Electronic-Resonance-Enhanced CARS for Quantitative in-situ Nitric-Oxide Measurements in High-Pressure Combustors

Award Information
Agency:
Department of Defense
Branch
Air Force
Amount:
$99,988.00
Award Year:
2005
Program:
STTR
Phase:
Phase I
Contract:
FA9550-05-C-0096
Agency Tracking Number:
F054-012-0211
Solicitation Year:
n/a
Solicitation Topic Code:
n/a
Solicitation Number:
n/a
Small Business Information
Innovative Scientific Solutions, Inc.
2766 Indian Ripple Rd, Dayton, OH, 45440
Hubzone Owned:
N
Minority Owned:
N
Woman Owned:
N
Duns:
884812025
Principal Investigator:
Sukesh Roy
Research Scientist
(937) 255-3115
sukesh@innssi.com
Business Contact:
Larry Goss
President
(937) 429-4980
gosslp@innssi.com
Research Institution:
PURDUE UNIV.
Robert P Lucht
585 Purdue Mall
West Lafayette, IN, 47907
(765) 494-5623
Nonprofit college or university
Abstract
The primary objective of this Phase-I effort is to develop an advanced coherent anti-Stokes Raman scattering (CARS) technique for quantitative concentration measurements of nitric oxide (NO) in high-pressure flames. The objectives of the proposed work are (1) to develop and demonstrate electronic-resonance enhanced (ERE) CARS for measurements of NO in high-pressure flames, (2) to compare ERE-CARS and laser-induced fluorescence (LIF) measurements, and (3) to develop a computer code for interpreting measured signals and quantifying NO concentrations. The proposed method has three very significant advantages over the conventional LIF-based measurements of NO: (1) in ERE-CARS the signal comes out as a laser-like beam, (2) for a given temperature and NO mole fraction, the LIF signal will remain the same or decrease slightly as the pressure increases whereas in ERE-CARS that the signal will increase as the square of the pressure as the pressure increases, and (3) CO2 and H2O will not interfere with the ERE-CARS signal, because the signal is generated with significant intensity only when the conditions of Raman resonance and electronic resonance are simultaneously met. Consequently, the ERE CARS technique offers the potential for much higher selectivity compared to LIF detection of NO in high-pressure flames.

* information listed above is at the time of submission.

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