Improved Thermoelectric Materials: Skutterudite Superlattices Prepared via Kinetic Trapping from Modulated Reactants

Award Information
Agency:
Department of Defense
Branch
Navy
Amount:
$70,000.00
Award Year:
1997
Program:
SBIR
Phase:
Phase I
Contract:
n/a
Agency Tracking Number:
36967
Solicitation Year:
n/a
Solicitation Topic Code:
n/a
Solicitation Number:
n/a
Small Business Information
Umpqua Research Co
P.O. Box 609, Myrtle Creek, OR, 97457
Hubzone Owned:
N
Minority Owned:
N
Woman Owned:
N
Duns:
n/a
Principal Investigator:
James R. Akse
(541) 863-7770
Business Contact:
() -
Research Institution:
n/a
Abstract
An innovative pathway toward the synthesis of thin film and bulk thermoelectric materials based on skutterudite structures is proposed. Filled skutterudites possess large unit cell sizes, low electrical resistivities, and encaged rare earth atoms which will rattle in their oversized environment scattering phonons responsible for the undesired thermal conductivity. These physical properties make them prime candidates for thermoelectric materials. Their potential for being synthesized as the conducting layer of a quantum well superlattice with its higher density of states for the conducting layer will produce a thin film material with a potentially high thermoelectric figure of merit. The innovative pathway proposed by Umpqua Research Company (UMPQUA) involves the physical vapor deposition of elemental layers and controlled thermal annealing to produce the desired Skutterudite material. A series of Lanthanum filled (Co/Fe)4Sb12 skutterudite materials will be made with various Co:Fe ratios to optimize its thermoelectric properties. Using experience gained, a series of LaFe4Sb12/AlSb superlattice structures will be synthesized and optimized for their thermoelectric properties.

* information listed above is at the time of submission.

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