Field-Enhanced Carbon Monoxide Tolerance of Polymer Electrolyte Membrane (PEM) Fuel Cells

Award Information
Agency:
Department of Defense
Branch
Army
Amount:
$100,000.00
Award Year:
2002
Program:
STTR
Phase:
Phase I
Contract:
DAAD19-02-C-0060
Award Id:
56080
Agency Tracking Number:
44227-CH
Solicitation Year:
n/a
Solicitation Topic Code:
n/a
Solicitation Number:
n/a
Small Business Information
3 Great Pasture Rd., Danbury, CT, 06813
Hubzone Owned:
N
Minority Owned:
N
Woman Owned:
N
Duns:
050627884
Principal Investigator:
LudwigLipp
Fuel Cell Development Engineer
(203) 205-2492
llipp@fce.com
Business Contact:
RossLevine, Esq.
Director of Contracts
(203) 825-6057
rlevine@fce.com
Research Institute:
The University of Iowa
David J Skorton
305 Chemistry Bldg
Iowa City, IA, 52242
(319) 355-2132
Nonprofit college or university
Abstract
"To be commercially competitive, PEM fuel cells have to be able to run on readily available fuels. Fuel reformers are practical, but fuel cell anode catalysts are severely poisoned by small quantities of carbon monoxide from the reformer. Despite mucheffort invested into increasing CO tolerance, desired performance levels have not been achieved.Recent data has shown great promise in mitigating the effect of CO on the anode when magnetic particles are introduced into the fuel cell anode. Local magneticfields couple into kinetic pathways through spin polarization and can alter product distributions and reaction rates.The overall objective of this research is to demonstrate that incorporation of magnetic particles into the catalyst layers of an MEAincreases the CO tolerance of the anode, and to exceed state-of-the-art performance at CO levels around 100 ppm or higher, at temperatures below 100¿C. To this end, magnetic particles of different sizes will be fabricated and their physical and chemicalproperties studied. Membrane electrode assemblies will be fabricated incorporating these particles and their performance will be tested with a variety of techniques in order to gain a better understanding of the underlying mechanism and to defineperformance limits and favorable operating conditions. This project is anticipated to result in a great advancement in carbon monoxide tolerance and performance of reformate-fed hydrogen/air polymer electrolyte membrane fuel cells. This will result inincreased efficiency and lower cost of fuel cells for transportation and stationary power applications."

* information listed above is at the time of submission.

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