. Enge KEYWORDS: Positioning, Navigation and Timing (PNT), Assured Positioning, Navigation and Timing (APNT), Low Earth Orbiting (LEO), Army PNT Operating System (pntOS), Signals of Opportunity (SOOP)

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Develop an ultra-broadband IR source for countermeasures capable of disrupting and/or disabling optical/IR guiding sensors in targets. DESCRIPTION: For directional IR countermeasures (IRCM) applications, generating high-average power, pulsed IR radiation with an ultra broad and uniform spectrum is highly desirable. The IR atmospheric transmission window of interest is in the range of ~8 – 13 um, i.e. long-wave IR (LWIR) and ~2 – 5 um, mid-wave IR (MWIR). In these spectral regimes, the IR radiation can be generated at the source and propagated to the target to disrupt its optical/IR sensors. However, there is a lack of suitable high-power sources in the MWIR and LWIR. High-average power, ultra-broad band radiation in this spectral regime can be generated by the spectral broadening and/or nonlinear parametric amplification of laser radiation in an appropriate nonlinear, lossless, material. Ultra-broad band radiation is generated from a laser pulse by a number of coupled highly nonlinear optical processes that include: i) self-phase modulation, ii) 4-wave mixing, iii) cross-phase modulation, iv) stimulated Raman scattering, and others. These mechanisms can lead to wide spectral broadening around the fundamental and other frequencies that may cover the MWIR and LWIR regimes with high overall conversion efficiencies. In addition, the IR radiation could have a high degree of directionality and thus can be propagated long distances within a small solid angle using an appropriate beam director. This topic seeks solutions that eliminate threats through the disruption of a target's optical control systems rather than destroying the target by thermal disruption mechanisms. Novel laser configurations, such as laser pulse formats and bandwidth manipulations that would generate ultra-broadband MWIR and LWIR radiation are of interest. The pump (source) lasers that generate the wideband radiation should be compact, reliable and commercially available. Proposed systems should be capable of disrupting IR sensors within the engagement time window, at tactically relevant ranges.   PHASE I: The offeror will theoretically/computationally and experimentally demonstrate the feasibility of remotely disrupting or disabling optical/IR sensors representative of those found in military targets at relevant ranges (greater than 1 km). By "disruption", it is meant that the device sensors are temporarily disrupted or permanently disabled so that the target cannot perform its mission. Theoretical studies and/or modeling to understand the phenomenon employed and/or beam director design characteristics as appropriate to the proposed solution should be included. The deliverable for Phase I will be the design of a system that will be constructed and tested in Phase II. PHASE II: The offeror will construct and deliver a system that can apply broad band, high average power, directional IR radiation on a remote target such that the target's optical/IR sensors are disrupted or permanently disabled. No specific target is necessary for a proposal to be of interest, however it must be demonstrated that the technique can be applied to targets of military relevance. A system with a capability of disrupting or disabling military targets beyond 1 km is desired. A plan for scaling the capability to longer ranges is also highly desirable. The offeror should also demonstrate - through theory, modeling or experiment – the extent to which the system may disrupt or disable targets greater than 1 km away. The deliverable for Phase II will be a functional prototype of the system design proposed in Phase I. The prototype will be utilized to gather test data and generate a test report demonstrating the application to optical/IR sensors. PHASE III DUAL USE APPLICATIONS: The offeror will outfit the DE countermeasures system with subsystems to identify, acquire, track, and defeat targets. The overall system must be rugged and mobile. The offeror will demo the system in a field test in an operationally relevant environment. Field tests are to be carried out using various types of targets representative of those employed in the military at tactically relevant ranges greater than 1 km. The deliverable for Phase III will be the functional prototype developed in Phase II integrated with acquisition/tracking subsystem. The integrated system will be utilized to gather test data and generate a test report demonstrating application to optical/IR sensors at relevant range. REFERENCES: 1. P. Sprangle, A. Ting, E. Esarey, R. Hubbard and B. Hafizi, “Active remote sensing using ultra broadband radiation”, NRL Memo Report # 7885, (1996); 2. C.A. Kapetanokos, B. Hafizi, H.M. Milchberg, P. Sprangle, R.F. Hubbard, and A. Ting, “Generation of High-Average-Power Ultrabroad-Band Infrared Pulses”, IEEE J. Quantum. Electronics, 35, 565 (1999); 3. C.A. Kapetanakos, B. Hafizi, P. Sprangle, R.F. Hubbard, and A. Ting, “Progress in the Development of a High Average Power Ultra-Broadband Infrared Radiation Source”, IEEE J. Quantum. Electronics, 37, 641 (2001); 4. G. P. Agrawal, “Nonlinear Fiber Optics”, San Diego, CA: Academic, 1995; 5. P. Sprangle, J. R. Penano and B. Hafizi, “Propagation of intense short laser pulses in the atmosphere”, Phys. Rev. E 66, 046418 (2002); 6. N. Menyuk, G. W. Iseler, and A. Mooradian “High-efficiency high-average-power second-harmonic generation with CdGeAs2”, Appl. Phys. Lett. 29, 422-423, (1976); 7. C. Kieleck et al., "Compact high-power/high-energy 2 μm and mid-infrared laser sources for OCM," Proc. SPIE, 8898, 889809 (2013); 8. R. Thapa et al., "Mid-IR supercontinuum generation in ultra-low loss, dispersion-zero shifted tellurite glass fiber with extended coverage beyond 4.5 μm," Proc. SPIE, 8898, 889808 (2013); 9. Directed IR Countermeasures, see at: https://elbitsystems.com/product/directed-ir-countermeasures-2/; 10. M. K. Rafailov, Ultrafast laser IR countermeasures, Proc. SPIE 7325, 73250W (2009) KEYWORDS: IRCM, laser, IR, infrared, broad, wide

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: To develop a compressible bi-spectral (0.4 – 12 microns) obscurant material for artillery applications. DESCRIPTION: Smoke and obscurants play a crucial role in protecting the Warfighter by decreasing the electromagnetic signature that is detectable by various sensors, seekers, trackers, optical enhancement devices and the human eye. Recent advances in materials science now enable the production of precisely engineered obscurants with nanometer level control over particle size and shape. Numerical modeling and many measured results on semiconducting and conducting microfibers affirm that more than order of magnitude increases over current performance levels are possible if these microfibers can be effectively disseminated as an un-agglomerated aerosol cloud. Research to discover a single material or a combination of materials that covers the bispectral portion of the EMS spectrum that exhibits very high performance per unit mass will enable bispectral obscuration for artillery and mortars. This advancement will expand the capability of the Army to project screens that defeat EO/IR threat sensors. PHASE I: Demonstrate with samples a material(s) with an extinction of at least 10 m2/gm across the wavelength region from 0.4 to 12 microns. (5) 1 g samples shall be provided to CBC for evaluation. Material should be selected to be robust enough to weather high compression forces and still perform at the desired level. Phase I will focus identifying the candidate material with an extinction of at least 10 m2/gm. Phase II will demonstrate the ability condense and redisperse the obscurant and the ability for the material to survive the high G forces (30,000) that it will be subjected to upon launch. PHASE II: Demonstrate that the material can be densified to 50% of theoretical maximum and that aerosolization of the sample results in at least 50% single particles. Demonstrate that the fabrication of the obscurant material is scalable by providing 4 1-kg samples with no loss in performance from that achieved with the small samples. In addition, in Phase II, a design of a manufacturing process to commercialize the manufacture of materials should be developed. PHASE III DUAL USE APPLICATIONS: The techniques developed in this program can be integrated into current and future military obscurant applications. Improved artillery and mortar rounds and other munitions are needed to reduce the current logistics burden of countermeasures to protect the soldier and associated equipment. This technology could have application in other Department of Defense interest areas including high explosives, fuel/air explosives and decontamination. Improved separation techniques can be beneficial for all powdered materials in the metallurgy, ceramic, pharmaceutical and fuel industries. Industrial applications could include electronics, fuel cells/batteries, furnaces and others. REFERENCES: 1. Bohren, C.F.; Huffman, D.R.; Absorption and Scattering of Light by Small Particles; Wiley-Interscience, New York, 1983; 2. Embury, Janon; Maximizing Infrared Extinction Coefficients for Metal Discs, Rods, and Spheres, ECBC-TR-226, Feb 2002, ADA400404, 77 Page(s); 3. Alyones S, Bruce CW, and Buin AK. "Numerical Methods for Solving the Problem of Electromagnetic Scattering By a Thin Finite Conducting Wire." IEEE Transactions on Antennas and Propagation 55.6: 1856-1861, 2007; 4. Bruce, CW., et al. "Millimeter-Wavelength Investigation of Fibrous Aerosol Absorption and Scattering Properties." Applied Optics 43.36: 6648-6655, 2004; 5. Waterman PC, "Scattering, Absorption and Extinction by Thin Fibers", J. Opt. Soc. Amer., vol. 22, no. 11, pp. 2430-2441, 2005; 6. Hart M and Bruce CW, "Backscatter Measurements of Thin Nickel-Coated Graphite Fibers," in IEEE Transactions on Antennas and Propagation, vol. 48, no. 5, pp. 842-843, 2000; 7. Johnson S, Obscurant Applications, ISN Review, MIT, June 2012 KEYWORDS: Bispectral, infrared, high performance, packing, aerosolization, obscuration

OBJECTIVE: Develop a structural design that has energy considerations for bio-based construction products including cross-laminated and mass timber as well as hybrid systems with polymer matrix composites. DESCRIPTION: This topic focuses the development of design tools for sustainable bio-based construction products for potential use in military construction applications. An increased focus on climate change has led the way for alternative construction materials. In particular, timber products, such as cross-laminated timber (CLT) and mass timber, have been increasing utilized. Wood production requires less energy than either steel or concrete, and contains sequestered CO2, lowering a building’s cradle-to-grave environmental impact [1]. It is also faster to construct in comparison to both steel and concrete, such that a well-designed timber project can have economic benefits as well as environmental ones. For example, the tallest timber structure in North America –the Brock Commons at the University of British Columbia, standing 18 stories tall and consisting of mass timber framing with a concrete core was erected in 70 days (four months shorter than typical buildings of this size). Furthermore, its carbon footprint reduction is in excess of 2,000 metric tons compared to similar concrete and steel structures [2]. In response to priorities in climate change mitigation and improved resilience of military construction, the Army requires new technologies that will better enable the design and construction of facilities utilizing sustainable construction products in a similar fashion as historical trends in military construction using steel and concrete. PHASE I: Demonstrate modeling and design tools focused initially during Phase 1 on blast response to typical anti-terrorism force protection threats / level of protection requirements focused on comparisons between typical construction approaches (CMU walls, concrete, etc.) vs. the use of bio-based building products such as CLT, mass timber, and hybrid systems. This may require limited experimentation, but it is anticipated that prior testing [3,4] can be leveraged to support this requirement. The design approach should be implemented in a preliminary tool, either software or spreadsheet based, for blast response. This design tool is not required to be fully validated or capable during Phase 1, but rather a conceptual demonstration of the tool for further development in Phase 2. Deliver a report documenting the initial research activities under Phase 1 to document the initial concept. PHASE II: Advance design tools to consider additional factors not studied in Phase 1 including additional design configurations and loading conditions for force protection applications. Phase 2 should also consider other structural design considerations as well as energy efficiency / thermal properties of bio-based systems compared with conventional construction approaches. Design approaches should be validated using large scale experimentation / demonstrations. Design approaches and modeling tools should be delivered in simple software tools that are likely tied to production level computational tools (e.g., structural / finite element analysis computational tools) or modifications to existing approaches for structural design. Deliver a reporting document that includes a description a description of the final design tools, the research and demonstration / validation results of all studies performed, and proposed directions for integration into military construction criteria, guidance, and specifications. PHASE III DUAL USE APPLICATIONS: The work has a broad range of applications for military construction as well as civilian applications for sustainable infrastructure. The studies conducted under Phase 1 and 2 will be novel and useful across a range of civilian and military applications. And we anticipate that, outside of unique force protection capabilities, the developed tools would have broad applicability and freedom for dissemination for civilian applications. REFERENCES: 1. C. Hill and K. Zimmer, "The Environmental Impacts of Wood Compared to Other Build-ing Materials," Norsk Institutt for Bioøkonomi, 2018; 2. P. Fast, "Case Study: An 18-storey tall mass timber hybrid student residence at the Uni-versity of British Columbia," in Internationales Holzbau-Forum IHF, 2016; 3. C. Senalik, "Blast-Resistant Testing for Loaded Mass Timber Structures," U.S. Forest Product Laboratory, 2018; 4. M. K. Weaver, C. M. Newberry, L. Podesto and C. O’Laughlin, "Blast Testing of Loaded Cross-Laminated Timber Structures," in Structural Congress , 2018 KEYWORDS: Blast, Force Protection, Energy, Modeling, Structural, Engineering, Materials, Building, Facilities, Wood, Timber, Sustainable, Construction

