Inexpensive, Environmentally Benign Li-Ion Battery Cathode Materials for HEV and PHEV Applications

Award Information
Agency:
Department of Energy
Branch
n/a
Amount:
$99,456.00
Award Year:
2007
Program:
STTR
Phase:
Phase I
Contract:
DE-FG02-07ER86333
Award Id:
84334
Agency Tracking Number:
83170
Solicitation Year:
n/a
Solicitation Topic Code:
n/a
Solicitation Number:
n/a
Small Business Information
82 Mechanic Street, Pawcatuck, CT, 06379
Hubzone Owned:
N
Minority Owned:
N
Woman Owned:
N
Duns:
617158712
Principal Investigator:
Malgorzata Gulbinska
Dr
(860) 599-1100
mgulbinska@lithion.com
Business Contact:
John Dufrat
Mr
(860) 599-1100
jdufrat@lithion.com
Research Institution:
Northeastern University
Sanjeev Mukerjee
120 Forsyth Street
Boston, MA, 2115
(617) 373-2382
Nonprofit college or university
Abstract
This project will develop inexpensive and environmentally benign LiMnPO4 cathodes for applications to lithium-ion batteries (LIB) used in electric and hybrid electric vehicles. This cathode material is expected to be far safer than Li-ion batteries employing traditional layered LiMO2 (M=Co, Ni) materials. A number of synthetic modifications will be pursued to optimize the LiMnPO4 material for use in Li-ion batteries: (1) decreasing the average particle size to a nano-region via sol-gel synthesis, thereby shortening the Li-ion diffusion path and ensuring the high rate performance of LiMnPO4 cathode materials; (2) doping with 1 atom percent of Nb5+ or Zr4+, which has proven successful in enhancing the electronic conductivity of LiFePO4 cathodes; and (3) adding conductive carbon nanoparticles during the sol-gel process, which also should increase the electronic conductivity of LiMnPO4 cathodes. In Phase I, cells will be tested for irreversible capacity, impedance, rate capability within varied temperature ranges, and self discharge rates. In-depth electrochemical characterizations of the best cathode candidate(s) will follow in Phase II, based on selected testing procedures of the DOE and the U.S. Advanced Battery Consortium. Commercial Applications and other Benefits as described by the awardee: Safe, inexpensive, and environmentally benign lithium-ion cells, with the high energy density and high-rate capability, should benefit the electric vehicle (EV) and hybrid electric vehicle (HEV) markets. Other niche markets include military man pack batteries and charging sources, aircraft applications, and specialized industrial applications.

* information listed above is at the time of submission.

Agency Micro-sites


SBA logo

Department of Agriculture logo

Department of Commerce logo

Department of Defense logo

Department of Education logo

Department of Energy logo

Department of Health and Human Services logo

Department of Homeland Security logo

Department of Transportation logo

Enviromental Protection Agency logo

National Aeronautics and Space Administration logo

National Science Foundation logo
US Flag An Official Website of the United States Government