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High Temperature Oxidation Resistant Coatings Integrated with Carbon/Carbon Hot Structures

Award Information
Agency: National Aeronautics and Space Administration
Branch: N/A
Contract: 80NSSC18P1973
Agency Tracking Number: 184183
Amount: $124,728.00
Phase: Phase I
Program: SBIR
Solicitation Topic Code: H5
Solicitation Number: SBIR_18_P1
Timeline
Solicitation Year: 2018
Award Year: 2018
Award Start Date (Proposal Award Date): 2018-07-27
Award End Date (Contract End Date): 2019-02-15
Small Business Information
4914 Moores Mill Road
Huntsville, AL 35811-1558
United States
DUNS: 799114574
HUBZone Owned: No
Woman Owned: No
Socially and Economically Disadvantaged: No
Principal Investigator
 Anatoliy Shchetkovskiy
 El-Form Director
 (256) 851-7653
 ashchetkovskiy@plasmapros.com
Business Contact
 Angela Hattaway
Phone: (256) 851-7653
Email: ahattaway@plasmapros.com
Research Institution
N/A
Abstract

The development of new hypersonic capabilities is important for the United States. In the near-term, application of hypersonic research and technologies is likely to be on enhanced defense systems, but this could eventually expand to include improved access to space capabilities that would directly benefit NASA. Hypersonic vehicle nose tips and leading edges require high thermal shock resistance combined with bending strength at a high angle of attack. Due to their high specific modulus, high fracture toughness and thermal conductivity, good thermal shock resistance, and excellent high temperature strength, advanced carbon/carbon (C/C) composites are considered as structural materials for atmospheric entry vehicles. C/C composites have densities in the range 1.6–2.0 gm/cm3, much lower than those of metals and ceramics, and can significantly reduce hypersonic vehicle component weight. During reentry into the atmosphere, a vehicle nose tip and leading edges can encounter extreme convective and radiative heating loads with the very high temperatures. Unfortunately, C/C composites start to rapidly oxidize above 700° which restricts their engineering applications in air. Multiple concepts of oxidation resistant coatings are currently in development for carbon/carbon composite protection. Most of the coatings are based on silicon carbide in combination with different refractory compounds. Thermal analyses indicate that portions of the C/C horizontal control surface and nose leading edge of the Mach 10 vehicle will experience temperatures apprmissiles, missile defense interceptors.oaching 2200°C, exceeding even the single use temperature limit of the SiC coated carbon/carbon. An oxidation protection system is proposed for C/C hot structures that is SiC free and able to meet these high temperature requirements by using oxygen barrier and refractory oxide coatings.

* Information listed above is at the time of submission. *

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