OBJECTIVE: Develop methods to remotely acquire terrain strength data using infrared (IR) sensors that results in increased vehicle safety, mobility, and maneuverability compared to current approaches to off-road navigation. DESCRIPTION: The Army modernization priority identifies the autonomous maneuverability and off-road mobility of platforms as a critical research area [1]. Robust online remote terrain strength estimation is essential for autonomous ground vehicle mobility over off-road deformable terrains while offline remote terrain strength estimation enables route planning. In order to maximize performance in off-road settings, mobility planning needs to account for the interaction between the vehicle running gear and terrain surface. The most widely used models for force prediction on deformable terrains are the semi-empirical models based on Bekker's classical terramechanics theory [2]. These terramechanics models require inputs of terrain strength properties that vary spatially and temporally. Current methods to acquire these inputs rely on in-situ or satellite-based geographic information systems (GIS) data. Terrain strength data gathered in the theatre of operation may be of high quality and resolution but is resource intensive in terms of manpower and time, making it potentially infeasible for large areas of operation. On the other hand, satellite-based terrain data may be available for large geographic regions, however, these sources often lack the capacity and resolution required to make accurate mobility predictions of terrain strength at the vehicle level [3]. Further, both methods fail to provide means of updating a priori terrain strength data during field operations, resulting in poor vehicle mobility if terrain properties have changed due to seasonal effects, weather impacts, natural disasters, and even human adversarial activity. A novel method to obtain terrain strength relies on remote sensing using IR sensors placed on a ground vehicle or a UAV. Several benefits of this approach include the ability to collect data at vehicle-level resolution, quickly gather terrain strength information over large areas of operation, and automate the transmission and processing of sensor readings to be used during offline route planning before an operation or online mobility planning within an autonomous control system of the ground vehicle in real time. Recent studies have shown success in using hyperspectral and thermal remote sensing in estimating soil type and soil strength [4]. However, fundamental research questions need to be addressed to advance remote sensing for autonomous ground vehicle off-road mobility. These questions/topics include: -Relating remote sensor measurements such as hyperspectral and thermal images to terrain mechanical properties such as cohesion, friction, bearing, and cone index. -Scalability of the technology from small terrain area to large operational region. -Efficiency of the technology to produce data for online navigation of autonomous vehicles in faster than real time. -Robustness of the technology to operate successfully under varying weather and ground conditions as well as measurement uncertainty. -How to integrate the remotely sensed terrain strength parameters into the running gear force prediction models for autonomous ground vehicle systems towards online and offline path planning? -Quantitatively evaluate the benefit of integrating remotely sensed terrain strength parameters for autonomous path planning and validate the results. -Evaluate the robustness of the remotely sensed terrain strength parameters under varying terrain conditions and different soil types. PHASE I: Identify the components required to develop remote sensing capabilities for offline mobility planning. Offline planning entails collecting terrain data over a large area such that a Go/No-Go map can be generated prior to conducting a military operation in that region. Required components may include the test vehicle, potential UAV, IR sensors, and terramechanics models to predict vehicle-terrain interaction using inferred terrain mechanical properties from remote sensing. Conduct initial integration of the components to demonstrate feasibility. The deliverable will be proof-of-concept field demonstration using physical hardware integrated with software to showcase the application of remote terrain sensing to ground vehicle mobility predictions in deformable terrain under off-road conditions. The demonstration output shall be able to support a short vehicle traversal (<0.5 km) with nearly real time terrain information (within 24 hours of sensing terrain). PHASE II: This phase would build upon the foundational efforts of Phase I. Extensive field testing across multiple soil types, varying environmental conditions such as increased moisture, and over large scale geometry will be conducted to evaluate the robustness of the approach, and if needed, employ methods to mitigate uncertainty in terrain strength estimations. Another task will be to update the remote sensing capability from an offline only implementation to online, meaning terrain strength will be remotely sensed and transmitted to an autonomous vehicle’s control algorithm to inform its path planner that uses terramechanics soil models in real time or faster. Note that online remote terrain sensing shall be performed by having the sensors mounted on the autonomous ground vehicle itself. Also, mobility trials with and without remotely sensed terrain strength estimations will be conducted in order to quantify its impact on off-road performance. The deliverable will be a prototype autonomous vehicle with remote sensing capability through IR sensors that augment the path planner’s decision making with terrain strength data in real time to improve mobility performance demonstrated across a wide range of military relevant conditions. PHASE III DUAL USE APPLICATIONS: Work in Phase III would focus on collaborating with Army personnel to transition the developed methodology to the Army. Both optionally manned and unmanned vehicles aligned with the Next Generation Combat Vehicle (NGCV) program, as well as robotic and bridging programs within Project Manager Force Projection of Program Executive Office Combat Support and Combat Service Support, would directly benefit whether they use terrain data remotely sensed offline before an operation or online during a mission in conjunction with the autonomous control system. The technology would be tested to evaluate its accuracy and robustness, and to demonstrate its effectiveness to Army stakeholders. Furthermore in this phase, the technology can be extended to include sharing of sensed terrain data across multiple platforms (V2X communication). This technology would also provide commercial sectors the capability of enhanced off-road mobility. The mining industry is moving towards automated vehicles for their promise of increased safety and productivity [5] with similar trends observed in the agriculture sector for increased yields [6]. In addition, as space exploration becomes more privatized, companies would look towards advanced terrain navigation technologies to ensure the success of planetary missions [7]. REFERENCES: 1. United States Army Modernization Strategy: Investing in the Future (2019); 2. Laughery, Sean C. et al. “Bekker's Terramechanics Model for Off-Road Vehicle Research.” (1990); 3. BRADBURY, MICHAEL, et al. Next-Generation NATO Reference Mobility Model (NG-NRMM). No. 27829. Tank Automotive Research, Development and Engineering Center (TARDEC) WARREN United States, 2016; 4. Ewing, Jordan, et al. "Utilizing Hyperspectral Remote Sensing for Soil Gradation." Remote Sensing 12.20 (2020): 3312; 5. Larsson, J., Broxvall, M., & Saffiotti, A. (2010). An evaluation of local autonomy applied to teleoperated vehicles in underground mines. In 2010 IEEE International Conference on Robotics and Automation (ICRA) (pp. 1745–1752); 6. B. H. Y. Alsalam, K. Morton, D. Campbell and F. Gonzalez, "Autonomous UAV with vision based on-board decision making for remote sensing and precision agriculture," 2017 IEEE Aerospace Conference, Big Sky, MT, 2017, pp. 1-12, doi: 10.1109/AERO.2017.7943593; 7. G. Genta, Private space exploration: A new way for starting a spacefaring society? Acta Astronautica (2014), http://dx.doi.org/10.1016/j.actaastro.2014.04.008i KEYWORDS: Infrared, sensing, autonomy, terramechanics, mobility, off-road, real time, unmanned ground vehicles

OBJECTIVE: Implement and maintain, cybersecurity protocols for the GVPM-RTCS neXtECU engine controller. This capability needs to meet current and future cybersecurity requirements for all ground vehicle programs. DESCRIPTION: Current Engine Control Units (ECUs) being used in military vehicles, such as the Honeywell’s Digital Engine Control Unit (DECU) used in Abrams M1A2 Tanks, are becoming un-supportable and obsolete. The neXtECU, is a viable drop-in replacement controller option for the Abrams M1A2 along with other vehicle platforms such as the 1790 M88 Hercules. It is also currently used to support the development of the Advanced Combat Engine (ACE) and Powertrain (APD) upgrades. The advantages of the neXtECU are not only that it can be implemented on multiple vehicle platforms, but that it will also provide protection for the data it sends and stores. It is essential to adapt and implement cybersecurity protocols into the neXtECU for Army ground vehicles because of the exponential growth of technology and an increased rate of cyber-attacks by U.S. adversaries both foreign and domestic. Currently fielded engine controllers have limited to no cybersecurity protection which leaves them open for Malware, phishing, and possibly clandestine equipment. Without the increased cybersecurity technologies on the engine controller a vehicle can be manipulated by threats in a variety of different ways such as: interrupted flow of data, unauthorized commands to critical components which can endanger human life, and is a danger to critical and costly equipment. Compromised equipment can also lead to drastic increases in life-cycle costs, and can potentially negatively affect overall mission capabilities and success. The cybersecurity measures developed for the neXtECU will effectively protect, restrict, and encrypt data, protocols, and communication systems. The technological solution to be developed will be required to integrate a Hardware Security Module (HSM) with a 5777m processor into the neXtECU. This solution will propose possible interfaces between the bootloader, ECU, and application software. The proposed solution shall also have the potential to secure all communication buses. The proposed Microcontroller Unit (MCU) solution shall possess and industry proven trusted key store concept. Furthermore, the MCU shall address production key updates in field, and an initial strategy for generating and securing keys. These updated technologies will provide users with a safe and secure operating system that provides real-time data and information using an encrypted and protected operating system. The cybersecurity technology will also enable the neXtECU’s system integrity by keeping information from being altered which provides confidence that the system information is confidential, protected, and un-corrupted. The neXtECU has many benefits for the Army due to its wide application for all ground vehicles, and it can provide a solution to upcoming sustainment issues, cybersecurity, and capability enhancements. This neXtECU with the proposed cybersecurity technology can also be used in the automotive industry, with autonomous driving vehicles, over-the-air vehicle software updates, wireless device linking, and for many other cyber based advancements that are presently growing.   PHASE I: Identify and determine the software, hardware, and other technologies/equipment needed to develop this cybersecurity technology concept to work with the neXtECU. The proposed solution shall not require a hardware re-design of the neXtECU. An integration and compatibility study should be conducted in this phase to be used in Phase II to interface the new technologies within the neXtECU. An investigation of solutions shall be compatible not only with the neXtECU, but other potential industry Microcontroller Units (MCU’s). Techniques and methods developed in this phase should meet all government cybersecurity provided requirements, as well as any other requirements developed during this phase. While developing requirements, this phase should evaluate overall key performance parameters needed to be successful to meet Phase II requirements. A competitive analysis and proposal of all potential embedded systems for security (i.e. ESCRYPT, Argus, Trillium, Karamba, etc.) or similar shall be conducted. A breakdown of all potential solutions as well as their commercial merit and their feasibility is required. Finally a bill of materials, volumes, and part costs for Phase I and Phase II designs should also be developed and outlined for the proposed solution. Designs in this phase also need to address any challenges identified in the above description or set of requirements. PHASE II: Phase II will develop and integrate the prototype software and hardware into the neXtECU based on the Phase I designs and solutions that were developed and recommended. The cybersecurity technology shall be designed to support all current development protocols for the neXtECU’s programming (ETAS XETK, CAN UDS, Lauterbach, etc.). During this phase bench testing demonstrations will be required to accurately gauge and establish performance parameters. The expectation will be to have the GVSC Cybersecurity team test the final design to assess the capability to secure software re-programming, secure communications, and to demonstrate overall integration into the neXtECU. Phase II efforts will finalize the requirements, overall system protections and system functionality. A final bill of materials, production costs, volumes, all developed software, and a prototype shall be deliverables for the Phase II design. PHASE III DUAL USE APPLICATIONS: During this phase the solution for the neXtECU’s cybersecurity technologies will be implemented. Additionally, integration of the neXtECU into the 1790 M88 Hercules vehicle platforms will take place during Phase III. REFERENCES: 1. NHTSA. “Cybersecurity Research Considerations for Heavy Vehicles” [online]: National Highway Safety Administration.[Accessed 2/4/2020] https://www.nhtsa.gov/sites/nhtsa.dot.gov/files/documents/sae2018sstachowski.2.pdf; 2. Stouffer, Keith, et al., “Guide to Industrial Control System (ICS) Security”, NIST Special Publication 800-82r2 (May 2015): http://dx.doi.org/10.6028/NIST.SP.800-82r2; 3. NHTSA. “Vehicle Cybersecurity” [online]: National Highway Safety Administration.[Accessed 2/4/2020]; 4. Leonard, Matt. “Defending Military Vehicles against Cyberattacks -.” GCN, 19 Mar. 2018. [Accessed 2/4/2020]; 5. Stone, Mark. “It's Time for an Automotive Cybersecurity Wake-Up Call.” Security Intelligence, 7 Mar. 2019, [Accessed 2/4/2020] https://securityintelligence.com/its-time-for-an-automotive-cybersecurity-wake-up-call/ KEYWORDS: neXtECU, Cybersecurity, Controller, Platforms, Protocols, Technology, Capabilities

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: To find an additive manufacturing process/method to produce large scale components for military systems that have repeatable material properties, using a physics-based approach. DESCRIPTION: Additive manufacturing (AM) is currently and will continue to be a major area of interest for the Army moving forward. This is for a variety of reasons, including sustainment (printing obsolete or difficult to acquire parts, part repair), readiness (eliminating long lead times), light-weighting (geometry optimization), and more. The Army, more so than most other industries, has the need to additively manufacture large scale metallic components. There are several AM methods that can be used for this (powder bed, electron beam, WAAM, cold spray, etc.), but none that are widely accepted (within the Army) to producing large scale (larger than 1 m2 in the x-y plane) production parts. GVSC Materials Directorate wishes to partner through the STTR program to further characterize large scale metal AM parts and work toward certification of the parts and the AM process/method used to manufacture them. Successful applicants must have commercially available AM technology (one AM method) that can print steel, aluminum, and/or titanium alloys, and meets a minimum build size of 1 square meter (in the x-y plane). Applicants must also have a planned or currently available in-situ process/technology that uses a physics-based approach to ensure repeatability and statistical confidence of material properties of the parts produced, regardless of the part geometry. Awardees will partner with a research entity which will test printed material in two phases. The intent of Phase I is for each awardee to use a different, large scale AM method. Phase I will consist of material characterization testing that will include, at a minimum; tensile properties, hardness distribution, impact toughness (Charpy v-notch or as-appropriate), microstructural analysis, void fraction, and fatigue. After Phase I, the awardees/AM methods will be down-selected to the one (or two) that show the most promising results and move forward into Phase II. Phase II will consist of refining the physics-based process to increase, as much as possible, the repeatability of material properties of parts with differing geometries. Material characterization testing will continue by taking samples directly from printed parts (vehicle components), which are identified by the government. The effort in Phase II is to increase the baseline properties identified in the first set of tests, resulting in a process and parts that meet Army weapon systems requirements. The final deliverables will be one or more prototype parts that can be used for on-vehicle testing, and a physics-based record showing the repeatability of the specific AM process. PHASE I: Phase I is intended for each awardee to use a different, large scale AM method (powder bed, electron beam, WAAM, cold spray, etc.). Phase I will determine the AM method(s)/process(es) that have the greatest feasibility to produce repeatable and statistically confident material properties of large scale metallic parts. Phase I will consist of material characterization testing that will include, at a minimum; tensile properties, hardness distribution, impact toughness (Charpy v-notch or as-appropriate), microstructural analysis, void fraction, and fatigue. PHASE II: Phase II awards will be made to firms on the basis of results of their Phase I effort and potential to transition to Phase III. Phase II will consist of refining the physics-based process to increase, as much as possible, the repeatability of material properties of parts with differing geometries. Material characterization testing will continue by taking samples directly from printed parts, which are identified by the government. The effort in Phase II is to increase the baseline properties identified in the first set of tests, resulting in a process and parts that meet Army weapon systems requirements. The final deliverable will be one or more prototype parts that can be used for on-vehicle testing. PHASE III DUAL USE APPLICATIONS: Phase III will end with a commercially available Additive Manufacturing method, with a physics-based control process, that is capable of printing large scale metallic components with reliable and repeatable material properties. The technology can be used to produce large components for Army vehicles such as structural components, chassis components, large turret components, large hatches, etc. It will also be useful for other industries, such as aerospace, large truck/trailer, and others. REFERENCES: 1. Gordon, Jerard & Narra, Sneha & Cunningham, Ross & Liu, He & Chen, Hangman & Suter, Robert & Beuth, Jack & Rollett, Anthony. (2020). Defect structure process maps for laser powder bed fusion additive manufacturing. Additive Manufacturing. 101552. 10.1016/j.addma.2020.101552; 2. Promoppatum, Patcharapit & Rollett, Anthony. (2020). Influence of material constitutive models on thermomechanical behaviors in the laser powder bed fusion of Ti-6Al-4V. Additive Manufacturing. 10.1016/j.addma.2020.101680; 3. https://www.sbir.gov/content/predictive-modeling-tools-metal-based-additive-manufacturing-1 KEYWORDS: additive manufacturing, big metal, electron beam, EBAM, wire arc, WAAM, cold spray, powder bed, physics-based control, in-situ control process, sustainment, readiness, lightweighting

