Quantum Calorimeters Based on HgCdTe Alloys

Award Information
Agency: National Aeronautics and Space Administration
Branch: N/A
Contract: NNX08CA23C
Agency Tracking Number: 065679
Amount: $599,955.00
Phase: Phase II
Program: SBIR
Solicitation Topic Code: S4.02
Solicitation Number: N/A
Solicitation Year: 2006
Award Year: 2008
Award Start Date (Proposal Award Date): 2007-12-21
Award End Date (Contract End Date): 2009-12-20
Small Business Information
590 Territorial Drive, Suite B, Bolingbrook, IL, 60440-4881
DUNS: 068568588
HUBZone Owned: N
Woman Owned: N
Socially and Economically Disadvantaged: N
Principal Investigator
 Jun Zhao
 Principal Investigator
 (630) 771-0203
Business Contact
 Sivalingam Sivanantan
Title: President
Phone: (630) 771-0201
Email: ssivananthan@epir.com
Research Institution
NASA's next generation of x-ray observation missions require x-ray calorimeters with superior energy resolution. Semimetallic HgTe has already proven itself as an excellent soft x-ray absorber material due to its low heat capacity. Hg0.834Cd0.166Te was shown in Phase 1 to have a heat capacity superior to that of HgTe. Hence Hg0.834Cd0.166Te-based microcalorimeter arrays are expected to have an energy resolution superior to that of HgTe-based ones. We propose the growth of single crystal Hg0.834Cd0.166Te layers by molecular beam epitaxy on Si substrates. Mercury vacancies will be filled after growth to reduce the possibility of them acting as acceptors and introducing a significant electronic heat capacity. The samples will be characterized by x-ray diffraction to assess their structural quality and crystallinity, FTIR mapping to confirm the uniformity of their energy gaps and alloy compositions, Hall measurements to assess their electrical transport properties, etch pit density counts to determine dislocation densities, transmission electron microscopy to determine microscopic structural information, and heat capacity and thermalization efficiency measurements at mK temperatures. These assessments will further test their promise as high energy resolution quantum calorimeters and will help optimize material and processing parameters. The thermal property measurements will be performed on samples specially processed to remove some or all of the Si substrates and CdTe buffer layers. Finally, the development of a broadband infrared/mm wave reflective coating will be undertaken. The produced samples will be compatible with incorporation into microcalorimeter arrays for NASA missions.

* Information listed above is at the time of submission. *

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