Development of Iron Phosphate Wasteforms for Fission Products Waste Streams

Award Information
Agency:
Department of Energy
Branch
n/a
Amount:
$149,978.00
Award Year:
2014
Program:
SBIR
Phase:
Phase I
Contract:
DE-SC0011906
Award Id:
n/a
Agency Tracking Number:
212338
Solicitation Year:
2014
Solicitation Topic Code:
19g
Solicitation Number:
DE-FOA-0001046
Small Business Information
4040 Hy Point North, Rolla, MO, 65401-8277
Hubzone Owned:
N
Minority Owned:
N
Woman Owned:
N
Duns:
190717025
Principal Investigator:
Cheol-Woon Kim
Dr.
() -
ckim@mo-sci.com
Business Contact:
Cheol-Woon Kim
Dr.
(573) 364-2338
ckim@mo-sci.com
Research Institution:
Stub




Abstract
Most liquid high-level nuclear waste is currently being immobilized to a solid form as a borosilicate glass by vitrification. However, many nuclear wastes have complex and diverse chemical compositions that reduce their compatibility with borosilicate glass. The current baseline spent nuclear fuel reprocess generates secondary waste streams that generally include large amounts of MoO3 and lanthanides that are poorly soluble in borosilicate glasses and thereby limit the waste loading. New waste forms as alternatives to borosilicate glass are being sought to increase the waste loading while retaining acceptable chemical durability and thus to decrease the total nuclear waste volume required for storage and disposal. The main goal of the proposed nine month, SBIR Phase I program is to develop suitable iron phosphate-based compositions for vitrifying the MoO3-rich waste generated from reprocessed spent nuclear fuel with greater waste loadings than can presently be achieved with borosilicate glass and while retaining chemical durability that meets or exceeds appropriate DOE standards. Our previous studies have already demonstrated proof-of- concept for molybdenum solubility in an iron phosphate glass. During the Phase I program, we will formulate iron phosphate compositions to develop advanced waste forms, which can contain larger amounts ( & gt;40 wt%) of the MoO3-rich waste, compared to a borosilicate glass, while demonstrating (1) a good glass forming tendency, (2) moderate/practical melting and forming temperatures ( & lt;1200C), and (3) acceptable waste form properties, especially a chemical durability meeting the Product Consistency Test (PCT) requirements. Commercial Applications and Other Benefits: The proposed research will demonstrate that iron phosphate waste forms will increase radioactivity concentrations that can be safely stored and thereby decrease the total nuclear waste volume for storage and disposal. This would lead to considerable savings of time and money for the Nations effort related to nuclear waste remediation, something that is especially needed for the advanced domestic fuel cycle program.

* information listed above is at the time of submission.

Agency Micro-sites


SBA logo

Department of Agriculture logo

Department of Commerce logo

Department of Defense logo

Department of Education logo

Department of Energy logo

Department of Health and Human Services logo

Department of Homeland Security logo

Department of Transportation logo

Enviromental Protection Agency logo

National Aeronautics and Space Administration logo

National Science Foundation logo
US Flag An Official Website of the United States Government