OBJECTIVE: Develop a non-invasive device that either 1) prevents functional impairment due to an Acute Stress Reaction (ASR) or 2) returns Soldier to performance following the occurrence an ASR. DESCRIPTION: Mental health symptoms stemming from severe stress exposure during deployment degrade performance and compromise the safety of Soldiers and their teams in far forward operational environments. In 2018, 28% of medical evacuations were attributed to mental health-related symptoms (Armed Forces Health Surveillance Branch, 2018). Anticipated conditions of the future battlefield will increase the cognitive demands on Soldiers, and it is expected that the incidence of severe stress exposures, and thus mental health symptoms, will escalate. Soldiers will be operating in small teams for prolonged periods without ready access to tactical or medical support due to communication-interfering capabilities of adversaries and other limitations of the operational environment. These conditions will increase exposure to severely stressful situations, prolong the amount of time Soldiers must cope with severe stress reactions, and magnify the opportunity for decrements in performance to put personal safety and the mission at risk. Therefore, it might be expected that the incidence of ASR will increase. An ASR is a normal response to a severe physical or mental stressor, such as combat, that results in maladaptive emotional, cognitive, somatic, and/or behavioral symptoms during the first 1-3 days following a traumatic event. Unfortunately, there are currently no FDA-approved treatments for ASR. Further, existing treatments for trauma-related disorders such as PTSD have limited efficacy in Soldiers and take 4-6 weeks to reach effects. It is therefore critical to develop safe and effective interventions to support Soldier performance prior to, during, and after severe stress exposure during combat operations. Additionally, treatments for ASR should not result in significant cognitive, motor or other functional side effects, act rapidly to sustain Soldier performance, and be safely administered in operational environments as part of pre-hospital care. This STTR aims to develop a non-invasive device that could be used in training prior to, during, or immediately following a traumatic stress exposure to maintain Soldier performance in an operational environment. The deliverable must function in a range of environments (e.g., laboratory, operational training, in garrison, and far forward deployment settings) where smartphone usage, service, and internet availability is variable. In the context of multi-domain operations, internet, electronic, or blue tooth connectivity will not be likely. PHASE I: Phase I will focus on development of performance parameters and initial concept testing for a prototype device. Performer should develop a plan for a practical deployment, use of the prototype in different environments (e.g., in lab, in garrison, training, deployed settings) where there is variable access to electronic or internet connectivity. Primary performance parameters to be considered for devices that will be utilized as preventative treatments include level of efficacy in maintaining baseline performance, preventing the occurrence of stress-related symptoms, training time needed, ease of use, retention time of treatment effects, impact on functional performance, portability, maintenance requirements and network requirements. Performance parameters to be considered for devices that will be utilized as pre-hospital treatments include level of efficacy in restoring performance and/or reducing stress-related symptoms, time to reach treatment effects, FDA market authorization (if applicable), ease of use, retention time of treatment effects, impact on functional performance, portability, maintenance requirements, network requirements, production costs, and maintenance costs. Finally, this phase will produce a virtual or in-person demonstration of device function based on established performance parameters. PHASE II: Phase II will focus on creating a field-testable prototype that meets the criteria determined in Phase I. The aim will be to demonstrate proof-of-concept by developing, testing, and refining a prototype. In order to accomplish this Phase II testing and evaluation, the objectives for human subject research for testing and data acquisition must be defined. A research protocol aimed at validating the prototype in a laboratory setting should evaluate the capabilities of the prototype through limited human testing in laboratory research. The laboratory testing should demonstrate that the device is able to 1) effectively prevent decrements in performance on operationally relevant tasks or increased stress symptoms following training and stressor administration in a laboratory setting or 2) effectively restore performance on operationally relevant tasks or stress symptoms following stressor administration in a laboratory setting. During this phase, the stressor administration does not need to be a traumatic stressor, but can utilize a well-validated model of human laboratory stress. The stress and measures of performance should be as operationally relevant and translatable to military stress and operational performance as are feasible. A regulatory strategy should be put in place if applicable, including a pre-submission meeting with the FDA to assist with protocol design. PHASE III DUAL USE APPLICATIONS: Phase III will focus on refinement of the device prototype, based on evaluation data obtained in Phase II, in order to create a final production-ready system. The full functionality of this final device will be evaluated within an operational field environment. For devices that will be utilized as preventative treatments, effectiveness will be evaluated using baseline performance metrics gathered prior to training with the device and an appropriate comparison group may be determined based on device specifications and with input from the FDA. For devices that will be utilized as pre-hospital treatments, effectiveness will be evaluated using an appropriate comparator based on the device specifications and with input from the FDA, as appropriate. The vision for this capability is to have a device that can be used during pre-deployment training to prevent an ASR or for pre-hospital treatment of ASRs during combat. Defense R&D funding may be obtained in coordination with an advanced developer, such as US Army Medical and Materiel Development Activity (USAMMDA) Warfighter Brain Health Project Management Office, to expedite the technology transition from the laboratory to operational use. As applicable, the company will develop a quality management system and regulatory strategy for FDA marketing application submission. This effort will deliver a product that is broadly usable by the DoD for prevention or treatment of ASR. The final product should be presented to applicable DoD representatives and program managers for transition to use in military environments. Further, the utility of this a non-invasive device may be relevant to industry, academia, and the general public for the potential treatment of other trauma-related disorders, pending additional FDA marketing authorizations. Awardees must outline a commercialization pathway including, but not limited to, regulatory strategy, marketing strategy, consumer feedback, and sales. REFERENCES: 1. Armed, Forces Health Surveillance Branch. "Update: Medical evacuations, active and reserve components, US Armed Forces, 2017." MSMR 25.7 (2018): 17 KEYWORDS: Traumatic stress, neuromodulation, neurofeedback, acute stress reaction, acute stress disorder

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Develop new oriented film based materials with superior ballistic performance, good durability, manufacturability, and cost competitive to currently fielded ballistic fibers and fabrics. DESCRIPTION: In recent years, advances in polymer processing science and technology have enabled the development of highly oriented polymer films with mechanical properties that significantly exceed previous materials made with the same base polymer. Advances have been made in producing and drawing films from difficult-to-process polymers with exceptional properties, such as ultrahigh molecular weight polyethylene. These materials have already advanced the state of protective soldier protective systems, such as with the development of the advanced combat Helmet Gen II.1 In addition to achieving preferential orientation of base polymers, researchers have demonstrated formation of nanocomposite films with exceptional properties. Optimization of film processing parameters can be greatly aided by laboratory techniques that allow better fundamental understanding of the structural evolution of polymer films during post-stretching processing; recent advances in synchrotron radiation (SR) light sources and detection techniques allow measurement of the polymer’s changing morphology in real time with the use of a combination of small- and wide-angle X-ray scattering (SAXS/WAXS). These studies can be used to create process-structure-property databases that can be used as the basis for model discovery and combined with artificial intelligence techniques to rapidly converge on optimal processing conditions, rather than using traditional trial and error techniques.2 There are compelling indications that oriented films may provide superior ballistic performance to oriented fibers made of the same polymer. Around 2007, several manufacturers began producing a solid state extruded film made from ultrahigh molecular weight polyethylene. The ballistic performance of this film was noted to be higher than expected given its low tensile strength relative to its ultrahigh molecular weight polyethylene fiber counterpart (3,4). Oriented films such as uniaxially oriented polypropylene have also shown promise for transparent armor.5 The technical challenge of meeting optical transmittance and clarity requirements for transparent armor while providing a high level of ballistic protection is much more significant than for opaque armor. Thus, transparent oriented films with improved ballistic performance are of particular interest in this topic. PHASE I: Phase I of the program should demonstrate feasibility of the technical approach and development of the initial material concept. Offerer will select materials for candidate films and explore processing mechanisms for creating oriented films with superior properties. Materials can include base polymers as well as additives. The focus of Phase I is to demonstrate the ability to enhance the properties of the base polymer film through processing and use of additives. Measurements to characterize the film material’s morphology and correlate it to processing conditions and to mechanical properties should be performed in Phase 1. Technologies will be evaluated for transition to Phase II based on improved tensile strength and modulus values. U* may also be used to evaluate performance advancement. 6 PHASE II: Phase II should focus on material production to generate prototypes for ballistic evaluation. The PI will develop materials and processes to fabricate ballistic flat panels at areal densities from about 0.5 pounds per square foot (psf) up to about 1.0 psf. At a minimum, materials for opaque armor should be tested for V50 against 17 grain fragment simulating projectile (FSP). Transparent materials should be tested for transmissivity, haze, scratch resistance, and V50 against 17 grain and 5.8 grain fsp (0.125 inch thich samples). Final deliverables should include a cost estimate for scale up and production of the material, technical data package, prototypes for evaluation by the Government and a final report. PHASE III DUAL USE APPLICATIONS: Phase III should focus on scale up of the material product and building prototype components to demonstrate appropriate applications of the material. For opaque armor, prototype components could include helmets and/or ceramic plate armor backings. Lenses or visors should be the focus for transparent material applications. While the animus for this topic is improved ballistic protection at the dismounted soldier level, the technology may be extrapolated for broader military use. Improved materials may also be of commercial interest for non-DoD protective and security services. REFERENCES: 1. https://www.military.com/daily-news/2017/03/30/army-shows-off-its-lightest-combat-helmet-ever.html; 2. Kim, Jun Young, “ Carbon Nanotube-Reinforced Thermotropic Liquid Crystal Polymer Nanocomposites”, Materials 2009, 2, 1955-1974; 3. University of Warwick. "Polythene films strong as aluminum could be used for windows, screens and phones." ScienceDaily. ScienceDaily, 1 April 2019. https://www.sciencedaily.com/releases/2019/04/190401121817.htm; 4. Singletary, J. and B. Lauke, “Polyolefin film–reinforced composites for personal protection” in Advanced Fibrous Composite Materials for Ballistic Protection, 2016; 5. Yunyin Lin, Ruhi Patel, Jun Cao, Wei Tu, Han Zhang, Emiliano Bilotti, Cees W.M. Bastiaansen, Ton Peijs. “Glass-like transparent high strength polyethylene films by tuning drawing temperature.” Polymer, 2019; 171: 180 DOI: 10.1016/j.polymer.2019.03.036; 6. Yuanfei Lin, Wei Chen, Lingpu Meng,a Daoliang Wanga and Liangbin Li “Recent advances in post-stretching processing of polymer films with in situ synchrotron radiation X-ray scattering”, Soft Matter, Issue 15, 2020 KEYWORDS: Ballistic materials, oriented polymer films, nanocomposites, transparent armor, ballistic eyewear

