Heterogenized Homogeneous Catalysts based on Polymer-Supported N-Heterocyclic Carbenes

Award Information
Agency:
National Science Foundation
Branch
n/a
Amount:
$106,219.00
Award Year:
2002
Program:
SBIR
Phase:
Phase I
Contract:
n/a
Award Id:
57884
Agency Tracking Number:
0128715
Solicitation Year:
n/a
Solicitation Topic Code:
n/a
Solicitation Number:
n/a
Small Business Information
887 Industrial Road, Suite G, San Carlos, CA, 94070
Hubzone Owned:
N
Minority Owned:
N
Woman Owned:
N
Duns:
n/a
Principal Investigator:
Jeffrey Labadie
(650) 598-1350
jlabadie@argotech.com
Business Contact:
() -
Research Institute:
n/a
Abstract
This Small Business Innovation Research Phase I project will research technical and commercial feasibility of heterogenized homogeneous (supported) palladium N-heterocyclic carbene (NHC) catalysts. Homogeneous palladium-catalyzed reactions are powerful methods for carbon-carbon and carbon-hetero atom bond formations, such as Heck and Suzuki reactions. However, their commercial adoption in fine chemical manufacture has been burdened by the inefficiencies associated with homogeneous catalysts, primarily recovery and recycling, which could be eliminated by the development of supported catalysts. Successful research and development would result in commercial products that would simplify post-reaction processing, reduced waste streams and reduction in costs via recycling.

* information listed above is at the time of submission.

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