Amperometric Detection of Arsine Gas

Award Information
Agency: Department of Health and Human Services
Branch: N/A
Contract: 1 R43 ES06736-1,
Agency Tracking Number: 25049
Amount: $74,991.00
Phase: Phase I
Program: SBIR
Awards Year: 1994
Solicitation Year: N/A
Solicitation Topic Code: N/A
Solicitation Number: N/A
Small Business Information
999 Chicago Avenue, Naperville, IL, 60540
DUNS: N/A
HUBZone Owned: N
Woman Owned: N
Socially and Economically Disadvantaged: N
Principal Investigator
 William Penrose
 (708) 357-0004
Business Contact
Phone: () -
Research Institution
N/A
Abstract
Arsine (AsH3) is a very toxic gas that is encountered in the semiconductor, metal refining andother industries. Complex ventilators, scrubbers, and detectors are needed to control the gas whereverit is used. We will investigate the detection of arsine gas in real time using an electrochemical sensor,as well as the potential for using electrochemical sensor, as well as the potential for using electrochemi-cal reactors for an electrochemical sensors, as well as the potential for using electrochemical reactorsfor oxidizing arsine in exhaust air streams. Alkylated arsines are known to react on gold workingelectrodes with great sensitivity. We will determine whether inorganic arsine can be detected in anamperometric gas sensor system. The sensitivity and selectivity will be measured. If necessary,auxiliary systems such as automatic baseline correction and absorptive preconcentration may be usedto improve the sensitivity. We will investigate whether the miniature cell used for sensing arsines canbe scaled up to reactor sizes in order to scrub arsines from workplace air.

* Information listed above is at the time of submission. *

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