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Research and develop an innovative, low ESOH risk coating for infrared (IR) and thermal management of a UAV. Demonstrate this IR-functional coating on a UAV in a relevant environment. DESCRIPTION: In multi-domain operations, Unmanned Aerial Vehicles (UAV) widely operate as an extension of the Warfighter and squad, enabling much better situational awareness. UAVs are also used commercially for transporting loads, monitoring networks, and many other civilian applications. More widespread infrared (IR) imaging capabilities among adversaries means that it is increasingly easy to identify UAVs during operation, reducing their effectiveness and compromising the mission. Due to both increased use of UAVs and increased access to IR imaging capabilities by adversaries, there is a strong and emerging need for coatings to protect UAVs from detection by reducing the expected maximum range to image. However, many of the available coatings that could protect the UAVs from detection, especially in the IR/ visible (optical) ranges, contain materials that are toxic and bad for the environment; e.g., isocyanates. Nature has enabled sophisticated color schemes in the animal kingdom, including bright and dark tones for camouflage. Bio-inspired materials have been extensively researched in the academia, and bio-inspired coatings fabricated with the ability to mask signature, and even regulate temperature, as Nature does. Simultaneously, bio-inspired materials and biomaterials are being explored in synthetic biology, enabling US manufacturing to be simpler, more environmentally friendly, use less toxic materials, and be less dependent on rare materials imported from few foreign nations. The DoD and Army must bring more environmentally friendly and less toxic materials into its supply chain, and is required to make surface coating products and processes that are more Environment, Safety, and Occupational Health (ESOH) sustainable. The goal of this topic is to develop an innovative coating with infrared functionality – managing both signature and thermal properties/temperature – for a small UAV that accompanies the Warfighter and is capable of reconnaissance missions. “Infrared functionality” includes passive (and active, i.e. actuated heat release port, etc) temperature control. Emissions must be controlled in the longwave IR (LWIR) or thermal IR, as specified quantitatively below. While the visible, near-infrared, and short-wave (SWIR) infrared are not a focus of this Topic, a coating that is successful for both military and commercial applications must also manage optical properties (e.g., reflectivity and absorption) in these spectral ranges. Batteries, operating as hot as 60°C, and motors, will contribute hotspots to a UAV’s thermal image. UAVs can be observed at distances ~ 100m with IR cameras [1], even when not visually observable. Advanced gimballed, large detection systems could image UAVs at shorter range. Bio-inspired materials, like bio-pigments, exhibit strong IR scattering and high refractive indices, and could strongly affect IR images of a passive coating [2]; these materials have been introduced into fibers. Coatings could be smooth and paint-like, or on fibers and/or textile-like material (i.e. [3]), possibly adding IR functionality, but they must be robust to withstand continuous flights at the rated velocity of the UAV, through different weather conditions. Coatings must have lower ESOH risk than traditional DoD paints, which can no longer contain materials like hexavalent chromium. Polyethylene is an example of one environmentally-interesting material, proposed for thermal and color management [4]. PHASE I: Conduct a feasibility study by identifying, through early stage experiments and modeling (not just modeling), a coating that can be used to trap heat inside a UAV that is conformal, paint-like, and does not have significant ESOH risk for use by operators and manufacturers; for example, a bio-inspired material with backwards infrared scattering centers. Deliver coated samples of representative UAV body elements (wings, battery encasements, motor hubs, etc.) with experimental results demonstrating IR absorption/reflection properties that indicate potential range reduction for LWIR camera-based detection/imaging below 100m. Model potential performance improvements relevant to increased operating temperature for UAV, and possibly LWIR imaging degradation. Model weight of coating for an entire UAV and any effects on aerodynamics of the UAV. Document results of experiments and modelling in a report. PHASE II: Building on Phase I work, in Year 1 of Phase II: demonstrate a prototype, consisting of a fully coated UAV using a coating with low ESOH risk, and demonstrate in a lab environment the coating’s effect on LWIR imaging (using a LWIR camera) of the UAV, degrading images taken at more than 100 m. Also in Year 1, demonstrate improvement to operating temperature range (e.g., any thermal management improvements). In Year 2, include in the prototype a way to mitigate temperature swings of the UAV; e.g., release heat if internal temperature becomes too high; for example, opening a heat exhaust port (“heat valve”) at the back of the UAV temporarily to reduce heat load inside the UAV. In Year 2, the 100 m maximum LWIR range must be improved, any leakage of elevated UAV body temperature into the SWIR range considered, and some temperature control demonstrated. Ideally in Year 2, conduct a toxicological assessment of any new materials used in the coating, with Army Public Health Command. Report ESOH impact and weight of the optimized coating, including potential new heat valve, and demonstrate minimal effects on aerodynamics of UAV and plan for mitigating any heat build-up in warmer environments. Demonstrate coating is as resilient to environmental conditions (temperature, humidity, rain, etc) as uncoated UAV body elements, or report on the reduction in operating ranges for these properties, ideally in a relevant environment (the full system must be demonstrated at least in a laboratory environment). Deliver full prototype of coated UAV to the government. Document results of experiments and modelling in reports for both Year 1 and Year 2. Comment in the reports about the tradeoffs of using a low ESOH-risk passive coating vs. active approaches to avoid detection like use of scattering agents in a released gas. PHASE III DUAL USE APPLICATIONS: Scale the technology demonstrated in Phase II up to a level that produces a full system that could be used in an operationally relevant environment for the Army. Demonstrate reduced IR signature and improved operating temperature range in this environment. Dual use potential for coating comes in two principle areas (1) its use for IR concealment and (2) its use for thermal regulation. (1) Coated UAVs could be marketed to law enforcement (police, department of homeland security, etc.) for its ability to provide UAV concealment to improve surveillance applications. Licensing to or partnering with existing UAV manufacturers in this commercial space would be ideal. (2) Coated UAVs and coatings could also be marketed to widespread commercial applications (agriculture, delivery services, photography, cinematography, hobbyists) on the basis of improving thermal regulation of the UAV in cold environments. Many users face issues from temperatures being too cold for batteries of flight computers to operate normally, reducing mission and flight times. REFERENCES: 1. Night-time Detection of UAVs Using Theral Infrared Camera; Andrasi; Radisic; Mustra; Ivosevic; Vol. 28; 2017; 183-190; https://www.sciencedirect.com/science/article/pii/S2352146517311043; 2. Natural light-scattering nanoparticles enable visible through short-wave infrared color modulation in cephalopods Adv. Opt. Mat. Kumar A. et. al; 6 1701369 2018. https://www.nanowerk.com/nanotechnology-news/newsid=49523.php , with reference to peer-reviewed publication; 3. Crye Precision; Compact Alpine Overwhites Product Detail; https://www.cryeprecision.com/ProductDetail/accow191lxl_compact-alpine-overwhites; 4. Lozano L. M. et. al. Optical engineering of polymer materials and composites for simultaneous color and thermal management Opt. Mat. Exp. 9 2019 KEYWORDS: Unmanned aerial vehicles (UAVs), Unmanned vehicles (UXVs), Thermal Management, IR Concealment, Bio-pigment Coatings, Bio-manufacturing

OBJECTIVE: Develop material compositions which dissolve in blood in times from ten minutes to one hour, which are compatible for use in the body, which can be shaped as needed, and which can be produced in commercial quantities at reasonable cost. DESCRIPTION: Photochemical tissue bonding (PTB) has been shown to have many important advantages in wound repair over more conventional treatments such as suturing [1, 2]. Advantages include no foreign body interactions, a tight seal with no leakage, and a lower skill level required to perform the procedure. In PTB a dye (usually Food and Drug Administration (FDA) approved Rose Bengal) is applied to the wounded area and then light is applied at a wavelength of 532 nm from a frequency doubled Nd:YAG laser about the size of a laser pointer. The procedure has been found to cross link two tissue segments with minimal temperature rise and with no incorporation of the Rose Bengal. In many PTB procedures internal to the body it would be useful to have a structural element to support the tissue while the procedure is being performed. Reference 2 describes the use of a stent in performing a vascular anastomosis. That reference used hollow polyvinyl alcohol (PVA) stents to demonstrate the principle and usefulness of such stents. However such PVA stents are not clinically viable as they are not easily removable after repair and are thrombogenic. A clinically viable solution would be a similarly shaped material, possibly an inorganic glass that dissolves in blood in an appropriate time – programmable from minutes to about an hour. Such a material would have to exhibit sufficient strength for the PTB procedure before being exposed to the dissolving blood and of course, the material and its dissolved components must be non-toxic. The topic in summary therefore calls for the development of a capability for producing a material that dissolves in blood in programmable times for minutes to up to an hour, can be fabricated in shapes, for example stents, as needed for PTB applications, has sufficient strength not to break up in application before being dissolved, and is non-toxic in its original form and dissolution products. The shaped material must be scalable to satisfy demand at a commercially viable price, both of which should be addressed in a proposed commercialization plan. PHASE I: Define and demonstrate a process for making a glass or other material which dissolves in blood and meets the other criteria described in the background section above. Test, demonstrate, and modify the material as necessary to reduce risk that the material can meet all requirements in a Phase II effort. In Phase I a saline solution may be used as a stand-in for blood, as their properties are entirely similar for this purpose. Develop a Phase II plan for refinement of the Phase I effort and a scale-up plan to make larger quantities of the fabricated material at a cost consistent with the proposal commercialization plan. PHASE II: Refine the material designs, fabrication processes, and testing and evaluation techniques using demonstrations and lessons learned in Phase I. Demonstrate fabricated material meeting all the criteria described in the background section above. Obtain all necessary approvals and demonstrate, together with the non-profit partner, that the fabricated materials can perform according to the objectives of the topic in small animal experiments, and that the benefits of photochemical tissue bonding such as no leakage and no adhesions are retained. Complete and begin implementation of the Phase I scale-up plan and adjust as necessary. Develop a plan for human experiments in Phase III, a plan for obtaining FDA approval, and begin implementing that plan. Begin discussions with potential Phase III funders and modify ongoing development to the extent feasible to satisfy requirements of those potential funders. PHASE III DUAL USE APPLICATIONS: With a successful Phase II completion, the benefits of photochemical tissue bonding would be overwhelming, including no foreign body interactions, avoiding leakage, and no adhesions, leading to greatly reduced mortality and morbidity. The ability of lesser skilled personnel to perform procedures, for example in vascular anastomosis, would be a great advantage in combat casualty care or in local, lower level trauma civilian hospitals, where for example a skilled vascular surgeon might not be readily available. These aspects make it very likely the company could obtain Phase III or interim funding from MRDC advanced development or from a medical supply company. A product could be in the form of a surgical kit containing a small laser, dye with applicator, and a variety of sizes of stent, the product of this STTR topic, along with written or more likely smartphone instructions. In Phase III the company and/or others partnered with it will demonstrate complete PTB surgical solutions using the dissolvable material technology developed in Phase I and II. It is likely PTB surgical solutions would be introduced into clinical use rapidly following its initial demonstrations and following an initial build-up period and with sufficient marketing (e. g. showing at surgical conferences, recruiting influencers, etc.) owing to its many advantages, particularly that it could be performed by non-specialized physicians who would not need to pass patients on to more specialized physicians. REFERENCES: 1. R.W. Redmond, I.E. Kochevar, C. Amann, et. al., Photochemical Tissue Bonding: Photons for Healing. Available at: https://www.researchgate.net/publication/242378573_Photochemical_Tissue_Bonding_Photons_for_Healing 2. S.T Johnson, A.C. O'Neill, P.M. Motarjem, C. Amann, T. Nguyen, M. A. Randolph, J. M. Winograd, I.E. Kochevar, R.W. Redmond, Photochemical tissue bonding: a promising technique for peripheral nerve repair, J Surg Res. (2007) 143(2):224-9. DOI: https://doi.org/10.1016/j.jss.2007.01.028 3. Senthil-Kumar P, Ng-Glazier JH, Randolph MA, Bodugiuz-Senturk H, Muratoglu OK, Kochevar IE, Winograd JM and Redmond RW. An intraluminal stent facilitates light-activated anastromosis. J Trauma Acute Care Surg. (2017) 83(1), S43-S49. DOI: https://doi.org/10.1097/ta.0000000000001487 KEYWORDS: Resorbable, glass, stent, photochemical, tissue bonding, wound repair

OBJECTIVE: Develop and demonstrate a technology to rapidly purify bacteriophages (phages) of Gram-negative bacteria to a level suitable for human therapeutic use, free of endotoxin and of other bacterial remnants including other pyrogens and pathogen-associated molecular patterns (PAMPS), for application in treating recalcitrant multidrug resistant infections of the Warfighter. DESCRIPTION: Multidrug resistant (MDR) bacterial infections present a worldwide public health crisis, and MDR wound infections are an enduring challenge for the Military Health System. Treatment options are diminishing with the proliferation of MDR and lack of new antibiotic development. Multi-domain operations (MDO) envision medical evacuation delayed days to weeks, leaving wounded Warfighters and front-line medical providers in prolonged care (PC) scenarios of uncertain duration. Front-line providers will need to care for high volumes of wounded for days while retaining mobility, severely limiting interventions to prevent sepsis caused by polytraumatic wounds. Increasing MDR bacteria combined with PC will yield infection rates of 50-60% of the wounded, with a dramatic increase of sepsis-related deaths that could parallel those of previous conflicts such as Vietnam, Korea, or the World War II Pacific Theatre (in which medical support was delayed for weeks). To address these challenges, innovative and scalable solutions are urgently needed to amplify the capability of front-line providers to care for large numbers of wounded. The bacterial ESKAPEE pathogens (Enterococcus faecium, Staphylococcus aureus, Klebsiella pneumoniae, Acinetobacter baumannii, Pseudomonas aeruginosa, Enterobacter spp., and Escherichia coli) frequently colonize healthy military personnel and are common agents of persistent infections of traumatic and burn wounds that are biofilm associated and MDR. The diminution in effective antibiotic options and urgent need for wound infection and sepsis mitigation necessitates the development of novel effective antimicrobials with alternative mechanisms of antibacterial activity that can be used in combination with existing Standard of Care (SOC) antibiotics. Phage therapeutics are thus being developed for therapeutic and prophylactic purposes. Lytic or virulent phages are viruses of bacteria that specifically infect and kill their bacterial host species, including antibiotic resistant and MDR variants. Since they possess specificity to their bacterial targets, phages eliminate the infectious species without perturbing normal human microflora. Phages have demonstrated therapeutic efficacy against ESKAPEE infections in the laboratory and in domestic and farm animals, with promising results in expanded access human treatment and even in recent clinical trials when used in combination with antibiotics. Phage therapy has the potential to become an important adjunctive therapy against MDR bacterial infections in civilian and military patients, but robust randomized clinical trials must first be conducted to investigate the benefits of phage therapy with SOC compared with SOC alone. Standardized reliable and repeatable manufacturing of phage biologics is needed to obtain safe, uniform phage products the US Food & Drug Administration (FDA) can approve to go into clinical trials. As phage biologic products enter large-scale phase 3 clinical trials, and obtain licensure to enter production as approved therapeutics, the scalability of these manufacturing processes will be essential. Because phage manufacturing is universally done by propagating the virus on a susceptible host bacterium, a critical challenge is the removal of bacterial remnants after phage propagation, including the removal of lipopolysaccharide (LPS, also termed endotoxin), a component of Gram-negative bacteria. Many phages use parts of LPS as a receptor and thus bind LPS with moderate to high affinity. This makes endotoxin removal for the level of purity needed for parenteral routes of delivery a challenge. A high purity phage product is critical for intravenous administration, often used in expanded access phage therapy regimens as a precursor of broader therapeutic application. The purpose of this STTR is to provide a technology or process to enable the rapid purification of bacteriophages, including the removal of bacterial remnants, from a variety of Gram-negative bacterial targets. The envisioned system will purify a wide variety of phages that propagate on a variety of bacterial strains of the Gram-negative ESKAPEE pathogens (Klebsiella pneumoniae, Acinetobacter baumannii, Pseudomonas aeruginosa, Enterobacter spp., and Escherichia coli). This capability will be scalable to directly enable the manufacture of therapeutic phages and phage cocktails, to provide purified preparations of diverse phages with very low residual endotoxin at levels deemed acceptable by FDA for parenteral delivery. Future users of the system will use the technology developed for the purification of a wide variety of phages against any or all of these Gram-negative bacterial pathogens. The technology may be, but is not limited to, micro-filtration systems, microfluidics, centrifugation, nano-materials, gel or polymer matrix or any combination of relevant and novel technologies. The device can be a closed or open modular system. The following features will be critical to consider when proposing a technology: 1) System enables users to purify a variety of phages against a range of Gram-negative pathogens (K. pneumoniae, A. baumannii, P. aeruginosa, Enterobacter spp., and E. coli) over a 24 hour period, allowing multiple phages to be processed within a work day for small scale manufacturing and a significant improvement in efficiency to current large scale phage purification. 2) System removes bacterial remnants of the production host strain including endotoxin and other pyrogens to acceptable levels for clinical use. The FDA acceptable limit of endotoxin for intravenous delivery is 5 EU per kg per h, thus 300 EU or lower is sought per 109 - 1010 plaque forming units (pfu) phage per dose (https://www.americanpharmaceuticalreview.com/Featured-Articles/353977-Calculating-Endotoxin-Limits-for-Drug-Products/). 3) System will be scalable from laboratory-level phage production and small-scale manufacturing (yields in the 1010 to 1011 pfu/mL range) to large-scale cGMP manufacturing of drug products. PHASE I: This phase is focused on the design of a proof-of-concept prototype technology that enables rapid phage purification from different Gram-negative bacterial hosts. During this phase, the performer may focus on endotoxin removal from a variety of phages against at least two Gram-negative ESKAPEE bacterial hosts, including P. aeruginosa since it can be challenging for the production of phages with low endotoxin levels. System does not need to be integrated in this phase but should have scalable workflow. At the end of this phase, a working prototype technology will efficiently purify phages from at least two bacterial species. Comparison with published methods can be used to assess the efficiency or rapidity of phage purification. PHASE II: During this phase, the technology/device will be integrated. The workflow from Phase I will be refined to expand the proof-of-concept to a product enabling rapid purification of diverse phages against diverse strains of the listed target species. Critical features of the technology will be addressed including measures of purity including endotoxin removal, efficiency and scalability. Testing will be controlled, rigorous and reproducible. PHASE III DUAL USE APPLICATIONS: Efforts during this phase should address the US Army Medical Materiel Development Activity and the office of Warfighter Protection and Acute Care small business. This phase will focus on scaling production, marketing of the developed technology to distributors, and contracts. Accompanying application instructions, simplified procedures, and training materials are drafted in a multimedia format for use and integration of the product into market. The end-state for this product is a commercially viable technology for phage product manufacturing in the industry that will also be used for phage product development by the Department of Defense. Performer should pursue a commercial path to improve phage manufacturing processes within the bio-pharma arena, but also across medical and educational institutes involved in personalized medical treatments and in product development. The developed process will be integrated into tailored phage therapy and into larger scale industrial manufacturing of phage products for human and veterinary health applications. This product will be broadly applicable to the civilian health care system for wound care, especially against MDR infections. The Contractor may collaborate with the Walter Reed Army Institute of Research (WRAIR) team in optimizing and validating the system. Potential funding sources include Medical Technical Enterprise Consortium and Congressionally Directed Medical Research Programs’ mechanisms including the Peer Reviewed Medical, Combat Readiness-Medical and Joint Warfighter Medical Research Programs. REFERENCES: 1. Vento TJ, Cole DW, Mende K, Calvano TP, Rini EA, Tully CC, Zera WC, Guymon CH, Yu X, Cheatle KA, Akers KS, Beckius ML, Landrum ML, Murray CK. Multidrug-resistant gram-negative bacteria colonization of healthy US military personnel in the US and Afghanistan. BMC Infect Dis. 2013;13:68. 2. Akers KS, Mende K, Cheatle KA, Zera WC, Yu X, Beckius ML, Aggarwal D, Li P, Sanchez CJ, Wenke JC, Weintrob AC, Tribble DR, Murray CK; Infectious Disease Clinical Research Program Trauma Infectious Disease Outcomes Study Group. Biofilms and persistent wound infections in United States military trauma patients: a case-control analysis. BMC Infect Dis. 2014 Apr 8;14:190. 3. Nikolich MP, Filippov AA. Bacteriophage therapy: Developments and directions. Antibiotics (Basel). 2020 Mar 24;9(3):135. 4. Luong T, Salabarria AC, Edwards RA, Roach DR. Standardized bacteriophage purification for personalized phage therapy. Nat Protoc. 2020 Sep;15(9):2867-2890. 5. Aslam S, Lampley E, Wooten D, Karris M, Benson C, Strathdee S, Schooley RT. Lessons learned from the first 10 consecutive cases of intravenous bacteriophage therapy to treat multidrug-resistant bacterial infections at a single center in the United States. Open Forum Infect Dis. 2020 Aug 27;7(9):ofaa389. KEYWORDS: Bacterial infections, multidrug resistance, bacteriophages, phages, antibacterials, phage purification, endotoxin removal, phage manufacturing

