Surface Modification of Exfoliated Graphite Nano-Reinforcements

Award Information
Agency:
National Aeronautics and Space Administration
Branch
n/a
Amount:
$69,999.00
Award Year:
2005
Program:
SBIR
Phase:
Phase I
Contract:
NNC05CA23C
Award Id:
72681
Agency Tracking Number:
041190
Solicitation Year:
n/a
Solicitation Topic Code:
n/a
Solicitation Number:
n/a
Small Business Information
9621 Camino del Sol NE, Albuquerque, NM, 87111
Hubzone Owned:
N
Minority Owned:
N
Woman Owned:
N
Duns:
859106296
Principal Investigator:
RonaldAllred
(505) 346-1685
adherenttech@earthlink.net
Business Contact:
SusanSwitzer
Business Official
(505) 346-1685
adherenttech@comcast.net
Research Institute:
n/a
Abstract
Nano forms of graphite and carbon, such as flakes, worms, and tubes, can significantly modify the properties of polymers when used as reinforcements. Challenges remain in processing composites with these nano-reinforcements in the form of attaining uniform dispersions. Many of these difficulties are due to a lack of wetting of the nano-reinforcements by the polymer. Poor wetting is caused by the very low surface energy of the as-produced graphite nano-reinforcements. Opportunities exist for modifying the surface chemistry and energy of nano-reinforcements that will allow improved wetting and provide a means for chemical bonding at the interface with high temperature polymers such as PMR-II-50 polyimide. Two approaches for surface modification are proposed: (1) oxidative plasma treatments to populate the graphite surface with carboxyl and hydroxyl groups, and (2) bonding of polyimide oligomers to the nano-reinforcements using reactive coupling agents. Both of these approaches have proven successful with micron size carbon and graphite fibers and with nanofibers. As such, these treatments should result in nano-reinforced composites with superior mechanical properties and environmental durability.

* information listed above is at the time of submission.

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