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Development of Surface Reaction Mechanism for C-SiC-SiO2-Rubber Composite Oxidation in Extreme Oxidizing Condition

Award Information
Agency: Department of Defense
Branch: Navy
Contract: N68335-10-C-0373
Agency Tracking Number: N10A-005-0148
Amount: $69,969.00
Phase: Phase I
Program: STTR
Solicitation Topic Code: N10A-T005
Solicitation Number: 2010.A
Timeline
Solicitation Year: 2010
Award Year: 2010
Award Start Date (Proposal Award Date): 2010-07-30
Award End Date (Contract End Date): 2011-02-28
Small Business Information
215 Wynn Dr., 5th Floor
Huntsville, AL 35805
United States
DUNS: 185169620
HUBZone Owned: No
Woman Owned: Yes
Socially and Economically Disadvantaged: No
Principal Investigator
 Debassis Sengupta
 Senior Principal Scientis
 (256) 726-4800
 tsb@cfdrc.com
Business Contact
 Deb Phipps
Title: Senior Contracts Speciali
Phone: (256) 726-4884
Email: dap@cfdrc.com
Research Institution
 The Pennsylvania State University
 David Richardson
 
Office of Engineering Research 101 Hammond Building
University Park, PA 16802
United States

 (814) 863-6185
 Nonprofit college or university
Abstract

The purpose of this STTR is to develop comprehensive detailed kinetics for oxidation of C-SiC-SiO2-rubber in extreme oxidizing environment. This material is used as a coating on the outer surface of Navy weapon systems. In order to predict the fate of this material under extreme conditions and mitigate the degradation of the coating, a comprehensive oxidation mechanism is required. In Phase I, CFDRC, in collaboration with Penn State, will develop a detailed surface reaction mechanism for C-SiC-SiO2-rubber oxidation. We will use novel molecular modeling methods, such as reactive molecular dynamics and quantum chemistry in conjunction with reaction rate theories and literature reports to develop the rate parameters of a series of elementary reactions. In Phase I, feasibility of this approach will be demonstrated via computing reactions related to SiC oxidation. When complete, this mechanism can be used with any thermal analysis code to predict the oxidative degradation of the composite material. In addition, this will also help in designing novel composites with improved properties.

* Information listed above is at the time of submission. *

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