OBJECTIVE: Develop technology that stabilize bacteriophage (phage) cocktails for long-term storage and use in austere environments. The proposed material solution would aid in improving effectiveness of phage therapy, and ease of use by ensuring long-term stability of phage at a range of temperatures (-20 to 45oC). Phage spray drying, packaging in nanoparticle, hydrogel polymer matrix, or a combination thereof, or other relevant technologies will be considered. DESCRIPTION: Projected warfare dynamics during multi-domain operations (MDO) will require prolonged care (PC) and stabilization of injuries at the point of injury due to extended evacuation times. Under these circumstances, the potential for life threating infections increases, and the need for solutions that prevent and treat wound infections and stabilize the wound is crucial. The global spread of multidrug-resistant organisms (MDRO) creates challenges for all levels of care within the health care system. Military personnel wounded in combat are susceptible to infection by MDROs at a higher rate than the civilian population due to combat wounds typically being larger and accompanied by bone and soft tissue disruption, localized ischemia, as well as severe hemorrhage. The rising rates of MDROs coupled with multiple failures to develop novel classes of antibiotics has renewed interest in alternative treatments to combat MDRO wound infections including the use of phage therapies. Phage preparations are stable for years with refrigerated storage, but gradually lose activity when stored at ambient temperature. Therefore, methodologies and materials that help maintain phage stability at a range of temperatures and promote ease of use are needed to facilitate application of phage treatments during PC and at the point of injury where refrigeration is not available. In addition, materials that would aid in phage delivery to the site of injury (superficial wounds, deep wounds with bone and soft tissue disruption, severe hemorrhage, burns, etc.) and ensure sustained-release of phage would be desirable. The following features will be critical to consider when proposing phage stabilization and delivery technology or materials: 1. A universal methodology or material aiding in phage stabilization at ambient and extreme temperatures for a period of six months to one year. The technologies to be considered, but not limited to, are spray drying, encapsulation in micro or nanoparticles, and incorporation into the hydrogels. 2. Stabilized phage delivered as a powder or as a solution that is easily applied directly to the injury. 3. Multi component hydrogel or nanoparticle based bandage, injectable, etc. 4. Biocompatible natural or synthetic material, non-toxic i.e. not causing any irritation or damage to the tissue. 5. Hemostatic property is desirable for the phage stabilization material. 6. Sustained release of phages from material over time ensuring prolonged phage treatment of the injury. 7. Combination delivery of both phage and antibiotic simultaneously would be advantageous. 8. Ease of use at point of injury. PHASE I: should focus on development and validation of a universal technology for the stabilization of a wide variety of phage types to permit storage at a wide range of temperatures (-20oC to 45oC) for a period of one months. A. This could be achieved by phage drying, encapsulation in micro- or nanoparticles, emulsification in oil particles, crosslinking to stabilizing molecules like Polyethylene glycol (PEG) or any combination of those methods. If drying method was selected, excipients like trehalose, gelatin, mannitol, sucrose, or amino acids need to be tested to select ones that work best with the wide range of different types of phages at varying temperatures. If identification of universal excipients for high and low temperatures becomes challenging, two preparations for -20oC to 0oC, and 1oC to 45°C could be considered. Excipients that will be used for testing should be nontoxic, not cause irritation to the tissue, and should be on the list of chemicals approved by FDA for human use. B. Alternatively, if phages stabilized by encapsulation in particles of choice or directly into the hydrogels, the phage stability and release from these materials need to be tested at different temperatures. Use of materials that are nontoxic, biocompatible and biodegradable is preferred. Materials with tenability of phage release will have an advantage. Flexibility to use hydrogels as injectable dressing or bandage will be a plus. Once the method or material for phage stabilization is selected, the period of stability needs to be verified, and should be at minimum of one months for phase I. At the end of this phase, methods and materials for phage stabilization and materials or working prototype for phage delivery should be demonstrated. Technology needs to be tested and validated with different types of phages. PHASE II: Stability experiments should continue for the duration of phase II. After selecting the best stabilization method for a wide range of phage, the means of phage delivery needs to be identified. The final phage stabilization proof-of-concept prototype applicator for stabilized phage delivery needs to be selected and tested. This could be a small lightweight spray on device or nebulizer. Dried phage could also be stored in sealed pouches or vials to protect from harmful effects of humidity, and mixed with the carrier solution or hydrogel just before application to the wound. This could give some flexibility to add different component or filler depending on the type of wound i.e. apply to the bandage or use as injectable dressing for deep wound treatment. The system could be designed in such way that dry phage is rehydrated just before use. Sustained phage release for 1-3 days is desirable for phage delivery. PHASE III DUAL USE APPLICATIONS: Efforts during this phase should address the US Army Medical Materiel Development Activity and the office of Warfighter Protection and Acute Care small business. This phase should demonstrate evidence of commercial viability of the product. Accompanying application instructions, simplified procedures, and training materials should be drafted in a multimedia format for the use and integration of the product into the market. The end-state for this product is a commercially viable technology that will enable application of phage therapy for prevention or acceleration of healing of wound infections and will aid in warfighter health protection efforts within the Department of Defense (DoD). The final product should provide phage stability and activity of a year or greater. This product could also be broadly applicable to the civilian health care system for wound care, especially against multi-drug resistant infections. The Contractor may collaborate with the Walter Reed Army Institute of Research (WRAIR) team in optimizing and validating system. Potential funding pathways include MTEC and JWMRP. REFERENCES: 1. TRADOC Pamphlet 525-3-1: The U.S. Army in Multi-Domain Operations 2028. (United States Army Training and Doctrine Command, 2018). Or https://wrairintranet.army.mil/WRAIRCares/toolchest/HHC/2019_army_modernization_strategy_final.pdf#search=MDO 2. Jonczyk E., Klak M, Miedzybrodski R, Gorski A. The influence of external factors on bacteriophages—review. Folia Microbiol. 2011; 56: 191-200. 3. Malik, D.J., et al., Formulation, stabilization and encapsulation of bacteriophage for phage therapy. Adv. Colloid Interface Sci, 2017. 249: p. 100-133. 4. Kaur, P.; Gondil, V.S.; Chhibber, S. A novel wound dressing consisting of PVA-SA hybrid hydrogel membrane for topical delivery of bacteriophages and antibiotics. Int. J. Pharm. 2019, 572, 118779. 5. Barros, J.A.R.; Melo, L.D.R.d.; Silva, R.A.R.d.; Ferraz, M.P.; Azeredo, J.C.V.d.R.; Pinheiro, V.M.d.C.; Colaço, B.J.A.; Fernandes, M.H.R.; Gomes, P.d.S.; Monteiro, F.J. Encapsulated bacteriophages in alginate-nanohydroxyapatite hydrogel as a novel delivery system to prevent orthopedic implant-associated infections. Nanomed. Nanotechnol. Biol. Med. 2020, 24, 102145 6. Wroe, J.A., C.T. Johnson, and A.J. Garcia, Bacteriophage delivering hydrogels reduce biofilm formation in vitro and infection in vivo. J Biomed Mater Res A, 2020. 108(1): p. 39-49. KEYWORDS: Bacterial infections, multidrug resistance, phages as antibacterial therapy, therapeutic phage, phage delivery material, phage stabilization, delivery application, spray drying, hydrogels, nanoparticle, alginate, chitosan, controlled release, biodegradable

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: Design, build and test non-reciprocal microwave devices fabricated from novel materials predicted from theory and validated at frequency regime exceeding 10 THz (preferably reaching as high as 100 THz) with insertion losses less than 3dB, and isolation losses less than 20dB. Microwave devices include but are not limited to gyrators, isolators and circulators fabricated from novel materials. DESCRIPTION: Current microwave devices based on ferrites are the mainstay of telecommunications. They have increasingly high insertion losses at high frequencies, limiting their useful frequency range typically below 100 GHz. The same functionality can be designed in semiconductor-based integrated circuits but operation at a few THz is the extreme limit of those devices. Non-reciprocal microwave devices, namely gyrators, isolators and circulators fabricated from novel materials are expected to have the potential to operate at high-THz frequencies, as the electron scattering is theoretically the limiting factor for the maximum operating frequency [1, 2]. Novel materials pertinent for high frequency applications include but are not limited to some non-magnetic metals [3], degenerately doped semiconductors [4], and goniopolar materials in which the dominant charge carrier exhibits n-type conduction in one direction and p-type conduction in another [5-7]. The material’s resistivity induced insertion losses need to be taken into account in the device design and performance as well. PHASE I: Formulate complete designs for a series of high frequency devices (gyrator, or isolator, or circulator) that optimize contact technology and can have frequency response characteristics exceeding 10THz at room temperature. The choice of material, operating characteristics and design should be justified on rigorous scientific principles, using experimental results to-date and theoretical models. PHASE II: Construct and optimize device geometry with respect to S-parameters. Demonstrate optimization based on measured trans-conductance matrix and insertion losses for a series of devices showing room temperature frequency response exceeding 10 THz (preferably up to 100 THz) and high temperature capability up to 10 GHz at temperatures up to 1000 C. PHASE III DUAL USE APPLICATIONS: Commercialize electronics switching platform. Expand the capability to meet requirements for other Air Force test facilities and mature the technology for commercialization to all DoD facilities and the private sector. REFERENCES: 1. J. F. Nye, Physical Properties of Crystals: Their Representation by Tensors and Matrices. Oxford University Press: 1985. 2. D. T. Stevenson, R. J. Keyes, Measurement of Carrier Lifetimes in Germanium and Silicon. J. Appl. Phys. 1955, 26 (2), 190-195. 3. T. E. Della Torre, L. Bennett, R. Watson. "Extension of the Bloch T3/2 Law to Magnetic Nanostructures: Bose-Einstein Condensation". Physical Review Letters. 94 (14): 147210 (2005). 4. A. Walsh, J. L. F. Da Silva, and S-H. Wei, “Origins of band-gap renormalization in degenerately doped semiconductors,” Physical Review B 78, 075211 (2008). 5. B. He, Y. Wang, M. Q. Arguilla, N. D. Cultrara, M. R. Scudder, J. E. Goldberger, W. Windl, and J. P. Heremans, The Fermi Surface Geometrical Origin of Axis-dependent Conduction Polarity in Layered Materials, Nature Materials 18 568-572 (2019). 6. Y. Wang, K. G. Koster, A. M. Ochs, M. R. Scudder, J. P. Heremans, W. Windl, and J. E. Goldberger, The Chemical Design Principles for Axis-Dependent Conduction Polarity, Journal of the American Chemical Society 142, 2812 (2020). 7. B. W. Y. Redemann, M. R. Scudder, D. Weber, Y. Wang, W. Windl, and J. E. Goldberger, Synthesis Structural, end Electronic Properties of Sr1-xCaxPdAs, Inorganic Chemical Frontiers 7, 2833 (2020). KEYWORDS: Microwave; insertion loss; n-type conduction; gyrator; isolator; circulator; S-parameters

OBJECTIVE: Design, fabricate, and demonstrate a new category of subwavelength non-reciprocal circulators, including arrays of them to form photonic topological insulators, operating at microwave frequencies without the need of magnetic materials and/or magnetic bias, which are compatible with integrated circuits technology. In contrast to conventional magnetic-based non-reciprocal components, the proposed components will be based on suitably tailored time-varying networks, they shall be fully integrable within the same substrate of common microwave integrated components, such as filters, mixers, oscillators, etc…, they should be deeply subwavelength in size, and at the same time they should achieve an isolation of at least 20 dB, an insertion loss lower than 1 dB and ensure broadband operation, spanning an octave or more. Arrays of these elements to realize topological insulators should guarantee reconfigurability and inherent robustness to disorder and imperfections, ideally suited for advanced 5G and 6G wireless systems. DESCRIPTION: Non-reciprocal microwave components are the basis of many sensing, defense and communication systems. Their functionality is almost exclusively achieved through magnetic materials, which are incompatible with integrated technology [1]. Recent work has shown that biasing with EM vectors (other than the magnetic field) which are odd under time reversal, such as the electric current [2] or the linear momentum [3], can also produce a non-reciprocal effect, relaxing the requirements on magnetic materials. These alternatives, however, are currently limited by typically weak effects, requiring large volumes of operation, and in some instances large power consumption and/or narrow bandwidths. Recent efforts have shown that temporal variations synthesizing angular momentum bias can actually overcome these problems [4-5], and realize broadband, ultracompact nonreciprocal devices. The ultimate goal of this project is to fabricate and demonstrate microwave devices exhibiting strong non-reciprocal responses in a deeply subwavelength scale, without the need of magnetic materials and with adequate bandwidth for the majority of practical applications. The fabrication methods must allow realization at low cost with conventional integrated technology. We envision arrays of these elements to implement true-time-delay (TTD) beamforming networks in which reconfigurable signal routing and wideband nanosecond-scale delays enable TTD-based beam forming of ultra-wideband signals spanning DC to GHz frequencies. We also envision arrays of integrated nonreciprocal elements to realize full-duplex phased-arrays in which programmable delays within each element enable independent phased-array beam forming in transmit- and receive-modes, and whose isolation features enable full-duplex simultaneous transmission and reception of broadband radio-wave signals. These devices will enable highly reconfigurable antenna systems for e.g. radar and communication systems, enhancing the spectrum efficiency, and drastically reducing weight, cost and avoiding the need of scarce magneto-optical materials. PHASE I: In the Phase I effort, a complete design of the proposed non-reciprocal components will be formulated and fabrication procedures will be developed. The proposed designs should include realistic layouts of the proposed integrated circuitry. Full-wave / circuit simulations should be based on accepted analytical methods or rigorous numerical models. Phase I efforts should also include designs of arrays of these elements to realize topological insulators with robust and reconfigurable nonreciprocal signal transport. PHASE II: In the Phase II effort, the design and fabrication process identified in Phase I will be evolved towards the integration of the proposed non-reciprocal components in realistic circuits, and evaluation of their performance. The robust response of the circulators and topological insulators under harsh environmental conditions and their integration in electronic circuits should also be verified. PHASE III DUAL USE APPLICATIONS: The Phase III work will demonstrate the repeatability of the fabrication process and the system integrability in true-time delay and advanced wireless antenna systems. Besides the applications across all branches of the armed forces, civilian applications of this technology will be explored, including communication systems, high-fidelity circuitry, etc. REFERENCES: [1] Lax B. & Button K. J. Microwave ferrites and ferrimagnetics (McGraw-Hill, 1962). [2] Kodera, T., Sounas, D. L. & Caloz, C. Artificial Faraday rotation using a ring metamaterial structure without static magnetic field. Appl. Phys. Lett. 99, 03114 (2011). [3] Yu, Z. & Fan, S. Complete optical isolation created by indirect interband photonic transitions. Nature Photonics 3, 91-94 (2009). [4] Sounas, D. & Alù, A. Non-Reciprocal Photonics Based on Time Modulation, Nature Photonics 11,774-783 (2017) [5] Kord, A., Sounas, D. & Alù, A. Magnet-Free Microwave Nonreciprocity, Proceedings of IEEE 108, 1728-1758 (2020) KEYWORDS: Magnetic-free, Non-reciprocal, Topological integrated microwave components

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), 22 CFR Parts 120-130, which controls the export and import of defense-related material and services, including export of sensitive technical data, or the Export Administration Regulation (EAR), 15 CFR Parts 730-774, which controls dual use items. Offerors must disclose any proposed use of foreign nationals (FNs), their country(ies) of origin, the type of visa or work permit possessed, and the statement of work (SOW) tasks intended for accomplishment by the FN(s) in accordance with section 3.5 of the Announcement. Offerors are advised foreign nationals proposed to perform on this topic may be restricted due to the technical data under US Export Control Laws. OBJECTIVE: To create a scalable, highly-modular, platform that can accommodate a wide variety of synthesis strategies to produce a large number of fine/specialty chemicals relevant to the energetics community, economically and on-demand. This platform needs to be nimble enough to take advantage of new and old synthetic routes to manufacture traditional energetic materials to maximize cost and efficiency as well as put new compounds into production. DESCRIPTION: Ingredients used in explosive, propellant, and pyrotechnic formulations comprise a wide array of chemistries, including organic (C, H, N, O based) and inorganic explosives and oxidizers, polymeric and oligomeric binders, metal fuel particles, plasticizers, catalysts, burn rate modifiers and a variety of other additives. For common formulation ingredients that are used in large volume such as high explosives, bulk-production generally occurs at large-scale specialty manufacturing plants. In contrast, boutique ingredients that are used either in smaller fractional amounts in energetic formulations or are only needed for periodic production runs are increasingly difficult to procure. Often the only available sources for these critical ingredients and precursors are now OCONUS, if available at all. This dearth of US sources and market drivers strong enough to produce in-service ingredients makes it difficult to rapidly prototype new, higher performing energetic formulations. Causes of this divestiture are multifaceted and include: being unfamiliar with unique synthetic processes such as nitration and reactions on highly strained systems, a lack experience with qualification specification requirements, and a lack of flexibility when it comes to handling sporadic and highly-variable (in terms of quantity) production runs. Coupled with the necessity for scalable synthesis platforms to produce critical, already-fielded ingredients; there is a similar need for small-scale, agile production to support synthesis of new and emerging energetic ingredients for rapid formulations development leading to higher performing propellants and explosives. The time between energetic molecule discovery to scaled-up batch synthesis in sufficient quantity for formulation and safety testing can often take many years. This lack of high-throughput synthetic strategies and tools at developmental quantities severely hinders the ability to rapidly prototype, test, and transition new energetic formulations. Considering recent progress in theoretical/predictive chemical synthesis [1] [2], scalable flow chemistry methods [3] [4] [5] and microfluidics [6], in-situ diagnostics to inform synthetic strategies, feedback control [7], modular chemical processes [8] [9] [10] [11] [12], and related advances pushed by pharmaceuticals [13] [14] [15] [16] [17] [18] and other chemical industries [19] [20] [21] [22] [23], it is anticipated that safe [24], cost-effective [25], switchable, and modular chemical synthesis platforms with a small and portable footprint can now be developed to change the paradigm of “less-than-bulk” production for critical/fielded and emerging energetic ingredients and precursors. PHASE I: Design on paper a modular and scalable synthetic platform that is configurable to produce representatives of four or more classes of energetic material ingredients and/or precursors with minimal configurational changes. The platform can integrate any synthetic process (continuous flow, microfluidics, batch, etc.) that is amendable to the modular and switchable platform goals. Other emerging advances in synthesis S&T should be exploited, examples including theoretical synthesis planning strategies [1], electro- and photo-catalysis [8], etc. Selected reactions should be justified by the ability to showcase platform chemical variability. The design should outline configuration changes (time, effort, cleanup, etc.) necessary to accommodate switching between the selected ingredients/precursors and cost analysis should be prepared comparing to current production cost as appropriate. Issues of scalability should be addressed; i.e., if scaling to progressively larger quantities is accomplished by larger volume or more rapid reagent throughput, parallel modules to multiply output, or some other means. Emphasis should be placed on creating the on-demand ability to switch between target material syntheses through system modularity, accounting for material handling safety concerns. Remote operation for safety considerations should be integrated into overall design. Phase I should present two or more “modules” that perform particular chemical synthesis and/or diagnostic functions. Elements within the modules can include regulated solid and or liquid reagent addition/dispensing, mixing protocols, exquisite control of temperature, chemical separation/purification steps. Control hardware and software must be included in the overall description of each module. In situ chemical diagnostics may be an integral part of the platform modules, but at least one should be dedicated to evaluate the synthetic strategy (FTIR, HPLC, GCMS, etc.) and should back-feed into any theoretical predictive strategies. The process modules can be COTS or custom built, but should be rationally chosen to facilitate multiple kinds of reaction environments with relevance to energetic materials chemistry. Details to integrate each of the modules is not required in phase I; however, plans to integrate into the complete synthetic platform should be outlined in the overall platform paper design. Emphasis is to be placed on any modules/operations that are special to new/emerging energetic materials synthesis strategies, but are not confined to particular end products. For example, nitration reaction strategies, cage formations, feedback to theoretical synthesis tools, etc. PHASE II: Prototype the switchable, modular on-demand synthesis capability to produce representatives of four or more classes of energetic material ingredients and/or precursors based on the Phase I design. Selected ingredients should be justified by critical need and (lack of) availability, DoD importance, and ability to showcase platform chemical variability. All appropriate synthesis process modules should be physically integrated into the overall platform with appropriate in situ diagnostic modules to inform/streamline synthetic strategies. Necessary process control hardware and software should be complete and running the modules. Capability to switch between and produce the example ingredients/precursors to completion (readiness to be formulated) should be confirmed. Ingredients produced using the new synthesis platform should be characterized and compared to ingredient/precursor specifications and requirements (MIL-SPEC, MIL-STD, ASTM, etc.) where possible. Platform scalability (grams to kilograms) should be demonstrated for at least one of the example ingredients. Pursue efforts to partner with appropriate DoD or other DoD contractor points of contact (POCs) for transition of manufacturing capabilities. PHASE III DUAL USE APPLICATIONS: Work with DoD or DoD contractor energetic material production community to duplicate and integrate new modular synthetic platform(s) to best fill critical EM material needs. Efforts will be guided by Navy TPOC and other SMEs, including the Critical Energetic Materials Working Group (CEMWG), Energetic Materials ManTech, and other stakeholders. REFERENCES: [1] T. Martinez. [Online]. Available: https://muri17.sites.stanford.edu/research. [2] C. W. Coley, W. H. Green and K. F. Jensen, "Machine Learning in Computer-Aided Synthesis Planning," Accounts of Chemical Research, vol. 51, no. 5, pp. 1281-1289, 1 May 2018. [3] J. Britton, "The assembly and use of continuous flow systems for chemical synthesis," Nature Protocols, vol. 12, pp. 2423-2446, 26 October 2017. [4] J. Britton and C. L. Raston, "Multi-step continuous-flow synthesis," Chemical Society Review, vol. 46, pp. 1250-1271, 2017. [5] J. Wegner, S. Ceylan and A. Kirschning, "Flow Chemistry – A Key Enabling Technology for (Multistep) Organic Synthesis," Advanced Synthesis & Catalysis, vol. 354, no. 1, pp. 17-57, 2012. [6] P. J. A. Kenis, R. F. Ismagilov, S. Takayama, G. M. Whitesides, S. Li and H. S. White, "Fabrication inside Microchannels Using Fluid Flow," Accounts of Chemical Resesarch, vol. 33, no. 12, pp. 841-847, 8 September 2000. [7] B. J. Reizman and J. F. Klavs, "Feedback in Flow for Accelerated Reaction Development," Accounts of Chemical Research, vol. 49, no. 9, pp. 1786-1796, 15 August 2016. [8] M. Elsherbini and T. Wirth, "Electroorganic Synthesis under Flow Conditions," Accounts of Chemical Research, vol. 52 , no. 12, p. 3287–3296, 2019. [9] Y.-H. Kim, L. K. Park, S. Yiacoumi and C. Tsouris, "Modular Chemical Process Intensification: A Review," The Annual Review of Chemical and Biomolecular Engineering, vol. 8, pp. 359-380, June 2017. [10] J. A. Selekman, J. Qiu, K. Tran, J. Stevens, V. Rosso, E. Simmons, Y. Xiao and J. Janey, "High-Throughput Automation in Chemical Process Development," Annual Review of Chemical and Biomolecular Engineering, vol. 8, pp. 525-547, 2017. [11] N. Krasberg, "Selection of Technical Reactor Equipment for Modular, Continuous Small-Scale Plants," Processes, vol. 2, no. 1, pp. 265-292, 10 March 2014. [12] M. Baumann, I. R. Baxendale, S. V. Ley, N. Nikbin, C. D. Smith and J. P. Tierney, "A modular flow reactor for performing Curtius rearrangements as a continuous flow process," Organic & Biomolecular Chemistry, vol. 6, no. 9, pp. 1577-1586, 12 March 2008. [13] B. J. Doyle, P. Elsner, B. Gutman, O. Hannaerts, C. Aellig, A. Macchi and D. M. Roberge, Mini-Monoplant Technology for Pharmaceutical Manufacturing, Washington, DC: American Chemical Society, 2020. [14] R. Porta, M. Benaglia and A. Puglisi, "Flow chemistry: recent developments in the synthesis of pharmaceutical products," Organic Process Research & Development, vol. 20, no. 1, pp. 2-25, 2016. [15] S. L. Lee, T. F. O'Connor, X. Yang, C. N. Cruz, S. Chatterjee, R. D. Madurawe, C. M. V. Moore, L. X. Yu and J. Woodcock, "Modernizing Pharmaceutical Manufacturing: from Batch to Continuous Production," Journal of Pharmaceutical Innovation, vol. 10, p. 191–199, 2015. [16] D. M. Roberge, B. Zimmermann, F. Rainone, M. Gottsponer, M. E. Eyholzer and N. Kockmann, "Microreactor Technology and Continuous Processes in the Fine Chemical and Pharmaceutical Industry: Is the Revolution Underway?," Organic Process Research & Development, vol. 12, no. 5, pp. 905-910, 2008. [17] L. Malet-Sanz and F. Susanne, "Continuous flow synthesis. A pharma perspective," Journal of medicinal chemistry, vol. 55, no. 9, pp. 4062-4098, 2012. [18] M. Baumann, T. S. Moody, M. Smyth and S. Wharry, "A Perspective on Continuous Flow Chemistry in the Pharmaceutical Industry," Organic Process Research & Development, vol. 20, no. 10, p. 1802–1813, 2020. [19] N. Krasberg, L. Hohmann, T. Bieringer, C. Bramsiepe and N. Kockmann, "Selection of Technical Reactor Equipment for Modular, Continuous Small-Scale Plants," Processes, vol. 2, no. 1, pp. 265-292, 2014. [20] "The Concept of Chemical Generators: On-Site On-Demand Production of Hazardous Reagents in Continuous Flow," Accounts of Chemical Research, vol. 53, no. 7, pp. 1330-1341, 2020. [21] "Advanced-Flow Reactors," Corning, [Online]. Available: https://www.corning.com/worldwide/en/innovation/corning-emerging-innovations/advanced-flow-reactors.html. [Accessed 2 February 2021]. [22] J. Zhang, C. Gong, X. Zeng and J. Xie, "Continuous flow chemistry: new strategies for preparative inorganic chemistry," Coordination Chemistry Reviews, vol. 324, pp. 39-53, 1 October 2016. [23] A. I. o. C. Engineers, "The Rapid Advancement in Process Intensification Deployment (RAPID) Institute," American Institute of Chemical Engineers, [Online]. Available: https://www.aiche.org/rapid/projects/list?field_focus_area_tid%5B%5D=118156&combine=#views-exposed-form-rapid-projects-page. [Accessed 2 February 2021]. [24] "Taming hazardous chemistry by continuous flow technology," Chemical Society Reviews, vol. 45, no. 18, pp. 4892-4928, 25 July 2016. [25] S. D. Schaber, D. I. Gerogiorgis, R. Ramachandran, J. M. B. Evans, P. I. Barton and B. L. Trout, "Economic Analysis of Integrated Continuous and Batch Pharmaceutical Manufacturing: A Case Study," Industrial & Engineering Chemistry Research, vol. 50, no. 17, p. 10083–10092, 2011. KEYWORDS: Energetic Materials; Energetic Ingredients; Critical Chemicals; Chemical Synthesis; Explosives; Oxidizers; Propellants; Pyrotechnics

OBJECTIVE: Develop, optimize, and demonstrate electrical tunneling-based nanophotonic devices that can sense and emit frequency-tunable infrared light at room temperature through the epsilon-near-zero phenomenon. DESCRIPTION: The Department of Defense (DoD) has an enduring need for imaging systems that operate across infrared (IR) frequencies with low size, weight, power, and cost (SWAP-C). A critical SWAP-C requirement for future systems is the ability to operate at ambient temperature. Recent work shows that tunnel diodes based on metal-insulator-metal (MIM) rectenna structures can convert infrared light into an electrical signal, but efforts have focused on broadband light harvesting, rather than spectrally resolved IR imaging. [1 – 3] Compound semiconductors, such as cadmium oxide, exhibit low losses at IR frequencies and support zero-index phenomena like epsilon near-zero (ENZ) polaritonic modes. [4 – 6] Salient features of ENZ modes—coherent perfect absorption and extreme field enhancement [6]—are ideal characteristics for an absorber layer in a MIM rectenna. Through choice of material and doping, ENZ modes are tunable across the IR, from 1 – 30 microns [4], narrow-band [5], amenable to charge and energy transfer at ultra-fast time scales [7], and support strong non-linear optical behaviors [8]. MIM diodes run in reverse bias emit light through inelastic electron tunneling, [9 – 11] so ENZ-based tunnel diodes could also serve as new, tunable IR light sources. PHASE I: Develop concepts supported with feasibility modeling for ENZ-based MIM IR (1) imaging and (2) emitting devices measuring 10x10 pixels, with each pixel separately able to detect or emit four different wavelengths between 2 – 14 microns, each with a maximum bandwidth of 100 meV. Design for an operating temperature range of -20 – 50˚C. The applied voltage needed to detect IR light should be less than 1V (ideally 0V). Outline the techniques and procedures to fabricate and characterize these devices. Describe a control scheme with which to achieve solid-state beam steering (e.g., phased array) for the emitter device. A highly desirable objective is to experimentally demonstrate IR detection and/or emission at a single wavelength between 2 – 14 microns using a single-pixel breadboard MIM device. Demonstrate operational temperature of 0 ˚C or above (25 ˚C desired). Characterize optoelectronic performance characteristics—100 meV maximum bandwidth and minimum 3dB minimum signal-to-noise ratio are desired. PHASE II: Based on Phase 1 results, fabricate, test, and demonstrate at least one operational ENZ-based MIM IR imaging device prototype, and at least one operational ENZ-based MIM IR emitter device prototype. Imaging and emitter shall operate fully across a temperature range of -20 – 50˚C, with 100 meV maximum bandwidth and 3dB minimum signal-to-noise ratio at each wavelength. Response times shall be on the order of 100 ps or less. Fully characterize the optoelectronic performance of the imaging device (e.g., I-V curves, signal-to-noise ratios vs. temperature, efficiency, detectivity or D*, etc.) and of the emitter device (power and spectral output, efficiency, etc.). The emitter shall demonstrate an optical phase array that can achieve beam steering over a 60˚ solid angle. Compare performance against existing commercial IR detectors and emitters that operate at ambient temperatures. PHASE III DUAL USE APPLICATIONS: Demonstrate ENZ-based IR imaging and emitting devices that will be appropriate for integration with existing and/or future DoD IR imaging and signaling systems. Partner with DoD laboratories and interested industrial parties to further define necessary capabilities and metrics, as well as the research and development necessary for commercialization and adoption. Expand devices to 100-by-100 pixels or more, and 25 frequencies or more. Achieve response times of 6 – 50 femtoseconds for 2 – 14 micron light. Consideration will include SWAP-C in design. REFERENCES: 1. P. Periasamy et al., “Fabrication and Characterization of MIM Diodes Based on Nb/Nb2O5 Via a Rapid Screening Technique”, Adv. Mater. 23 (2011), 3080 – 3085. 2. J. Shank et al., “Power Generation from a Radiative Thermal Source Using a Large-Area Infrared Rectenna”, Phys. Rev. Applied, 9 (2018), 054040. 3. P.S. Davids et al., “Electrical Power Generation from Moderate-Temperature Radiative Thermal Sources”, Science, 367 (2020), 1341 – 1345. 4. N. Kinsey et al., “Near-Zero-Index Materials for Photonics”, Nat. Rev. Mats., 4 (2019), 742 – 760. 5. E. Sachet et al., “Dysprosium-Doped Cadmium Oxide as a Gateway Material for Mid-Infrared Plasmonics”, Nat. Mater., 14 (2015) 414 – 420. 6. S. Campione et al., “Theory of Epsilon-Near-Zero Modes in Ultrathin Films”, Phys. Rev. B., 91 (2015) 121408(R). 7. J.A. Tomko et al., “Long-Lived Modulation of Plasmonic Absorption by Ballistic Thermal Injection”, Nat. Nanotech., 16 (2021) 47 – 51. 8. Y. Yang et al., “High-Harmonic Generation from an Epsilon-Near-Zero Material”, Nat. Phys., 15 (2019) 1022 – 1026. 9. M. Parzefall et al., “Antenna-Coupled Photon Emission from Hexagonal Boron Nitride Tunnel Junctions”, Nat. Nanotech., 10 (2015) 1058 – 1064. 10. P. Wang et al., “Reactive Tunnel Junctions in Electrically Driven Plasmonic Nanorod Metamaterials”, Nat. Nanotech., 13 (2018) 159 – 164. 11. H. Qian et al., “Efficient Light Generation from Enhanced Inelastic Electron Tunneling”, Nat. Photon., 12 (2018) 485 – 488. KEYWORDS: Infrared sensors; nanophotonics; epsilon-near-zero materials; tunneling diodes

OBJECTIVE: Develop highly sensitive tunable sensors in microwave, THz, and IR regions via Josephson Junctions, based on twisted 2D heterostructures of graphene Moiré superconductors. DESCRIPTION: In order to address the future demands on sensitivity, robustness and overall multi-functionality, future multi-domain sensing systems in all environments will need highly sensitive sensors with tunable spectral characteristics. A recently emerged novel Moiré quantum matter paradigm using two graphene sheets twisted by an angle close to a theoretically predicted ‘magic angle’, can result in flat band structure near the Dirac point, giving rise to a strongly-correlated electronic system and enabling quantum phases, such as correlated insulators, Chern insulators, superconductivity, etc. Further advances in modeling, design, fabrication and measurement of twisted 2D heterostructures are needed for better understanding these phenomena in order to be employed for microwave, THz, and far-IR detectors with improved sensitivity by up to three orders of magnitude over current capabilities [a,b]. The goal of this technology development is to design, develop and demonstrate a prototype Moiré based tunable detector with improved sensitivity by at least an order of magnitude. While the overall goal is to address the need for advanced detection systems (e.g., microwave, THz, or IR) by exploring new phenomena in Moiré quantum materials, here the focus is on the approach of tunable Josephson junction based on graphene Moiré superconductors. PHASE I: Develop necessary computational methods, rigorously model the proposed heterostructure-based sensor system, and formulate and provide a detailed plan for fabricating and demonstrating the twistronics-based sensor system. Summarize the recent scientific and technical progress being relied on, relevant to the measurement, modeling, design, and fabrication of twisted 2D heterostructure-based devices. Detail the designs improving microwave, THz, and far-IR detector technology via the Moiré superconductivity, and develop and present modeling and quantitative arguments to establish feasibility. PHASE II: Construct and demonstrate prototype devices based on Phase 1 feasibility and design. Apply RF techniques to develop Josephson sensors based on Moiré superconductivity [c]. Exploit and demonstrate the gate-tunable superconductivity in the twisted Moiré system as a unique opportunity to develop a sensitive detector for lower-energy photons, and for broader bandwidth, that makes it feasible for hyperspectral imaging. Employ higher ratios of kinetic inductance (higher than conventional superconductivity) and demonstrate high signal-to-noise ratios. The twisted Moiré system consisting of only two [d] or three [e] active material layers has an extremely small heat capacity, on the order of one Boltzmann constant, which can enable a giant thermal response from even just a single photon. Address practical issues of making consistent twist angles between layers in a reproducible way using a scalable process and incorporate into an atomically thin twisted moiré system that has promise of providing the ultimate material platform for microwave and THz sensing. PHASE III DUAL USE APPLICATIONS: The proposer is required to obtain funding from either the private sector, a non-STTR Government source, or both, to develop the prototype into a viable product or non-R&D service for sale in military or private sector markets. STTR Phase III refers to work that derives from, extends, or completes an effort made under prior STTR funding agreements, but is funded by sources other than the STTR Program. Phase III work is typically oriented towards commercialization of STTR research or technology. REFERENCES: a. Observation of the Dirac fluid and the breakdown of the Wiedemann-Franz law in graphene, Crossno, Shi, Wang, Liu, Harzheim, Lucas, Sachdev, P. Kim, Taniguchi, Watanabe, Ohki, Fong, Science 351, 1058 (2016). b. Microwave characterization of Josephson junction arrays: Implementing a low loss superinductance, Masluk, Kamal, Minev, Devoret, Phys. Rev. Lett. 109, 137002 (2012). c. Magic-angle bilayer graphene nanocalorimeters: toward broadband, energy-resolving single photon detection, Seifert, X. Lu, Stepanov, Durán Retamal, Nano Lett. 20, 3459 (2020). d. Tunable spin-polarized correlated states in twisted double bilayer graphene, Liu, T Taniguchi, A Vishwanath, P Kim, Nature 583, 221-225 (2020). e. Correlated Superconducting and Insulating States in Twisted Trilayer Graphene Moiré of Moiré Superlattices, Tsai, Luskin, Kaxiras, Wang, et al, arXiv:1912.03375. f. Graphene-based Josephson junction microwave bolometer, Lee, Taniguchi, Watanabe, Kim, Englund, Fong, Nature 586, 20 (2020). g. Josephson-junction infrared single-photon detector, Walsh, Jung, Lee, Efetov, Wu, Kim, Fong, arXiv:2011.02624. KEYWORDS: 2-D heterostructure; Graphene; Moiré quantum matter; Twistronics; single photon detection; Superconductivity

OBJECTIVE: Create a data repository for population migration data and modeling for public use consisting of data that can be integrated from diverse open sources, codebooks, computational models with source code, and a tool suite to enable researchers to develop new analytic models as well as upload new data, codebooks, and computational models to support predictive and causal modeling of global population migration patterns alongside causes and consequences of population migration, as well as mitigating factors that determine those patterns. DESCRIPTION: There are no existing comprehensive tools to predictively model the impact of the increasing incidence of population migration due to environmental change and human-caused crises, which poses challenges for global security. Large-scale environmental changes such as floods, earthquakes, and droughts, can drive population migration; so to can war and regime change. Both types of events can precipitate impacts on health, crime, and sociopolitical instability as humans relocate to access critical resources. Migration impacts both in- and out-migration regions. Receiving regions for migrants experience stresses on social institutions and infrastructure (e.g., economic, healthcare, education, political systems), and can exacerbate already-present sociocultural conflicts as new cultures come into contact with the receiving culture. Out-migration regions suffer from the loss of human and social capital leading to a crippling of their social institutions and infrastructure, which are precursors to a fragile state. The net outcome is a potential for geopolitical and social conflict that poses a risk to global stability. At the same time, there are opportunities to catalyze new markets that can jump-start economic growth, generate increased cooperation across diverse cultural groups, and introduce new forms of human and social capital to a region receiving migrants. If impacts of naturally occurring environmental change and human-caused crises on migration patterns can be predicted, potential out-migration regions can mitigate the likelihood of mass exoduses of their population through proactive planning, and in-migration regions can prepare for the impact of the new migrants on their culture and infrastructure. To address this issue, scientists across academia and the private sector have begun to create new datasets and mine existing open source data to develop models to predict patterns of population migration and the causes and consequences of these patterns. These scientific efforts, however, require intensive searching for and assessment of diverse data (e.g., meterological, event, demographic, ethnographic, geospatial data) from different sources, that are structured in different ways (e.g., qualitative vs. quantitative data). Moreover, modeling the dynamic relationships between natural and human-induced change and population dynamics is challenging due to both temporal and spatial parameters, alongside human and collective decision-making that determine if/how populations will move in the face of crises. What is needed is a tool to house or link to relevant data sets and computational models to capture interdependencies between human social systems and environmental and human-induced events. Such a tool will facilitate development, validation, and replicability of predictive models of population migration under duress and improve the capacity of policymakers and decision leaders to identify potential hot-spots in advance, develop strategic plans to mitigate adverse consequences such as stress on the social infrastructure and cross-cultural conflict, and turn the population dynamics into opportunities for economic growth and cultural enrichment. The aim of this topic is to create a public open-source sustainable platform to integrate diverse data sources and predictive models of population migration resulting from crises; encourage a community of scientists, policymakers, and decision leaders to share data and models; and motivate cross-disciplinary collaboration to generate basic and applied advances to better predict, address the adverse impacts of, and optimize opportunities related to crises-induced population migration. PHASE I: Develop a prototype of a tool to integrate data, models, and analytics depicting patterns of population migration due to human-induced or environmental events, including a data preparation protocol for ingestion of time series environment or climate data and human-caused crises event data, as well as data from at least two other open sources of population, migration, demographic, or ethnographic data for proof of concept (i.e., test data pool), with at least one source of structured data and one source of unstructured data; develop the protocol for importing computational models that can be applied to an integrated subset of the test data as defined by the data preparation protocol. The data and model formats must be compatible with Department of Defense (DoD) standards to ensure interoperability with other DoD datasets. Phase 1 should also include the development of a prototype tool interface that includes computational output of analyses of data sets included in the tool as well as visualization of those analytic results. A usability test of the prototype tool with a sample of researchers should be conducted and a report issued detailing the analysis of the test. PHASE II: Expand the data pool to include at least a dozen open sources of data (both structured and unstructured) uploaded by researchers outside the performer’s team as well as data sources linked to the tool from existing open source data (e.g., census data, general social survey data, human research area files) to demonstrate the versatility of the ingestion protocol and efficiency of the modeling/analytics component of the tool. Refine the user interface to address improvements discovered in the Phase 1 usability test. Test the refined and expanded tool on a large sample of researchers, to include government scientists and analysts, as well academic and private sector researchers. (1) Develop a continuity plan to enable ongoing viability of the tool subsequent to the STTR award; the continuity plan must describe how/where the tool would reside for broad accessibility (i.e., identify a durable plan and host for the tool capable of sustaining it without additional government funding) and how it will be maintained and refreshed beyond the scope of the STTR award; (2) Generate commercialization plan to ensure continued public access to open-source databases within the tool, while providing a for-profit pathway and/or licensing plan to leverage market demand for proprietary elements of the observatory including computational models, visualization and analytic algorithms, and consulting services. PHASE III DUAL USE APPLICATIONS: Additional data capabilities and models can be added to the tool, including health data, crime/deviance data, event data (e.g., from news reports), climate and disaster data, utility data (e.g., energy use trends, transportation routes, communication networks), epidemiological models, network models, and survival models to enhance the broad applicability of the tool across sectors interested in population dynamics to increase commercialization potential. REFERENCES: An, Li (2012). Modeling human decisions in coupled human-natural system: Review of agent-based models. Ecological Modelling, 229(24), 25-36. Berhin, II, I Blasi Valduga, J Garcia, & J. Bltazzar Salgueirrinho, O de Andrade Guerra (2017). Climate change and forced migrations: An effort toward recognizing climate refugees. Geoforum, 84, 147-150. Cattaneo, C, M Bein, CJ Frolich, D Kniveton, I Martinez-Zarzoso, M Mastrorillo, K. Millock, E, Piguet, and B. Schraven (2019). Human Migration in the Era of Climate Change. Rev. of Env Econ & Policy, 13,(2), 189-206 Gopalakrishnan, S., C. E. Landry, & M. D. Smith. (2018). Climate change adaptation in coastal environments: modeling challenges for resource and environmental economists. Rev of Env Econ & Policy, 12, 48–68. Muneepeerakul, R. J Anderies (2017). Strategic behaviors and governance challenges in social-ecological systems. Earth’s Future, 865-876. Thalheimer, L., & Heslin, A. (2020). The picture from above: Using satellite imagery to overcome methodological challenges in studying environmental displacement. Oxford Monitor of Forced Migration, 8(2). Wouter Botzen, WJ, O Descheens, & M Sanders (2018). The economic impacts of natural disasters: A review of models and empirical Studies, Rev. of Env Econ & Impacts, 13(2), 167-188. KEYWORDS: environment; analysis; conflict; data archive

OBJECTIVE: Utilize the fundamental understanding of biological propulsion to develop and demonstrate a highly efficient, quiet underwater vehicle design optimized for range, endurance and speed. The design should be based on rigorous analysis and leverage results from recent computational and experimental fluid dynamics investigations. Since unmanned platforms do not have human habitation requirements, new design spaces are available that might include novel propulsors (e.g. fins, tails or other bio-inspired mechanisms) that utilize unsteady propulsion, body shape and body deformation. This STTR will provide increased capabilities for UUVs based on the technology push from the fundamental understanding we now have of how biological swimmers propel themselves efficiently and quietly. DESCRIPTION: There is an ongoing desire for greater range, endurance and speed for unmanned underwater vehicles (UUVs). UUV designs that are informed by biology offer the potential for improved performance. Certain aquatic animal species are capable of much higher maximum speeds than man-made UUVs. Furthermore, other species are capable of swimming with a very low cost-of-transport (COT) (energy per mass per distance travelled) compared to man-made UUVs [1], and with much reduced acoustic signatures. The performance of aquatic animals with respect to swimming speed, efficiency and quietness can serve as benchmarks to direct the development of biologically-informed UUVs (BIUUV) with enhanced capabilities. Unlike manned submarines, unmanned underwater vehicles are not constrained in shape by human habitability requirements. Therefore, a significant new design space is accessible for UUVs, for example, in body shape, body deformation and type of propulsor. This new design space may provide advantages in terms of range, stealth, endurance and speed. A great deal of progress has been made in the fundamental understanding of the hydrodynamics of propulsion of aquatic animals, in both experimental and computational investigations [2]: Flexibility and viscous effects, profile and planform shapes can impact both thrust and efficiency [2], and so do the dynamics: combined heave and pitch motions and phase difference, as well as non-sinusoidal gaits and intermittent actuation. [3] To explore high-frequency performance space, a platform based on yellowfin tuna (Thunnus albacares) and Atlantic mackerel (Scomber scombrus) was designed and tested [3]. Body kinematics, speed, and power were measured at increasing tail beat frequencies, while experimental analyses of freely swimming tuna and mackerel allowed comparison with the tuna-like robotic system. Batoid fish such as manta rays (Manta birostris) and cownose rays (Rhinoptera bonasus) being notable for their fast, efficient swimming and high maneuverability, a ray-inspired underwater vehicle – the MantaBot – has been the subject of extensive investigation. [4] Scaling laws that elucidate the dominant flow physics for pitching foils have been developed and can provide guidance for the design of bio-inspired propulsive systems. [5] These findings now enable development of underwater platforms that exploit the fundamental knowledge acquired from such studies above. This Topic will pursue the design and demonstration of innovative, bio-inspired unmanned underwater platforms with capabilities well beyond the state of the art for range, stealth, endurance and speed. The overall design objective and targeted capabilities apply to an untethered UUV, between 1-5 meters in length, and capable of operating in salt water to depths of 50 ft, to support Phase II and Phase III testing. Conventional designs such as propellers and jets are not in scope for this topic. The design will be evaluated according to measurable performance criteria: – Speed: minimum of 4 meters/sec, with an objective of 6 meters/sec or higher. – Cost of Transport (COT): proposed project should optimize the COT and demonstrate clear improvement over the state-of-the-art, for the chosen vehicle length and speed. – Quietness: underwater acoustic energy generated by the vehicles, should be minimized by design. – Power: the design shall not rely on energy harvesting from the environment, but can incorporate methods of energy recovery from mechanical motion itself. It shall utilize state of the art energy storage (R&D into energy storage is outside the scope of this topic). – Power Transmission: the design shall use state of the art means of transferring power to the propulsor. Successful proposals will explain how the proposed means of power transmission will contribute to meeting the performance objectives. The scope of this Topic includes, but is not limited to, R&D into artificial muscles supporting the performance criteria. – Sensing and control: approaches to sensing and dynamic control that optimize hydrodynamic interactions and flow physics are in-scope for this Topic. A successful proposal will explain how these will contribute to meeting the performance objectives. – Path Planning: use off-the-shelf components to provide sufficient capability for the BIUUV to perform the demonstrations during Phase II and Phase III, including straight line tracks and simple maneuvers sufficient to demonstrate speed, range, endurance and acoustics. R&D into path planning is outside the scope of this topic. – Vehicle cost: estimated costs of scaled manufacturing will be a factor in the proposal evaluations, and can be used to guide material and design selection. PHASE I: The small business shall demonstrate the feasibility of the concept in meeting Navy needs for a BIUUV that is capable of meeting the desired performance objectives, via a variety of possible methods: model-scale experiments, computation, or previous results and data, as well as fabrication of components (if feasible) for any difficult-to manufacture component. This body of evidence shall, as much as possible, support the predicted speed and COT performance and other high risk aspects of the design. The Phase I should convincingly show that the design is sufficiently robust to undergo the testing described in Phase II and Phase III. PHASE II: The small business shall fabricate a prototype, according to the requirements stated in this Topic, and evaluate the design via in-water tests conducted at a facility arranged by the small business. These tests shall target the listed performance objectives, such as speed, range, endurance, COT and quietness, via untethered operations. At a minimum, the prototype testing shall consist of (1) basic operability testing, (2) speed trials, (3) range/endurance trials, and (4) acoustic testing. The small business may propose other tests as needed to demonstrate the benefits of their design, and perform analyses to establish reliability, identify areas in need of further improvement if necessary, as well as analyze manufacturing scalability in order to transition the design into a useful product for the Navy PHASE III DUAL USE APPLICATIONS: The small business shall apply the knowledge gained in Phase II to build an advanced prototype BIUUV. The small business shall test the advanced prototype according to the Phase II test goals. The small business shall support Government testing of the advanced prototype BIUUV. REFERENCES: 1. Frank E Fish, Advantages of aquatic animals as models for bio-inspired drones over present AUV technology. 2020 Bioinspir. Biomim. 15 025001. 2. Alexander J. Smits, Undulatory and oscillatory swimming, Journal of Fluid Mechanics, 2019, and references therein. 3. J. Zhu, C. White, D. K. Wainwright, V. Di Santo, G. V. Lauder, H. Bart-Smith, Tuna robotics: A high-frequency experimental platform exploring the performance space of swimming fishes. Sci. Robot. 4, 4615 (2019) 18 September 2019. 4. Geng Liu, Yan Ren, Jianzhong Zhu, Hilary Bart-Smith, Haibo Dong. Thrust producing mechanisms in ray-inspired underwater vehicle propulsion. Theoretical and Applied Mechanics Lett 5(2015) 54–57. 5. Fatma Ayancik, Qiang Zhong, Daniel B. Quinn, Aaron Brandes, Hilary Bart-Smith and Keith W. Moored, Scaling laws for the propulsive performance of three-dimensional pitching propulsors, J. Fluid Mech. (2019), vol. 871, pp. 1117-1138. KEYWORDS: Biological propulsion; unmanned underwater vehicle; biologically-inspired design

The technology within this topic is restricted under the International Traffic in Arms Regulation (ITAR), which controls the export and import of defense-related material and services. Offerors must disclose any proposed use of foreign nationals, their country of origin, and what tasks each would accomplish in the statement of work in accordance with section 5.4.c.(8) of the solicitation. Additionally, Offerors will describe compliance mechanisms offerors have in place or will put in place to address any ITAR issues that arise during the course of agreement administration. OBJECTIVE: The objective of this topic is to develop applied research toward an innovative capability to leverage artificial intelligence to communicate appropriate targeting solutions for Stand Off Precision Guided Munitions leveraging a common autonomy architecture. DESCRIPTION: Proposers will develop innovative recommendations and concepts for a machine learning modular architecture for non-line of sight targeting and communication from small Unmanned Aerial System (sUAS) / Munitions to a Common Launch Tube (CLT) compliant Stand Off Precision Guided Munition. The focus of this topic is to develop and coordinate an accurate and autonomous method of dynamic targeting for a target where traditional methods of Global Positioning System (GPS) or laser designation may not be available. The concepts should include how a “swarm” of sUASs (under the cover of buildings or foliage) could develop and communicate (via a Mission Data Link) precise targeting to a munition for GPS permissive, degraded, and denied environments. If this effort progresses beyond this feasibility study, the Government may provide an open architecture to be use for a potential SBIR Phase II. PHASE I: Conduct a feasibility study to assess what is in the art of the possible that satisfies the requirements specified in the above paragraphs entitled “Objective” and “Description.” The objective of this USSOCOM Phase I SBIR effort is to conduct and document the results of a thorough feasibility study (“Technology Readiness Level 3”) to investigate what is in the art of the possible within the given trade space that will satisfy a needed technology. The feasibility study should investigate all options that meet or exceed the minimum performance parameters specified in this write up. It should also address the risks and potential payoffs of the innovative technology options that are investigated and recommend the option that best achieves the objective of this technology pursuit. The funds obligated on the resulting Phase I SBIR contracts are to be used for the sole purpose of conducting a thorough feasibility study using scientific experiments and laboratory studies as necessary. Operational prototypes will not be developed with USSOCOM SBIR funds during Phase I feasibility studies. Operational prototypes developed with other than SBIR funds that are provided at the end of Phase I feasibility studies will not be considered in deciding what firm(s) will be selected for Phase II. PHASE II: Develop, install, and demonstrate a prototype system determined to be the most feasible solution during the Phase I feasibility study on sUAS/Munition Teaming for Advanced Precision Strike. PHASE III DUAL USE APPLICATIONS: This system could be used in a broad range of military applications where a requirement exists for edge communication between AI systems in a common architecture. This may be for rapid employment of emerging technologies or interoperability across the battle space. REFERENCES: 1. Vimeo, SOCOM S&T Futures Homepage, Artificial Intelligence for Small Unit Maneuver (AISUM), https://vimeo.com/showcase/7006292 KEYWORDS: Weapons; Missile; Munition; Special Operations; Standoff; Precision; Guidance; Artificial Intelligence; Machine Learning; Denied; Autonomy; Contested; Common Launch Tube.